CAS: 6470-87-7; 9,10-Dioxo-9,10-Dihydroanthracene-2-Carbonyl Chloride
该化合物是一种活性有机化合物,主要用作染料,药品和特殊化学品合成的中间体;其炭疽基质具有稳定性和染色特性,使其对高热度和轻度的色素产生价值;碳基氯化物功能组增强回动性,促进高效的电解和凝聚反应;该复合物特别有助于制作需要控制功能化的炭丙酮衍生物;其明确界定的结构确保合成应用的一贯性,而其纯度对于最大限度地减少侧面反应至关重要;妥善处理由于其湿度敏感性和潜在的腐蚀性,至关重要.
- 英文名称9,10-Dioxo-9,10-Dihydroanthracene-2-Carbonyl Chloride
- 中文名称蒽醌-2-甲酰氯
- IUPAC名称9,10-dioxo-9,10-dihydroanthracene-2-carbonyl chloride
- 其它别名2-Anthroylchloride, 9,10-dihydro-9,10-dioxo- (8CI); 2-(Chlor°Carbonyl)anthraquinone; 2-Anthraquinonecarbonyl chloride; 2-Anthraquinonecarboxylic acid chloride; 9,10-Dioxo-9,10-dihydro-2-anthracenecarbonyl chloride; Anthraquinone-b-carbonyl chloride
- CAS编号6470-87-7
- MFCD编号:MFCD00059498
- EINECS号:672-715-1
- 分子式:C15H7ClO3分子量:270.67
- 产品CID: 1630638
- 产品分类有机原料 → 羧酸类化合物及衍生物 → 羧酸酰卤化物
物理性质
MSDS等安全信息
欧盟法规
C&L通报上下游产品
CAS号117-78-2 蒽醌-2-羧酸 | CAS号84-54-8 2-甲基蒽醌 | CAS号10273-60-6 2-acetylanthrac... | CAS号7223-72-5 9,10-dioxoanthr... | CAS号81086-02-4 N-(2-(Diethylam... | CAS号96175-53-0 dodecyl 9,10-di... | CAS号6363-86-6 9,10-二氧代-9,10-二...合成工艺路线路线简述
📜蒽醌-2-羧酸置于草酰氯,N,N-二甲基甲酰胺体系中,用 二氯甲烷 作为反应溶剂,化学反应生成 蒽醌-2-甲酰氯
参考文献:包含c8标记的2'-脱氧腺苷的寡脱氧核苷酸的合成和稳定性:用于dna介导的电荷转移研究的新型氧化还原核碱基探针.
标题:包含c8标记的2'-脱氧腺苷的寡脱氧核苷酸的合成和稳定性:用于dna介导的电荷转移研究的新型氧化还原核碱基探针.
摘要:[反应:见正文]描述了一种有效且方便的合成策略,用于氧化还原标记的2'-脱氧腺苷的c8衍生物.pd(0)交叉偶联化学方法适用于氧化和还原氧化还原探针.吩噻嗪和蒽醌核苷的相应亚磷酰胺适合于自动dna合成.所得标记的寡聚脱氧核苷酸链形成稳定的b型双链体,其熔化温度和cd光谱与未标记类似物的相似.
DOI:10.1021/ol006303F
海关参考信息
- 2912110000-甲醛
2912210000-苯甲醛
2914610000-蒽醌
2903110000-一氯甲烷及氯乙烷 - 💡 提示：海关信息按照顺序优先匹配，如需确认的海关信息，请参考相关资料。
- 详情请参考：📖 海关编码查询和海关进出口税则
专利信息
专利号:US-6531591-B1
优先权日:1999-07-07
标 题 :Synthesis of stable quinone and photoreactive ketone phosphoramidite reagents for solid phase synthesis of photoreactive-oligomer conjugates
发明人：FENSHOLDT JEF
权利人:EXIQON AS
摘要:Quinone phosphoramidite reagents as well as photoreactive ketone phosphoramidite reagents, such as anthraquinone phosphoramidite reagents and benzophenone phosphoramidite reagents were synthesized and used for the solid phase synthesis of photoreactive-oligonucleotide conjugates. These phosphoramidite reagents are stable, suitable for large-scale synthesis and designed for automated solid phase synthesis of oligomers terminating in a photoreactive moiety.
专利号:EP-1202998-B1
优先权日:1999-07-07
标 题 :Synthesis of stable quinone and photoreactive ketone phosphoramidite reagents for solid phase synthesis of photoreactive-oligomer conjugates
发明人：FENSHOLDT JEF
权利人:EXIQON AS
摘要:Quinone phosphoramidite reagents as well as photoreactive ketone phosphoramidite reagents, such as anthraquinone phosphoramidite reagents and benzophenone phosphoramidite reagents were synthesized and used for the solid phase synthesis of photoreactive-oligonucleotide conjugates. These phosphoramidite reagents are stable, suitable for large-scale synthesis and designed for automated solid phase synthesis of oligomers terminating in a photoreactive moiety.
专利号:EP-1202998-A1
优先权日:1999-07-07
标题:Synthesis of stable quinone and photoreactive ketone phosphoramidite reagents for solid phase synthesis of photoreactive-oligomer conjugates
专利号:WO-0104129-A1
优先权日:1999-07-07
标题:Synthesis of stable quinone and photoreactive ketone phosphoramidite reagents for solid phase synthesis of photoreactive-oligomer conjugates
供应商参考报价(招募中)
品牌试剂参考报价(招募中)
📌 第三方产品分析报告
合成参考文献
摘要:Zhang, M.; Su, W., Science of Synthesis: Cross Coupling and Heck-Type Reactions, (2012) 3, 104.
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