CAS: 61240-34-4; (1R,5R,6R,7R)-5-Allyl-7-(Benzo[d][1,3]Dioxol-5-yl)-3-Methoxy-6-Methylbicyclo[3.2.1]Oct-3-Ene-2,8-Dione

英文名称(1R,5R,6R,7R)-5-Allyl-7-(Benzo[d][1,3]Dioxol-5-yl)-3-Methoxy-6-Methylbicyclo[3.2.1]Oct-3-Ene-2,8-Dione
中文名称(1R,5R,6R,7R)-REL-7-(1,3-苯并二氧戊环-5-基)-3-甲氧基-6-甲基-5-(2-丙烯-1-基)双环[3.2.1]辛-3-烯-2,8-二酮
IUPAC名称(1R,5R,6R,7R)-5-allyl-7-(benzo[d][1,3]dioxol-5-yl)-3-methoxy-6-methylbicyclo[3.2.1]oct-3-ene-2,8-dione
其它别名Denudadione C; (1R,5R,6R,7R)-Rel-7-(1,3-Benzodioxol-5-yl)-3-Methoxy-6-Methyl-5-(2-Propen-1-yl)Bicyclo[3.2.1]Oct-3-Ene-2,8-Dione; Bicyclo[3.2.1]Oct-3-Ene-2,8-Dione, 7-(1,3-Benzodioxol-5-yl)-3-Methoxy-6-Methyl-5-(2-Propen-1-yl)-, (1R,5R,6R,7R)-Rel-; Rel-(1R5R6R7R)-7-(13-Benzodioxol-5-yl)-3-Methoxy-6-Methyl-5-(2-Propen-1-yl)Bicyclo[3.2.1]Oct-3-Ene-28-Dione
CAS编号61240-34-4
MFCD编号:MFCD28009417
分子式:C20H20O5分子量:340.38
产品CID: 1593924
产品分类有机原料 → 有机杂环化合物 → 苯并间二氧杂环戊烯类

相似结构搜索
InChIKey: YCTWRMSXONXESR-NBSNSOTFSA-N
InChI=1S/C20H20O5/c1-4-7-20-9-15(23-3)18(21)17(19(20)22)16(11(20)2)12-5-6-13-14(8-12)25-10-24-13/h4-6,8-9,11,16-17H,1,7,10H2,2-3H3/t11-,16+,17+,20+/m1/s1
计算化学: 氢键受体数5.0氢键供体数0.0可旋转键数4.0

MSDS等安全信息

危险描述H303May be harmful if swallowed+H313Skin contact may be harmful+H333Inhalation may be harmful to the body
防范说明P264+P280+P305+P351+P338+P337+P313
危险品标志Xi
安全声明H303+H313+H333

上下游产品

2-hydroxy-4,5-dimethoxyallylbenzene (Z)-5-(prop-1-en-1-yl)benzo[d][1,3]dioxole

合成工艺路线路线简述

📜4,5-二甲氧基-2-(2-丙烯基)苯酚,5-[(E)-丙-1-烯基]苯并[1,3]二氧杂环戊烯以甲醇,溶剂黄146 作为反应溶剂,以81%的收率获得产物(1R,5R,6R,7R)-Rel-7-(1,3-苯并二氧戊环-5-基)-3-甲氧基-6-甲基-5-(2-丙烯-1-基)双环[3.2.1]辛-3-烯-2,8-二酮
参考文献:Shizuri,Yoshikazu; Yamamura,Shosuke,Tetrahedron Letters,1983,Vol. 24,# 45,P. 5011-5012
标题:Shizuri,Yoshikazu; Yamamura,Shosuke,Tetrahedron Letters,1983,Vol. 24,# 45,P. 5011-5012