CAS: 2396-63-6; Hepta-1,6-Diyne

该化合物是分子式C7H8的线性极光二极管,具有两个终端烷基组,该化合物主要用于有机合成和材料科学,因为它在点击化学,循环增殖反应和聚合过程中具有高度的回活动性.它的对称结构和终端烷基,使它成为建造复杂的分子结构,包括聚合聚合物和大型循环化合物的宝贵建筑块.二极管功能还使它得以在交叉反应和金属-有机框架(MOFs)中使用.分子重量相对较低且定义明确的再活动,1,6-heptadiyne是需要精确分子设计的研究和工业应用的多功能中间体.

结构式图片

欧盟法规

ECHA物质ECHA物质C&L通报REACH预注册

上下游产品

sodium acetylide 1,3-dibromo-propane acetylene ammonia Cyclotetrakosatetrain-(1.6.13.18) 1,6-undecadiyne 5-hexyl-2,3-dihydro-1H-indene 5-phenylindan

合成工艺路线路线简述

  • 合成目标产物 1,6-Heptadiyne 主要起始原料 1,3-Dibromopropane And Acetylene
  • (文献来源)合成步骤主要原料 1,3-Dibromopropane 和 Acetylene
📜乙炔钠,1,3-二溴丙烷置于乙醚,氨,乙炔体系中,化学反应生成1,6-庚二炔
参考文献:Parker Et Al.,Journal Of The Chemical Society,1959,P. 2433,2436
标题:Parker Et Al.,Journal Of The Chemical Society,1959,P. 2433,2436

海关参考信息

专利信息


专利号:US-6603070-B2
优先权日:2000-07-21
标题 :Convergent synthesis of multiporphyrin light-harvesting rods
发明人:LINDSEY JONATHAN S; LOEWE ROBERT S
权利人:UNIV NORTH CAROLINA STATE
摘要:The present invention provides a convergent method for the synthesis of light harvesting rods. The rods are oligomers of the formula A 1 (A b+1 ) b , wherein b is at least 1, A 1 through A b+1 are covalently coupled rod segments, and each rod segment A 1 through A 1+b comprises a compound of the formula X 1 (X m+1 ) m wherein m is at least 1 and X 1 through X m+1 are covalently coupled porphyrinic macrocycles. Light harvesting arrays and solar cells containing such light harvesting rods are also described, along with intermediates useful in such methods and rods produced by such methods.

专利号:US-3578724-A
优先权日:1968-03-04
标 题:Migration and isomerization of acetylenes
发明人:HUBERT ANDRE JULES
权利人:UNION CARBIDE CORP
摘要:PROCESS FOR THE MIGRATION OF ACETYLENIC BONDS AND A PROCESS FOR THE ISOMERIZATION OF HYDROCARBONS CONTAINING ACETYLENIC BONDS TO HYDROCARBONS CONTAINING CONJUGATED UNSATURATION, BY CONTACTING A COMPOUND CONTAINING ONE OR TWO ACETYLENIC BONDS WITH POTASSIUM AMIDE ON ALUMINA. THE UNSATURATED COMPOUNDS PRODUCED BY THE PROCESS OF THE INVENTION ARE USEFUL AS ULTRAVIOLET LIGHT ABSORBERS, AS CROSS-LINKING AGENTS FOR POLYOLEFINIC ELASTOMERS, AND AS INTERMEDIATES IN THE SYNTHESIS OF NEW COMPOUNDS.

专利号:US-9994602-B2
优先权日:2010-12-27
标 题 :Spiroannulated nucleosides and process for the preparation thereof
发明人:CHEPURI VENKATA RAMANA; DUSHING MANGESH PANDURANG
权利人:COUNCIL SCIENT IND RES
摘要:We claim a simple strategy for the synthesis of a collection of C(3′)-spirodihydroisobenzo-furannulated and C(3′)-spirodihydroisobenzo-furannulated nucleosides featuring a [2+2+2]-cyclotrimerization as the key reaction. The cyclotrimerization reactions are facile with the unprotected nucleosides having a diyne unit. When both alkynes of the diyne are terminal, the regioselectivity is poor. However, when one of the terminal alkynes is additionally substituted, the cyclotrimerizations are highly diastereoselective. Since the key bicycloannulation is the final step, this strategy provides flexibility in terms of the alkynes and is thus amenable for the synthesis of a focussed small molecule library.

专利号:US-2003111108-A1
优先权日:2000-07-21
标题:Convergent synthesis of multiporphyrin light-harvesting rods

专利号:US-10287225-B2
优先权日:2015-05-13
标 题:Chain multiyne compound, preparation method and application thereof
发明人:XIA HAIPING; ZHUO QINGDE; LIN JIANFENG; ZHOU XIAOXI; CHEN ZHIXIN; SHAO YIFAN; ZHANG HONG; HE XUMIN
权利人:UNIV XIAMEN
摘要:The present invention relates to fields of organic chemistry and organometallic chemistry. The present invention discloses a chain multiyne compound, a preparation method thereof and an application in synthesizing a fused-ring metallacyclic compound. A structure of the chain multiyne compound in the present invention is shown as Formula I below. The present invention also provides a preparation method of the chain multiyne compound and an application thereof in a synthesis of a fused-ring metallacyclic compound. The chain multiyne compound disclosed in the present invention has multiple functional groups and the structure of the chain multiyne compound is adjustable. The chain multiyne compound can also be used to synthesize the fused-ring metallacyclic compound efficiently. The preparation method of the chain multiyne compound disclosed in the present invention is simple, which can be used to prepare the chain multiyne compound rapidly and efficiently.

专利号:CN-115335358-B
优先权日:2020-03-20
标题 :Synthesis of Capsaicin Derivatives

供应商参考报价(招募中)

品牌试剂参考报价(招募中)

📌 第三方产品分析报告

✅ COA系统入驻 | 共享模式

合成参考文献


摘要:Gandon, V.; Thorimbert, S.; Malacria, M., Science of Synthesis, (2009) 46, 187.
摘要:Gandon, V.; Thorimbert, S.; Malacria, M., Science of Synthesis, (2009) 46, 190.
摘要:Amatore, M.; Aubert, C.; Malacria, M.; Petit, M., Science of Synthesis Knowledge Updates, (2012) 3, 24.
摘要:Pilgrim, B. S.; Tucker, M. J., Science of Synthesis Knowledge Updates, (2019) 1, 274.
摘要:Yoshimatsu, M., Science of Synthesis Knowledge Updates, (2016) 2, 387.
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