合成目标产物 1,6-Heptadiyne 主要起始原料 1,3-Dibromopropane And Acetylene
(文献来源)合成步骤主要原料 1,3-Dibromopropane 和 Acetylene
📜乙炔钠,1,3-二溴丙烷置于乙醚,氨,乙炔体系中,化学反应生成1,6-庚二炔 参考文献:Parker Et Al.,Journal Of The Chemical Society,1959,P. 2433,2436 标题:Parker Et Al.,Journal Of The Chemical Society,1959,P. 2433,2436
专利号:US-6603070-B2 优先权日:2000-07-21 标题 :Convergent synthesis of multiporphyrin light-harvesting rods 发明人:LINDSEY JONATHAN S; LOEWE ROBERT S 权利人:UNIV NORTH CAROLINA STATE 摘要:The present invention provides a convergent method for the synthesis of light harvesting rods. The rods are oligomers of the formula A 1 (A b+1 ) b , wherein b is at least 1, A 1 through A b+1 are covalently coupled rod segments, and each rod segment A 1 through A 1+b comprises a compound of the formula X 1 (X m+1 ) m wherein m is at least 1 and X 1 through X m+1 are covalently coupled porphyrinic macrocycles. Light harvesting arrays and solar cells containing such light harvesting rods are also described, along with intermediates useful in such methods and rods produced by such methods.
专利号:US-3578724-A 优先权日:1968-03-04 标 题:Migration and isomerization of acetylenes 发明人:HUBERT ANDRE JULES 权利人:UNION CARBIDE CORP 摘要:PROCESS FOR THE MIGRATION OF ACETYLENIC BONDS AND A PROCESS FOR THE ISOMERIZATION OF HYDROCARBONS CONTAINING ACETYLENIC BONDS TO HYDROCARBONS CONTAINING CONJUGATED UNSATURATION, BY CONTACTING A COMPOUND CONTAINING ONE OR TWO ACETYLENIC BONDS WITH POTASSIUM AMIDE ON ALUMINA. THE UNSATURATED COMPOUNDS PRODUCED BY THE PROCESS OF THE INVENTION ARE USEFUL AS ULTRAVIOLET LIGHT ABSORBERS, AS CROSS-LINKING AGENTS FOR POLYOLEFINIC ELASTOMERS, AND AS INTERMEDIATES IN THE SYNTHESIS OF NEW COMPOUNDS.
专利号:US-9994602-B2 优先权日:2010-12-27 标 题 :Spiroannulated nucleosides and process for the preparation thereof 发明人:CHEPURI VENKATA RAMANA; DUSHING MANGESH PANDURANG 权利人:COUNCIL SCIENT IND RES 摘要:We claim a simple strategy for the synthesis of a collection of C(3′)-spirodihydroisobenzo-furannulated and C(3′)-spirodihydroisobenzo-furannulated nucleosides featuring a [2+2+2]-cyclotrimerization as the key reaction. The cyclotrimerization reactions are facile with the unprotected nucleosides having a diyne unit. When both alkynes of the diyne are terminal, the regioselectivity is poor. However, when one of the terminal alkynes is additionally substituted, the cyclotrimerizations are highly diastereoselective. Since the key bicycloannulation is the final step, this strategy provides flexibility in terms of the alkynes and is thus amenable for the synthesis of a focussed small molecule library.
专利号:US-2003111108-A1 优先权日:2000-07-21 标题:Convergent synthesis of multiporphyrin light-harvesting rods
专利号:US-10287225-B2 优先权日:2015-05-13 标 题:Chain multiyne compound, preparation method and application thereof 发明人:XIA HAIPING; ZHUO QINGDE; LIN JIANFENG; ZHOU XIAOXI; CHEN ZHIXIN; SHAO YIFAN; ZHANG HONG; HE XUMIN 权利人:UNIV XIAMEN 摘要:The present invention relates to fields of organic chemistry and organometallic chemistry. The present invention discloses a chain multiyne compound, a preparation method thereof and an application in synthesizing a fused-ring metallacyclic compound. A structure of the chain multiyne compound in the present invention is shown as Formula I below. The present invention also provides a preparation method of the chain multiyne compound and an application thereof in a synthesis of a fused-ring metallacyclic compound. The chain multiyne compound disclosed in the present invention has multiple functional groups and the structure of the chain multiyne compound is adjustable. The chain multiyne compound can also be used to synthesize the fused-ring metallacyclic compound efficiently. The preparation method of the chain multiyne compound disclosed in the present invention is simple, which can be used to prepare the chain multiyne compound rapidly and efficiently.
专利号:CN-115335358-B 优先权日:2020-03-20 标题 :Synthesis of Capsaicin Derivatives
摘要:Gandon, V.; Thorimbert, S.; Malacria, M., Science of Synthesis, (2009) 46, 187. 摘要:Gandon, V.; Thorimbert, S.; Malacria, M., Science of Synthesis, (2009) 46, 190. 摘要:Amatore, M.; Aubert, C.; Malacria, M.; Petit, M., Science of Synthesis Knowledge Updates, (2012) 3, 24. 摘要:Pilgrim, B. S.; Tucker, M. J., Science of Synthesis Knowledge Updates, (2019) 1, 274. 摘要:Yoshimatsu, M., Science of Synthesis Knowledge Updates, (2016) 2, 387.