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3-dodecylthiophene laurylmagnesium bromide 1-dodecylbromide 3,3-didodecyl-2,2′;5′,2″;5″,2-quaterthiophene 5,5'''-dibromo-3,3'''-bis(dodecyl)-2,2':5',2'':5'',2'''-quarterthiophene 58H78O6S4C58H78O6S4 溴代十二烷置于n-溴代丁二酰亚胺(Nbs),1,3-Bis[(Diphenylphosphino)Propane]Dichloronickel(II),Magnesium体系中,用 四氢呋喃,N,N-二甲基甲酰胺 用作溶剂,化学反应生成2-溴-3-十二烷基噻吩
参考文献:Synthesis Of Donor-acceptor Copolymer Using Benzoselenadiazole As Acceptor For Otft
标题:Synthesis Of Donor-acceptor Copolymer Using Benzoselenadiazole As Acceptor For Otft
摘要:合成的共聚物具有较低的能隙,并表现出约0.1 Cm2 V−1 S−1的空穴迁移率.
Doi:10.1039/c5Ra23805F
专利信息
专利号:US-9328109-B2
优先权日:2013-01-14
标 题:Process for the preparation of benzohetero [1, 3] diazole compounds disubstituted with heteroaryl groups
发明人:BIANCHI GABRIELE; PO' RICCARDO
权利人:ENI SPA
摘要:Process for the preparation of a benzohetero-[1,3]diazole compound disubstituted with brominated heteroaryl groups which comprises reacting at least one dihalogenated benzohetero[1,3]diazole compound with at least one brominated heteroaryl compound. Said benzohetero[1,3]diazole compound disubstituted with brominated heteroaryl groups can be advantageously used in the synthesis of compounds useful in the construction of solar concentrators (LSCs—“Luminescent Solar Concentratorsâ€?). Furthermore, said benzohetero[1,3]diazole compound disubstituted with brominated heteroaryl groups can be advantageously used in the synthesis of photoactive polymers useful in the construction of photovoltaic devices (or solar devices) such as, for example, photovoltaic cells (or solar cells), photovoltaic modules (or solar modules), on both rigid or flexible supports. Furthermore, said benzohetero[1,3]diazole compound disubstituted with brominated heteroaryl groups can be advantageously used as precursor of monomeric units in the synthesis of semiconductr polymers.
专利号:CN-101213234-B
优先权日:2005-04-01
标 题:Living Synthesis of Conductive Polymers Including Regioregular Polymers, Polythiophenes and Block Copolymers
专利号:CN-101213234-A
优先权日:2005-04-01
标题 :Living synthesis of conducting polymers including regioregular polymers, polythiophenes, and block copolymers
专利号:CN-101402629-A
优先权日:2008-11-19
标 题 :Synthesis and uses of terthienyl and derivatives thereof
专利号:US-7102017-B2
优先权日:2004-06-10
标 题 :Processes to prepare small molecular thiophene compounds
发明人:LIU PING; WU YILIANG; ONG BENG S; BIRAU MARIA
权利人:XEROX CORP
摘要:A process composed of subjecting a reaction mixture comprising a reaction medium, a coupling agent, and a precursor to a coupling temperature to preferentially form a desired small molecular thiophene compound in a single-step synthesis, wherein the precursor consists of: (i) an optional divalent linkage, and (ii) a plurality of thiophene units, each thiophene unit being represented by structure (A) n nwherein each thiophene unit is bonded at either or both of the second ring position and the fifth ring position.