1-氯-2,2,3,3-四氟丙烷置于cu/ni 氢气体系中,化学反应生成 2,3,3,3-四氟丙烯 参考文献:Use Of Copper-Nickel Catalysts For Dehlogenation Of Chlorofluorocompounds 标题:Use Of Copper-Nickel Catalysts For Dehlogenation Of Chlorofluorocompounds 摘要:该披露描述了一种去卤化氯氟化合物的过程.该过程包括在存在催化剂的情况下,将饱和氯氟化合物与氢接触,以在足以去除氯和/或氟取代基的温度下产生含氟末端烯烃.
专利号:US-9079818-B2 优先权日:2007-10-15 标 题 :Process for synthesis of fluorinated olefins 发明人:MUKHOPADHYAY SUDIP; BORTZ CHERYL L; LIGHT BARBARA A; CANTLON CHERYL L; JOHNSON ROBERT C 权利人:MUKHOPADHYAY SUDIP; BORTZ CHERYL L; LIGHT BARBARA A; CANTLON CHERYL L; JOHNSON ROBERT C; HONEYWELL INT INC 摘要:Disclosed is a process for the synthesis of fluorinated olefins, and in particularly preferred embodiments tetrafluorinated olefins having F on an unsaturated, non-terminal carbon, such as 2,3,3,3-tetrafluoropropene. The preferred processes of the present invention in accordance with one embodiment generally comprise:n (a) reacting a compound of formula (I)n nX 1 X 2   (I)n nwith a compound of formula (II)n nCX 1 X 2 X 3 CX 1 â•?CX 1 X 2   (II)n nto produce a reaction product comprising a compound of formula (III)n nCF 3 CHX 1 CH 2 X 2   (III), andn (b) exposing said compound of formula (III) to reaction conditions effective to convert said compound of formula (III) to a compound of formula (IV)n nCF 3 CZâ•?CH 2   (IV)n nwherein X 1 , X 2 , and X 3 are each independently selected from the group consisting of hydrogen, chlorine, bromine, fluorine and iodine, provided that X 1 and X 2 in formula (I) are not both hydrogen and Z is Cl, I, Br, or F
专利号:US-2012184653-A1 优先权日:2011-01-18 标 题:Synthesis of linear phosphorus-containing functional fluorocopolymer 发明人:WANG LIANG; WANG VIKTORIA 权利人:WANG LIANG; WANG VIKTORIA 摘要:This invention relates to a synthesis of a linear fluorocopolymer having a plurality of pendant phosphorus-containing functional groups. The synthesized phosphorus-containing fluorocopolymer has chain linearity and narrow molecular weight distributions. It has applications as a lubricant additive that provides friction-reduction, anti-wear, and corrosion protection properties.
专利号:US-7371904-B2 优先权日:2004-04-29 标题:Processes for synthesis of 1,3,3,3-tetrafluoropropene 发明人:MA JING JI; MUKHOPADHYAY SUDIP; NAIR HARIDASAN K; TUNG HSUEH S; VAN DER PUY MICHAEL 权利人:HONEYWELL INT INC 摘要:Disclosed is a process for the synthesis of 1,3,3,3-tetrafluoropropene which comprises, in one embodiment, reacting a compound of CF 3 X 1 with a compound of CX 2 Hâ•?CHX 3 , wherein X 1 , X 2 , and X 3 are each independently selected from the group consisting of fluorine, chlorine, bromine and iodine, to produce a reaction product comprising a compound of CF 3 CHâ•?CHX 3 , wherein X 3 is as described above; and when X 3 is not fluorine, fluorinating the compound to produce 1,3,3,3-tetrafluoropropene. The process in another embodiment comprises preparing tetrafluoropropene comprising thermally cracking one or more compounds capable of producing a reaction mixture which preferably comprises diflurocarbene radicals and vinylidene fluoride, and converting said reaction mixture into—tetrafluoropropene (1,3,3,3-tetrafluoropropene).
专利号:US-7714177-B2 优先权日:2004-04-29 标题:Processes for synthesis of 1,3,3,3-tetrafluoropropene 发明人:MUKHOPADHYAY SUDIP; NAIR HARIDASAN K; TUNG HSUEH S; VAN DER PUY MICHAEL 权利人:HONEYWELL INT INC 摘要:Disclosed is a process for the synthesis of 1,3,3,3-tetrafluoropropene comprising: a) reacting a compound of the formula (I) CHFX 2 with a compound of formula (II) CH 2 â•?CF 2 to produce a reaction product comprising a compound of formula (III) CHXFCH 2 CXF 2 , wherein each X is independently selected from the group consisting of chlorine, bromine and iodine; and (b) exposing said compound of formula (III) to reaction conditions effective to convert said compound to 1,3,3,3-tetrafluoropropene.
专利号:US-8128902-B2 优先权日:2011-04-12 标题:Method for the synthesis of anhydrous hydrogen halide and anhydrous carbon dioxide 发明人:TARANCON III GREGORIO 权利人:TARANCON III GREGORIO; MIDWEST REFRIGERANTS LLC 摘要:A method for the synthesis of anhydrous hydrogen halide fluids from organic halide fluids, such as perfluorocarbon fluids and refrigerant fluids, and anhydrous carbon dioxide for the environmentally safe disposition thereof.
专利号:US-8043574-B1 优先权日:2011-04-12 标 题:Apparatus for the synthesis of anhydrous hydrogen halide and anhydrous carbon dioxide 发明人:TARANCON III GREGORIO 权利人:MIDWEST REFRIGERANTS LLC 摘要:An apparatus for the synthesis of anhydrous hydrogen halide fluids from organic halide fluids, such as perfluorocarbon fluids and refrigerant fluids, and anhydrous carbon dioxide for the environmentally safe disposition thereof.
摘要:Bartels, F.; Zimmer, R.; Christmann, M., Science of Synthesis Knowledge Updates, (2017) 3, 236. 摘要:S95 | PFASANEXCH | PFAS List from the NORMAN PFAS Analytical Exchange Activity | DOI:10.5281/zenodo.6384309 摘要:Compound: 1-Propene, 2,3,3,3-tetrafluoro-, homopolymer 摘要:S74 | REFTPS | Transformation Products and Reactions from Literature | DOI:10.5281/zenodo.4318838 摘要:Caron, S.; Lee, J.; Liu, Y.; Nguyen, T. N.; Piper, J. L.; Vicini, A. C., Science of Synthesis: Modern Strategies in Organofluorine Chemistry, (2025) 2.