CAS: 16466-61-8; Di-Tert-Butyl Hydrazine-1,2-Dicarboxylate

相似化合物

1073-62-7 20570-96-1 21075-83-2

上下游产品

N-(tert-butyloxycarbonyl) azide t-butoxycarbonylhydrazine tert-butyl cyanoformate tert-butyl dicarbonatedi-tert-butyl dicarbonatedi-tert-butyl-diazodicarboxylate 36H40N6O6C36H40N6O6 6,7-Bis-bromomethyl-1,4-dihydro-phthalazine-2,3-dicarboxylic acid di-tert-butyl ester 6-(Toluene-4-sulfonyl)-4,6-dihydro-1H-pyrrolo[3,4-d]pyridazine-2,3-dicarboxylic acid di-tert-butyl ester

叔-丁基氯甲酸酯置于肼体系中,用 乙醇,水 用作溶剂,化学反应 0.5H,以40%的收率获得二叔丁基叠氮草酸
参考文献:黄素和可见光介导的mitsunobu反应条件下的光催化酯化†
标题:黄素和可见光介导的mitsunobu反应条件下的光催化酯化†
摘要:证明了基于黄素的空中光氧化在mitsunobu反应条件下进行酯化反应中的有用性,从而提供了从相应的二烷基肼二羧酸二乙酯中回收/生成空中二烷基偶氮二羧酸酯的方法.同时,通过黄素的光诱导电子转移激活三苯膦(ph 3 P)可以使无偶氮试剂进行酯化.已显示使用3-乙酸甲基黄酮黄素四乙酸酯(10%),氧气(末端氧化剂),可见光(450 Nm),Ph 3 P和二羧酸肼二甲酸二烷基酯(10%)的优化系统可提供各种醇的高效立体选择性偶联和酸变成酯,并保留构型.
Doi:10.1039/c6Ob02770A

专利信息

专利号:EP-0024372-A1
优先权日:1979-08-03
标题:Derivatives of clavulanic acid, their preparation and pharmaceutical compositions containing them
发明人：DENERLEY PAUL MILLINGTON; EGLINGTON ALFRED JOHN; HARBRIDGE JOHN BARRY
权利人:BEECHAM GROUP PLC
摘要:The compounds of the formula (II):n and salts and esters thereof wherein the hydroxyl group occupies position 2 or 4 R 1 and R 2 may be the same or different and represent hydrogen, halogen, hydroxy, lower alkyl, cyclopentyl, cyclohexyl, lower alkoxy or R, and R 2 when an adjacent carbon atoms may together represent a 1,4-buta-1,3-dienylene group or a polymethylene group containing from 3 to 5 carbon atoms; have been found to be β-lactam antibiotics and synergists with penicillins and cephalosporins. Their preparation and use is described. The synthesis of intermediates useful in their preparation is also described.

专利号:CN-117603156-A
优先权日:2023-11-22
标 题:Synthesis method of pinoxaden intermediate N-acetyl- [1,4,5] -oxydiazepam