CAS: 15738-23-5; Sodium Tetra-P-Tolylborate

英文名称Sodium Tetra-P-Tolylborate
中文名称四对甲苯硼酸钠
IUPAC名称sodium tetra-p-tolylborate
其它别名Sodium Tetrakis(4-Methylphenyl)Borate, Tetra(P-Tolyl)Boron Sodium; Borate(1-), Tetrakis(4-Methylphenyl)-, Sodium(1:1); Sodium:Tetrakis(4-Methylphenyl)Boranuide; Sodium Tetrakis(4-Tolyl)Borate; Sodium Tetra(P-Tolyl)Borate, Analytical And Chromatography Reagent
CAS编号15738-23-5
MFCD编号:MFCD00672225
分子式:C28H28BNa
分子量:398.33
产品CID: 786536
产品分类有机原料→催化剂与配体→催化剂→其它金属催化剂

相似结构搜索
InChIKey: VVPGHQQFKGSIPJ-UHFFFAOYSA-N
InChI=1S/C28H28B.Na/c1-21-5-13-25(14-6-21)29(26-15-7-22(2)8-16-26,27-17-9-23(3)10-18-27)28-19-11-24(4)12-20-28;/h5-20H,1-4H3;/q-1;+1…
计算化学: 氢键受体数*氢键供体数0.0可旋转键数4.0

相似化合物

14637-34-4 25776-12-9 14680-77-4

MSDS等安全信息

GHS符号GHS06
警示词Danger
危险描述H301-H315-H319
防范说明P264-P270-P280-P302+P352-P330-P362+P364-P405-P501
危险等级6.1
UN编号2811.0
包装等级Ⅲ
WGK Germany3

上下游产品

sodium tetrafluoroborate para-methylphenylmagnesium bromide lithium tetrakis(p-methylphenyl)borate sodium cation(4,4'-dimethyl-1,1'-biphenyl) 4-Methylbiphenyl 2-(p-tolyl)naphthalene (8R,9S,13S,14S)-13-methyl-3-(p-tolyl)-6,7,8,9,11,12,13,14,15,16-decahydro-17H-cyclopenta[a]phenanthren-17-one

合成工艺路线路线简述

合成目标产物 Sodium Tetra(P-Tolyl)Borate 主要起始原料 Sodium Tetrafluoroborate And 4-Bromotoluene
(文献来源)合成步骤主要原料 Sodium Tetrafluoroborate 和 4-Bromotoluene

对溴甲苯置于magnesium,氟硼酸钠体系中,用乙醚用作溶剂,化学反应 48.0H,反应生成8-羟基-5,7-二甲氧基-2-[(7E,9E,11E)-4-甲氧基-3,5,6,11-四甲基-7,9,11-十三碳三烯-1-基]-3-甲基-4H-苯并吡喃-4-酮
参考文献:室温下无配体,原子效率高的suzuki-Miyaura型交叉偶联反应
标题:室温下无配体,原子效率高的suzuki-Miyaura型交叉偶联反应
摘要:报道了四芳基硼酸钠与芳基碘化物和溴化物的原子有效的交叉偶联反应.该反应可以使用由氯化钯,碳酸钠和甲醇(pdcl 2 / Na 2 Co 3 / Meoh)组成的催化体系,在无热条件下,在室温,露天条件下直接进行.该反应以原子有效的方式进行,如4当量的芳基卤化物与1当量的四芳基硼酸钠有效偶联,以非常好至优异的收率提供4当量的相应的官能化联芳基.
Doi:10.1016/j.Tet.2010.07.022

海关参考信息

2902300000-甲苯
💡 提示：海关信息按照顺序优先匹配，如需确认的海关信息，请参考相关资料。
详情请参考：📖 海关编码查询和海关进出口税则

专利信息

专利号:US-9663594-B2
优先权日:2014-05-15
标题 :Synthesis of aryl coupled bis phenoxides and their use in olefin polymerization catalyst systems with activator-supports
发明人：HLAVINKA MARK L
权利人:CHEVRON PHILLIPS CHEMICAL CO LP; CHEVRON PHILIPS CHEMICAL COMPANY LP
摘要:Disclosed herein are methods of making bis(phenol) ligand compounds and transition metal bis(phenolate) compounds. The transition metal bis(phenolate) compounds can be used as components in catalyst systems for the polymerization of olefins.

专利号:EP-3143006-A1
优先权日:2014-05-15
标题 :Synthesis of aryl coupled bis phenoxides and their use in olefin polymerization catalyst systems with activator-supports

专利号:US-9394387-B2
优先权日:2014-05-15
标题:Synthesis of aryl coupled bis phenoxides and their use in olefin polymerization catalyst systems with activator-supports

专利号:US-2015329652-A1
优先权日:2014-05-15
标题 :Synthesis of Aryl Coupled BIS Phenoxides and Their Use in Olefin Polymerization Catalyst Systems With Activator-Supports

专利号:US-2016289351-A1
优先权日:2014-05-15
标题:Synthesis of Aryl Coupled BIS Phenoxides and Their Use in Olefin Polymerization Catalyst Systems With Activator-Supports

专利号:EP-3143006-B1
优先权日:2014-05-15
标题 :Synthesis of aryl coupled bis phenoxides and their use in olefin polymerization catalyst systems with activator-supports