CAS: 1450-23-3; 1,1,1,2,2,2-Hexaphenyldisilane
该化合物是一种有机硅化合物,含有分子式(C6H55)6Si2.其特点是六联苯组将它捆绑在分裂性核上,使其成为有机和有机金属合成的有用的试剂,该化合物具有高度的热稳定性,并经常被用作含硅材料的前体,包括以硅为基础的聚合物和陶瓷.其富联苯结构有助于其有机溶解性,促进其在溶液阶段反应中的使用.六联苯二烯还因其作为先进材料的构件所具有的潜力,对光发光和光电子应用也感兴趣.其稳定性和再活动使其在研究和工业环境中具有价值.
- 英文名称1,1,1,2,2,2-Hexaphenyldisilane
- 中文名称六苯基二硅烷
- IUPAC名称1,1,1,2,2,2-hexaphenyldisilane
- 其它别名Disilane,hexaphenyl- (6CI,7CI,8CI,9CI); Hexaphenyldisilane
- CAS编号1450-23-3
- MFCD编号:MFCD00039558
- EINECS号:215-913-1
- FDA UNII编号:A836PXA3G6
- 分子式:C36H30Si2分子量:518.79
- 产品CID: 685748
- 产品分类化学试剂 → 有机试剂 → 硅烷
物理性质
- 熔点358-360 °C
- 沸点578.0±23.0 °C at 760 mmHg
- 闪点279.3±15.6 °C
- 密度1.1±0.1 g/cm3
- LogP:13.01
- 折射率1.654
- 蒸汽压0.0±1.5 mmHg at 25°C
- 溶解性Very Faint Turbidity In Hot Toluene
- 敏感性如果遵照规格使用和储存则不会分解，未有已知危险反应，避免氧化物
- 外观形态白色至几乎白色固体
- 储存条件保持贮藏器密封保存、储存在阴凉、干燥环境的地方，确保工作间有良好的通风或排气装置
- 产品应用该化合物用于将[11C]CO2转换为[11 C]CO.
- 性质描述六苯基二硅烷(1450-23-3)的性状:熔点:358-360°C;闪点:＞200°C.只需轻轻,
MSDS等安全信息
欧盟法规
ECHA物质C&L通报REACH预注册上下游产品
Triphenylsilyl chloride phenyl sodium benzophenone1,2-bis(triphenylsilyl)ethane (1,4-dihydro-[4]pyridyl)-triphenyl-silane triphenylsilyl bromide 5-Triphenylsilyl-1-pentanol合成工艺路线路线简述
📜三苯基硅烷置于dicarbonyl(Cyclopentadienyl)Methyliron(II)体系中,用 N,N-二甲基甲酰胺 用作溶剂,化学反应 48.0H,以95%的收率获得六苯基二硅烷
参考文献:Preparation Of Si-Si Bond-Bearing Compounds
标题:Preparation Of Si-Si Bond-Bearing Compounds
摘要:Si-si键含有化合物通过在有机溶剂中存在铁配合物催化剂的情况下,通过辐射或加热si-h基团含有的硅化合物有效制备.这些si-si键含有的化合物可用作光刻胶组合物,陶瓷前驱体组合物和导电组合物的基材料.
海关参考信息
- 2902200000-苯
- 💡 提示：海关信息按照顺序优先匹配，如需确认的海关信息，请参考相关资料。
- 详情请参考：📖 海关编码查询和海关进出口税则
专利信息
专利号:US-8575381-B2
优先权日:2010-09-17
标题:Trihydridosilyl-terminated polysilanes and methods of preparation
发明人：ARKLES BARRY C; PAN YOULIN; LARSON GERALD L
权利人:ARKLES BARRY C; PAN YOULIN; LARSON GERALD L; GELEST TECHNOLOGIES INC
摘要:Novel trihydridosilyl-terminated polysilanes and methods for their synthesis, which are applicable to other polysilanes, are provided. The synthetic methods provide for facile preparation of products with minimal handling of pyrophoric intermediates and byproducts. The novel compounds contain at least three silicon-silicon bonds and at least one terminal silicon atom having three hydrogen substituents.
专利号:CN-114409689-A
优先权日:2021-12-17
标题:Synthesis of Disilane from Chlorosilane
供应商参考报价(招募中)
品牌试剂参考报价(招募中)
📌 第三方产品分析报告
主要参考文献
参考标题:Electroreductive Synthesis Of Polysilanes, Polygermanes, And Related Polymers With Magnesium Electrodes1作者:Shigenori Kashimura,Manabu Ishifune,Natsuki Yamashita,Hang-Bom Bu,Masakatsu Takebayashi,Satsuki Kitajima,Daisuke Yoshiwara,Yasuki Kataoka,Ryoichi Nishida,Shin-Ichi Kawasaki,Hiroaki Murase,Tatsuya Shono |发布日期:1999.9.1
摘要:Poly(Alkylarylsilane) (M(N) = 5200-31000, M(W)/m(N) = 1.4-1.8) In 5-79% Yield. The Effects Of Electrode Material, Monomer Concentration, Amount Of Supplied Electricity, And Ultrasound Were Investigated. This Electroreductive Method Was Also Successfully Applied To The Synthesis Of Polygermanes, Silane-Geramane Copolymers, And Also Poly[p-(Disilanylene)Phenylenes].
合成参考文献
摘要:Hwu, J. R.; Ethiraj, K. S., Science of Synthesis, (2002) 4, 194.
摘要:Hwu, J. R.; Ethiraj, K. S., Science of Synthesis, (2002) 4, 198.
摘要:Hwu, J. R.; Ethiraj, K. S., Science of Synthesis, (2002) 4, 194.
摘要:Hwu, J. R.; Ethiraj, K. S., Science of Synthesis, (2002) 4, 190.
📝 需求与反馈
尽可能描述清楚需求与问题信息
