CAS: 130727-41-2; Thiol-C9-Peg4

该化合物是一种化学化合物,其独特的结构特征包括长脂链,多醚联系和一个终极酒精组.一个美甲类(-SH)的存在引入了硫醇特性,可产生反应性和形成分解结的可能性.该化合物可能由于醚和酒精功能而表现出水利生物特性,而长碳氢化合物链则可能助长疏水性特征.这些结构特征表明在表面活性剂,乳化剂或各种配方中作为稳定剂的潜在应用.此外,甲卡普托组可能增强该化合物与金属离子或其他活性物种互动的能力,使其在协调化学或作为离子体方面有用.

结构式图片

相似化合物

23684-16-4 130727-44-5 130727-42-3

上下游产品

undec-11-yl>tri(ethylene glycol)1-(methylcarbonyl)thioundec-11-yltri(ethylene glycol) 1,11-dibromoundecane 2,2'-[1,2-ethanediylbis(oxy)]bisethanol

合成工艺路线路线简述

  • 合成目标产物 1-(9-Mercaptononyl)-3,6,9-Trioxaundecan-11-Ol 主要起始原料 11-Bromo-1-Undecene
  • (文献来源)合成步骤主要原料 11-Bromo-1-Undecene
📜三乙二醇置于sodium Hydride,硫脲体系中,用 乙醇,N,N-二甲基甲酰胺 用作溶剂,化学反应 36.5H,反应生成三(乙烯醇) 单-11-十一烷基硫醇
参考文献:蛋白质抗性自组装单分子膜的实用性研究
标题:蛋白质抗性自组装单分子膜的实用性研究
摘要:本研究描述了从α,ω-二溴代烷烃开始的,以低聚乙二醇为末端的 链烷硫醇(oeg-At S)的新合成途径,第一步是与 Oeg 或与三苯甲基硫醇反应 .除了 Oeg 和 At的 这些醚共轭物外,还通过既定程序制备了类似的酯和酰胺共轭物.所有硫醇均用于在清洁的金表面上形成自组装单分子层( Sams ),并将它们在4oc的水中于水中储存1-2周,然后在 Igg,Bsa 和溶菌酶的条件下测试非特异性蛋白的吸附程度. 1毫克厘米-3磷酸盐缓冲盐水中蛋白质的浓度.在这些以实践为导向的测试条件下,具有三(乙二醇)链( Eg 3)的 Sam 表现出不令人满意的蛋白质抗性,与 Eg 4或更长的 Oeg 链形成鲜明对比 .当将它们连接至长酰基链(16-巯基十六烷酸)而不是12-巯基十二烷或11-巯基十一烷时,Eg 3的有效性 得以部分恢复.此外发现,(ⅰ) Sam 形成在20μ 中号 硫醇 与 500μ
Doi:10.1007/s00706-007-0584-7

海关参考信息

专利信息


专利号:US-11180507-B2
优先权日:2016-07-08
标题:Synthesis of functionalizable or functionalized poly(3,4-ethylenedioxythiphene)-based polymers and monomers therefor
发明人:CUI XINYAN; CAO BIN
权利人:UNIV PITTSBURGH COMMONWEALTH SYS HIGHER EDUCATION; UNIV OF PITTSBURGH—OF THE COMMONWEALTH SYSTEM OF HIGHER EDUCATION
摘要:A method of forming a compound having the formula (I′): (I′) includes the reaction: (II′) in the presence of a base, wherein X is a halo atom selected from the group consisting of Cl, Br and I.

专利号:US-2023132381-A9
优先权日:2016-07-08
标 题 :Synthesis of functionalizable or functionalized poly(3,4-ethylenedioxythiphene)-based polymers and monomers therefor

专利号:WO-2023113033-A1
优先权日:2021-12-16
标题 :Gas diffusion electrode
发明人:KONDO SHOICHI; MAEDA SHINICHI; SHIGA NORIHITO
权利人:NISSAN CHEMICAL CORP
摘要:[Problem] The present invention addresses the problem of increasing the rate of reaction by controlling ammonium ions, which are generated by ammonia as the objective of the electrolytic synthesis of ammonia and protons that are supplied to the cathode, by means of the cathode and the cathode catalyst layer. [Solution] The present invention provides a gas diffusion electrode which is integrated with a catalyst layer that uses a material selected from the group consisting of cathode catalyst layer materials. Examples of the cathode catalyst layer materials include a fired body and an ionic liquid.

专利号:US-2020181163-A1
优先权日:2016-07-08
标 题 :Synthesis of functionalizable or functionalized poly(3,4-ethylenedioxythiphene)-based polymers and monomers therefor

专利号:US-2022041618-A1
优先权日:2016-07-08
标题 :Synthesis of functionalizable or functionalized poly(3,4-ethylenedioxythiphene)-based polymers and monomers therefor

供应商参考报价(招募中)

品牌试剂参考报价(招募中)

📌 第三方产品分析报告

✅ COA系统入驻 | 共享模式

主要参考文献

[参考文献]: An S, Et Al. Small-Molecule Protacs: An Emerging And Promising Approach For The Development Of Targeted Therapy Drugs. Ebiomedicine. 2018 Oct;36:553-562
[参考文献]: Martin Bauch, Et Al. Plasmonic Amplification For Bioassays With Epi-Fluorescence Readout. Opt Express. 2014 Dec 29;22(26):32026-38.

合成参考文献


参考文献:10.1038/s42003-023-05242-x
摘要:Sarma S, Catella CM, San Pedro ET, Xiao X, Durmusoglu D, Menegatti S, Crook N, Magness ST, Hall CK. Design of 8-mer peptides that block Clostridioides difficile toxin A in intestinal cells. Commun Biol. 2023 Aug 26;6(1):878.
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