CAS: 5760-50-9; Methyl9-Undecenoate

相似化合物

1120-25-8 2390-09-2 112-62-9

上下游产品

油酸甲酯 Methyl Oleate 112-62-9
反-9-十八碳烯酸甲酯 Methyl (9E)-Octadec-9-Enoate 1937-62-8
10-烯酸甲酯 Methyl 10-Undecenoate 111-81-9
Methyl 11-Aminoundecanoate 28691-27-2
11-氨基十一酸 11-Aminoundecanoic Acid 2432-99-7

📜2-丁烯,油酸甲酯置于hoveyda-Grubbs Catalyst Second Generation体系中,用 甲苯 作为反应溶剂,化学反应生成 2-Undecene,9-十一烯酸甲酯
参考文献:螯合苯甲酸钌配合物:合成,一般催化活性及其在烯烃复分解聚合中的应用
标题:螯合苯甲酸钌配合物:合成,一般催化活性及其在烯烃复分解聚合中的应用
摘要:合成了环状钌酚盐,并将这些化合物用作烯烃复分解催化剂.对它们的催化活性的研究表明,这些催化剂在用化学试剂活化后,能促进闭环复分解(rcm),烯炔和交叉复分解(cm)反应(包括丁烯醛分解),并取得了非常好的效果.重要的是,这些潜在的催化剂可溶于纯净的二环戊二烯(dcpd),并在该单体的开环易位聚合反应(romp)中显示出非常好的适用性.
DOI:10.1002/chem.201403580

专利信息

专利号:US-8569560-B2
优先权日:2006-10-13
标题 :Synthesis of terminal alkenes from internal alkenes via olefin metathesis
发明人：SCHRODI YANN; PEDERSON RICHARD L; KAIDO HIROKI; TUPY MICHAEL J
权利人:ELEVANCE RENEWABLE SCIENCES
摘要:This disclosure relates generally to olefin metathesis, and more particularly relates to the synthesis of terminal alkenes from internal alkenes using a cross-metathesis reaction catalyzed by an olefin metathesis catalyst. According to one aspect, for example, a method is provided for synthesizing a terminal olefin, the method comprising contacting, in the presence of a ruthenium alkylidene metathesis catalyst, an olefinic substrate comprised of at least one internal olefin with a cross metathesis partner comprised of an alpha olefinic reactant, under reaction conditions effective to allow cross-metathesis to occur, wherein the reaction conditions include a reaction temperature of at least 35° C. The methods, compositions, reactions and reaction systems herein disclosed have utility in the fields of catalysis, organic synthesis, and industrial chemistry.

专利号:WO-2008048522-A1
优先权日:2006-10-13
标 题:Methods of making monounsaturated functionalized alkene compounds by metathesis
发明人：ABRAHAM TIMOTHY W; KAIDO HIROKI; LEE CHOON WOO; PEDERSON RICHARD L; SCHRODI YANN; TUPY MICHAEL JOHN
权利人:CARGILL INC; MATERIA INC; ABRAHAM TIMOTHY W; KAIDO HIROKI; LEE CHOON WOO; PEDERSON RICHARD L; SCHRODI YANN; TUPY MICHAEL JOHN
摘要:Described is a method of chemically modifying a starting composition comprising polyunsaturated alkene compounds in order to convert at least a portion of the polyunsaturated alkene compounds into functionalized monounsaturated alkene compounds. The separated monounsaturated alkene compounds may be useful, for example, as a starting material in the synthesis of organic chemicals such as diacids, diesters, and the like.

专利号:US-2013035532-A1
优先权日:2006-10-13
标题 :Synthesis of terminal alkenes from internal alkenes via olefin metathesis

专利号:US-2010145086-A1
优先权日:2006-10-13
标 题:Synthesis of Terminal Alkenes From Internal Alkenes Via Olefin Metathesis

专利号:WO-2008046106-A2
优先权日:2006-10-13
标 题:Synthesis of terminal alkenes from internal alkenes via olefin metathesis

专利号:US-8501973-B2
优先权日:2006-10-13
标题 :Synthesis of terminal alkenes from internal alkenes via olefin metathesis