CAS: 492-70-6; 1,2-Diphenylethane-1,2-Diol

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CAS号451-40-1 二苯乙酮 | CAS号119-53-9 2-羟基-2-苯基苯乙酮 | CAS号947-91-1 二苯基乙醛 | CAS号100-52-7 苯甲醛 | CAS号4528-64-7 4,4-二苯基-2-环己烯-1-酮 | CAS号134-81-6 联苯甲酰 | CAS号65-85-0 苯甲酸 | CAS号34557-54-5 methane | CAS号64-19-7 冰醋酸 | CAS号3469-20-3 2,3-二苯基吲哚

📜联苯甲酰置于sodium Tetrahydroborate体系中,用 乙醇 作为反应溶剂,以78 %的收率获得产物氢化安息香
参考文献:用高价 Cu(Iii)-cf3 化合物和 Dmso 双重氧化环氧化物以反应生成 1,2-二酮
标题:用高价 Cu(Iii)-cf3 化合物和 Dmso 双重氧化环氧化物以反应生成 1,2-二酮
摘要:本研究报道了高价 Phencu(Iii)(Cf 3) 3和 Dmso 对 1,2-二芳基环氧化物进行连续脱氢和转移氧化,反应生成 1,2-二酮. Cu(Iii)-cf 3化合物作为cf 3自由基源来夺取环氧化物环的氢原子.所得的醚 α-碳自由基经历开环重排,得到酮 α-碳自由基中间体,该中间体被 Dmso 氧化并释放出 Me 2 S. Cu(Iii)-Cf 3化合物和 Dmso 的组合可以可用于开发其他新颖的氧化反应.
DOI:10.1021/acs.Joc.3C01160

专利信息

专利号:US-10801033-B2
优先权日:2016-04-05
标题 :Recombinant polynucleotide involved in lactone synthesis and process for synthesis of lactones thereof
发明人：GUPTA VIDYA SHRIKANT; DESHPANDE ASHISH BALWANT; OAK PRANJALI SUDHIR; GIRI ASHOK PRABHAKAR
权利人:COUNCIL SCIENT IND RES
摘要:The present invention provides the polynucleotide encoding enzyme involved in lactone synthesis and a process for synthesis of lactones using said polynucleotides. The invention also provides recombinant plasmid expression vector comprising said polynucleotide sequence. The recombinant protein encoded by said polynucleotides leads to synthesis of lactones having flavour peculiar to Alphonso mangoes.

专利号:US-9388131-B2
优先权日:2011-04-27
标题:Automated synthesis of small molecules using chiral, non-racemic boronates
发明人：BURKE MARTIN D; LI JUNQI; GILLIS ERIC P
权利人:UNIV ILLINOIS
摘要:Provided are methods for making and using chiral, non-racemic protected organoboronic acids, including pinene-derived iminodiacetic acid (PIDA) boronates, to direct and enable stereoselective synthesis of organic molecules. Also provided are methods for purifying PIDA boronates from solution. Also provided are methods for deprotection of boronic acids from their PIDA ligands. The purification and deprotection methods may be used in conjunction with methods for coupling or otherwise reacting boronic acids. Iterative cycles of deprotection, coupling, and purification can be performed to synthesize chiral, non-racemic compounds. The methods are suitable for use in an automated chemical synthesis process. Also provided is an automated small molecule synthesizer apparatus for performing automated stereoselective synthesis of chiral, non-racemic small molecules using iterative cycles of deprotection, coupling, and purification.

专利号:US-10669292-B2
优先权日:2014-05-05
标 题 :Synthesis of boronate salts and uses thereof
发明人：HECKER SCOTT; BOYER SERGE
权利人:REMPEX PHARMACEUTICALS INC
摘要:Disclosed herein are boronate intermediates in the synthesis of antimicrobial compounds and the use and preparation thereof. Some embodiments relate to crystalline boronate salt derivatives and their use in the synthesis of therapeutic compounds.

专利号:US-2005148781-A1
优先权日:2003-10-31
标题 :Process for the asymmetric synthesis of dihydrobenzoxathins
发明人：SONG ZHIGUO J; WATERS MARJORIE S
摘要:This invention relates to an asymmetric synthesis of sulfides via a chiral sulfoxide directed stereospecific reduction of α,β-unsaturated sulfoxide to the saturated sulfide. These sulfides can be useful as selective estrogen receptor modulators or anti-neoplastic agents.

专利号:US-9862745-B2
优先权日:2004-03-30
标题 :Synthesis of boronic ester and acid compounds
发明人：AMMOSCATO VINCE; BISHOP JOHN E; CHIU FANG-TING; GEISER ACHIM; GOMEZ JEAN-MARC; HETT ROBERT; KOELLNER CHRISTOPH; KULKARNI VITHALANAND R; LO YOUNG; MUNK STEPHEN; PICKERSGILL I FRASER
权利人:MILLENNIUM PHARM INC; MILLENNIUM PHARM INC
摘要:The invention relates to the synthesis of boronic ester and acid compounds. More particularly, the invention provides improved synthetic processes for the large-scale production of boronic ester and acid compounds, including the peptide boronic acid proteasome inhibitor bortezomib.

专利号:US-10487099-B2
优先权日:2017-06-30
标 题:Synthesis of hypervalent iodine reagents with dioxygen
发明人：POWERS DAVID CHARLES; MAITY ASIM; HYUN SUNG-MIN
权利人:TEXAS A & M UNIV SYS
摘要:Methods of synthesis of hypervalent iodine reagents and methods for oxidation of organic compounds are disclosed.