CAS: 195-64-2; Phenanthro[3,4-D][1,3]Dioxole

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    3,4-methylenedioxyphenanthrene-1-carboxylic acid d][1,3]dioxole-6-carboxylic acidphenanthro[3,4-d][1,3]dioxole-6-carboxylic acid N-(2-Bromobenzylidene)cyclohexylamine 2-Iodo-3,4-(methylendioxy)benzaldehyde cyclohexylimine

    合成工艺路线路线简述

      📜Phenanthro[3,4-D][1,3]Dioxole-6-Carboxylic Acid置于喹啉,铜体系中,化学反应生成6-甲基-2-硫代-2,3-二氢-4(1H)-嘧啶酮
      参考文献:Shirai; Oda,Yakugaku Zasshi/journal Of The Pharmaceutical Society Of Japan,1959,Vol. 79,P. 241,244
      标题:Shirai; Oda,Yakugaku Zasshi/journal Of The Pharmaceutical Society Of Japan,1959,Vol. 79,P. 241,244

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      ✅ COA系统入驻 | 共享模式

      主要参考文献

      参考标题:A Novel Strategy For The Synthesis Of Oxygenated Phenanthrenes Involving A Combination Of Ullmann And Mcmurry Reactions
      作者:Anne-Elisabeth Gies,Michel Pfeffer |发布日期:1999.5.1
      摘要:Preparation Of Polyoxygenated Phenanthrenes From Substituted Derivatives Of Benzaldehyde Is Described. The Key Compound Is A 6,6'-Biphenyl-1,1'-Dicarboxaldehyde Intermediate Formed Through An Ambient Temperature Ullmann Coupling. The Subsequent Mcmurry Condensation Gave Rise To The Phenanthrene In 45-57% Yields.

      合成参考文献

      参考DOI号:10.1021/jo982522r
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