四氯化铱 以 Solid 用作溶剂,化学反应生成四氯化铱 参考文献:Kamiya,Nobuyuki; Hoshino,Ken-Ichi; Ota,Ken-Ichiro,Nippon Kagaku Kaishi/journal Of The Chemical Society Of Japan 标题:Kamiya,Nobuyuki; Hoshino,Ken-Ichi; Ota,Ken-Ichiro,Nippon Kagaku Kaishi/journal Of The Chemical Society Of Japan
专利信息
专利号:US-2024424490-A1 优先权日:2021-01-25 标 题 :Method of synthesis of carbon-supported platinum group metal or metal alloy nanoparticles 发明人:WNUK PAWEL; LEWERA ADAM; JURCZAKOWSKI RAFAL; POWALA FILIP; KOLODZIEJCZYK JAN 权利人:UNIV WARSZAWSKI 摘要:The presented invention relates to a method of synthesis of carbon-supported platinum group metal or metal alloy nanoparticles, which comprises the following steps:n adsorbing on carbon support complexes of a platinum group metal with a urea complexing agent selected from a group comprising urea, urea derivative, a mixture of urea with at least one urea derivative, and a mixture of at least two urea derivatives; and reducing the complexes adsorbed on the carbon support to metal nanoparticles, forming a product of carbon-supported metal nanoparticles. nn The invention also provides the use of the carbon-supported platinum group metal or metal alloy nanoparticles obtained by the method of the invention as catalyst. n The present invention further relates to a method of adsorption of precursors of platinum group metals on the surface of a carbon support and use of complexes of platinum group metals with urea complexing agent for adsorption of platinum group metal precursors on carbon support.
专利号:US-6376423-B2 优先权日:1997-04-11 标 题 :Catalyst for preparation of synthesis gas and process for preparing carbon monoxide 发明人:YAGI FUYUKI; NAGUMO ATSURO; WADA YUKITAKA; SHIMURA MITSUNORI; ASAOKA SACHIO; WAKAMATSU SHUHEI 权利人:CHIYODA CHEM ENG CONSTRUCT CO 摘要:Disclosed are a catalyst for producing a synthesis gas using a carbon-containing organic compound as a raw material and a process for producing carbon monoxide. The catalyst for producing a synthesis gas is composed of a carrier formed of a metal oxide and at least one catalytic metal selected from rhodium, ruthenium, iridium, palladium and platinum and supported on the carrier and is characterized in that the catalyst has a specific surface area of 25 m 2 /g or less, in that the electronegativity of the metal ion of the carrier metal oxide is 13.0 or less and in that the amount of the supported catalytic metal is 0.0005-0.1 mole %, in terms of a metal, based on the carrier metal oxide. The process for producing carbon monoxide includes a step of reacting a carbon-containing organic compound with carbon dioxide in a pressurized condition to produce a synthesis gas, and a step of concentrating carbon monoxide in the thus obtained synthesis gas and is characterized in that the above-described catalyst is used as a catalyst in the synthesis gas producing step.
专利号:US-6340437-B1 优先权日:1997-04-11 标 题:Process for preparing synthesis gas by autothermal reforming 发明人:YAGI FUYUKI; NAGUMO ATSURO; WADA YUKITAKA; SHIMURA MITSUNORI; ASAOKA SACHIO; WAKAMATSU SHUHEI 权利人:CHIYODA CHEM ENG CONSTRUCT CO 摘要:Disclosed is a process for producing a synthesis gas by an autothermal reforming method including a step of partially oxidizing a carbon-containing organic compound to produce a high temperature mixed gas, and a synthesis producing step of reacting the unreacted carbon-containing organic compound contained in the high temperature mixed gas with carbon dioxide and/or steam, wherein a catalyst having a considerably suppressed carbon deposition activity is used as a catalyst for the synthesis gas producing step. The catalyst is characterized in that the catalyst comprises a carrier formed of a metal oxide, and at least one catalytic metal selected from rhodium, ruthenium, iridium, palladium and platinum and supported on the carrier, in that the catalyst has a specific surface area of 25 m 2 /g or less, in that metal ion of the carrier metal oxide has electronegativity of 13.0 or less, and in that the amount of the catalytic metal supported is 0.0005-0.1 mole %, in terms of a metal, based on the carrier metal oxide.
专利号:US-2024253022-A1 优先权日:2021-06-04 标 题 :Hydroxyapatite catalysts for isobutanol synthesis 发明人:LONG RICHARD; RUAN TIAN; SCHIPPER DESMOND; Havran Mueller Vesna 权利人:UOP LLC; CHINA PETROLEUM & CHEM CORP 摘要:Metal-doped hydroxyapatite catalysts for isobutanol and propanol synthesis have been developed which exhibit good isobutanol yield in propanol-methanol and ethanol-methanol reactions. The metal-doped hydroxyapatites include, but are not limited to, one or more of metal-doped Mg x PO y , Ca x PO y , Sr x PO y and Ba x PO y . The metal-doped hydroxyapatites may have different phosphorus to alkaline earth ratios. Methods for making isobutanol and propanol using the metal-doped hydroxyapatite catalysts are also provided.
专利号:WO-2022158990-A1 优先权日:2021-01-25 标 题 :Method of synthesis of carbon-supported platinum group metal or metal alloy nanoparticles
专利号:US-2025058379-A1 优先权日:2022-12-13 标 题 :Method of preparing iridium nanocrystal 发明人:WANG YANFEI; YU YINGLONG; SHAO CHENYI; LONG CHUAN; ZHAO QINFENG; WANG JINGJING; HE YEHENG; LI QINGXUN 权利人:PETROCHINA CO LTD 摘要:The present application provides a preparation method for iridium nanocrystal, including the following steps: mixing an iridium salt, an alcohol solvent and a centrifugal waste liquid to form a mixed solution, and adding an alkali solution in an inert atmosphere for a heating reaction. After centrifugation, an iridium nanocrystal is obtained. The centrifugal waste liquid is a waste liquid produced in the pre-synthesis process of iridium nanocrystal. The preparation method can shorten the reaction time, and the obtained iridium nanocrystal has the advantages of high yield and low cost.
摘要:Gigiena Truda i Professional'nye Zabolevaniya. Labor Hygiene and Occupational Diseases., 21(7)(55), 1977 摘要:Cotton FA, Wilkinson G; Advanced Inorganic Chemistry 5th ed NY, NY: John Wiley and Sons, p. 902 (1988)