CAS: 644-97-3; Dichlorophenylphosphine

上下游产品

CAS号638-21-1 苯基膦 | CAS号824-72-6 苯膦酰二氯 | CAS号4895-65-2 Tetrachloro(phe... | CAS号603-35-0 三苯基膦 | CAS号71-43-2 苯 | CAS号23588-02-5 ethyl phenylpho... | CAS号108-94-1 环己酮 | CAS号55045-25-5 phenyltrichloro... | CAS号587-85-9 二苯基汞 | CAS号603-33-8 三苯基铋 | CAS号112305-77-8 9-[ethoxy(pheny... | CAS号1005-21-6 trimethyl(pheny... | CAS号112305-74-5 9-[ethoxy(pheny... | CAS号111708-04-4 bis(methoxymeth... | CAS号1079-65-8 二苯基溴膦 | CAS号1006-83-3 2-phenyl-1,3,2-... | CAS号1089-77-6 乙基-1,2-二基二(苯基次磷酸) | CAS号1100-11-4 4-[[4-(dimethyl... | CAS号36802-41-2 双(2-甲氧基)苯基膦 | CAS号3497-00-5 苯基硫代膦酰二氯

氯苯置于磷化氢,三氯化磷体系中,70.0~350.0 °C,4.0 Mpa 条件下,反应 6.0H,以94.35%的收率获得产物苯基二氯化磷
参考文献:一种生产苯基二氯化磷的方法
标题:一种生产苯基二氯化磷的方法
摘要:本发明涉及一种生产苯基二氯化磷的方法.其技术方案是:以氯化苯,单质磷,三氯化磷为原料,采用在管式反应器中进行反应,制备了苯基二氯化磷,其反应方程式如下:P4 + 6C6H5Cl + 2Pcl=6C6H5Pcl.有益效果是:由于该法主反应在管式反应器中进行,不需使用催化剂,即可使物料按配比直接达到反应条件进行快速反应,缩短了生产周期,避免了大量副产物的反应生成;同时解决了以往利用高压釜进行高温高压反应所带来的安全隐患;且生产过程无废气,废渣,废水的反应生成,其操作简单,产品便于分离,产品纯度高;使用原料成本低,收率高,较现行工艺制备苯基二氯化磷具有较大的成本优势及环保优势.

专利信息

专利号:US-4756739-A
优先权日:1985-12-21
标题 :Pyridine derivatives and the N-oxides thereof, and the use thereof as intermediates for the synthesis of plant protecting agents
发明人：FUSS ANDREAS; KOCH VOLKER
权利人:HOECHST AG
摘要:The compounds of the formula I (I) in which A denotes N or N->O, Z denotes O or NH, R denotes H, (halo)alkyl, (halo)alkenyl, (halo)alkynyl or alkoxycarbonyl, R1 denotes hydrogen, halogen, amino, -NHOH, hydroxyl, (substituted) phenylazo or a radical of the formulae Y=C=N-, Y1Y2C=N-, Y3NH- or K denotes 0 or 1, and m and n, independently of one another, denote a number from 1 to 4, with the proviso that, when Z-R denotes OH or NH2, (R1)n denotes at least one radical of the formula or represents two radicals, in the 5 or 6 position of the heterocyclic ring, which, in the 5 position, denote halogen and, in the 6 position, denote a radical of the group comprising halogen, amino, hydroxyl or phenylazo, which may be substituted as specified above, are valuable intermediates in the synthesis of plant protection agents.

专利号:US-4985567-A
优先权日:1988-03-07
标题:Chiral phosphinopyrrolidine compounds and their use for asymmetric synthesis of optically active compounds
发明人：ACHIWA KAZUO; TAKEDA HIDEO
权利人:KAZUO ACHIWA; FUJI YAKUHIN KOGYO KK
摘要:New chiral phosphinopyrrolidine compounds of the general formula: ##STR1## wherein R 1 is hydrogen or --COA 1 , --COOA 2 , --CONHA 3 , --SO 2 A 4 or --PO(A 5 ) 2 , A 1 , A 2 , A 3 , A 4 and A 5 each represents independently alkyl or aryl, R 2 is phenyl, di(lower-alkyl)aminophenyl, lower-alkoxyphenyl or 3,5-dimethyl-4-methoxyphenyl, and R 3 is phenyl, lower-alkylphenyl, di(lower-alkyl)aminophenyl, lower-alkoxyphenyl or 3,5-dimethyl-4-methoxyphenyl, with the proviso that R 2 and R 3 may not simultaneously by phenyl, p-di(lower-alkyl)-aminophenyl or p-lower-alkoxyphenyl, as well as the use of these compounds as ligand for a metal complex catalyst for asymmetric synthesis of optically active compounds. The new chiral phosphinopyrrolidine compounds are useful ligands which attain both of high optical yield and high reaction efficiency in catalytic asymmetric reduction.

专利号:US-4096182-A
优先权日:1976-03-19
标 题:Process for the simultaneous preparation of 2,5-dioxo-1,2-oxa-phospholanes and β-halogenpropionic acid halide
发明人：RUPP WALTER; FINKE MANFRED
权利人:HOECHST AG
摘要:2,5-Dioxo-1,2-oxa-phospholanes of the formula (I) ##STR1## wherein R 1 is an organic radical and R 2 and R 3 each also represents an organic radical or hydrogen, are prepared by reacting 2-haloformylethyl-phosphinic acid halides of the formula (II) ##STR2## wherein R 1 , R 2 and R 3 are defined as in formula (I) and X means Cl or Br, preferably Cl, with an approximatey equimolar quantity of acrylic acid. The compounds (II) may also be produced in the reaction batch and in situ by reacting about equimolar quantities of a dihalophosphine of the formula (III) ##STR3## with an α,β-unsaturated acid (IV) n n R.sup.4 -- OH (IV) n n In the formulae (III) and (IV) R 1 , R 2 , R 3 and X are defined as indicated above. n In the reaction there is formed, in addition to the compounds (I), practically exclusively β-halopropionic acid and no free hydrogen halide. n The phospholanes (I) are valuable flame retarding agents for plastics, intermediates, for example, for the synthesis of biocidals etc.

专利号:US-12291489-B2
优先权日:2016-07-01
标 题 :Synthesis of nanocomposites and their use in enhancing plant nutrition
发明人：BISWAS PRATIM; RALIYA RAMESH
权利人:BISWAS PRATIM; RALIYA RAMESH; WASHINGTON UNIVERSITY ST LOUIS
摘要:The present disclosure is related to the development of improved fertilizer for precision and sustainable agriculture. A method was developed wherein efficient NPK nanocomposite for plant nutrition was synthesized in a single step using aerosol science and technology concepts. Further a formulation was prepared by addition of ZnO, TiO 2 and other nanoparticles to the NPK nanocomposite. Also, an aerosol based foliar application technique was developed for the precise delivery of nanoparticles to the plants.

专利号:US-4535144-A
优先权日:1983-01-28
标 题:Synthesis of high molecular weight polybenzimidazole with arylhalo phosphorus compound catalyst
发明人：CHOE EUI W; CONCIATORI ANTHONY B
权利人:CELANESE CORP
摘要:This invention provides a two stage melt polymerization process for the production of an improved type of high molecular weight polybenzimidazole, which involves the use of an arylhalophosphine or arylhalophosphite polymerization catalyst. The process provides poly-2,2'-(m-phenylene)-5,5'-bibenzimidazole of improved color and Plugging Value, and is further characterized by an inherent viscosity of at least about 1.0 dl/g, and a weight average molecular weight of at least about 100,000.

专利号:US-4533725-A
优先权日:1983-01-28
标题:Synthesis of high molecular weight polybenzimidazole with arylhalo phosphorus compound catalyst
发明人：CHOE EUI W; CONCIATORI ANTHONY B
权利人:DELANESE CORP
摘要:This invention provides a two stage melt polymerization process for the production of an improved type of high molecular weight polybenzimidazole, which involves the use of an arylhalophosphine or arylhalophosphite polymerization catalyst. The process provides poly-2,2'-(m-phenylene)-5,5'-bibenzimidazole of improved color and Plugging Value, and is further characterized by an inherent viscosity of at least about 1.0 dl/g, and weight average molecular weight of at least about 100,000.