CAS: 3582-72-7; Chloro-(Chloro-Methyl-Phenylsilyl)Oxy-Methyl-Phenylsilane
该化合物是一种氯化的二硅氧烷化合物,具有甲基和苯基替代成分;其分子结构,结合活氯原子与气动阻塞芳香和脂体组,使其成为有机硅化学的多功能中间体;该化合物因其能够进行受控水解和凝聚反应,能够合成量身定制的硅氧烷聚合物和功能性材料而特别受重视;其二氯功能允许进一步衍生,而苯基组则能提高有机基质的热稳定性和溶性;该产品通常用于硅酮特殊配方,表面改造和先进混合材料的前体.
物理性质
MSDS等安全信息
上下游产品
dichloromethylphenylsilane dimethyl sulfoxide 1,3-dimethyl-1,3-diphenyldisiloxane-1,3-diol 1,3,5,7-tetramethyl-1,3,5,7-tetraphenylcyclotetrasila-4,8-diaza-2,6-dioxane chloro-trimethyl-silane (R,R)-1,3-dimethyl-1,3-diphenyl-1,3-siloxanediol合成工艺路线路线简述
📜(S)-(-)-[(-)-Menthyloxy](4-Methoxy-1-Naphthyl)Methylphenylsilane置于氢氧化钾,一氯化碘体系中,用 氯仿,Xylene 用作溶剂,化学反应 17.0H,反应生成1,3-二氯-1,3-二甲基-1,3-二苯基二硅氧烷
参考文献:A Stereoselective Approach To Optically Active Bifunctional 1,3-Dimethyl-1,3-Diphenyldisiloxanes
标题:A Stereoselective Approach To Optically Active Bifunctional 1,3-Dimethyl-1,3-Diphenyldisiloxanes
摘要:[graphics]Functionalized Disiloxanes Have Attracted Much Attention As Versatile Synthetic Intermediates In The Preparation Of Disiloxane Containing Polymers. In This Report,A Highly Stereoselective (98% Inversion) Halogenating Cleavage Reaction Of The Silicon-Naphthyl Bond To Obtain Optically Active (S,S)-1,3-Dimethyl-1,3-Diphenyldisiloxanediol ((S,S):(R,S):(R,R) = 86:14:0) Was Demonstrated.
Doi:10.1021/ol990068N
海关参考信息
- 2902200000-苯
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📌 第三方产品分析报告
合成参考文献
参考文献:10.1007/bf00843946
摘要:Andrianov KA, Klimova MI, Khananashvili LM, Sipyagina MA. Condensation of α,ω-dihydroxypolydimethylsiloxane oligomers with 1,3-dimethyl-1,3-diphenyl-1,3-disiloxanediol diacetate. Russian Chemical Bulletin. 1963 Apr;12(4):583–5. doi: 10.1007/bf00843946.
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