CAS: 3582-72-7; Chloro-(Chloro-Methyl-Phenylsilyl)Oxy-Methyl-Phenylsilane

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dichloromethylphenylsilane dimethyl sulfoxide 1,3-dimethyl-1,3-diphenyldisiloxane-1,3-diol 1,3,5,7-tetramethyl-1,3,5,7-tetraphenylcyclotetrasila-4,8-diaza-2,6-dioxane chloro-trimethyl-silane (R,R)-1,3-dimethyl-1,3-diphenyl-1,3-siloxanediol

(S)-(-)-[(-)-Menthyloxy](4-Methoxy-1-Naphthyl)Methylphenylsilane置于氢氧化钾,一氯化碘体系中,用 氯仿,Xylene 用作溶剂,化学反应 17.0H,反应生成1,3-二氯-1,3-二甲基-1,3-二苯基二硅氧烷
参考文献:A Stereoselective Approach To Optically Active Bifunctional 1,3-Dimethyl-1,3-Diphenyldisiloxanes
标题:A Stereoselective Approach To Optically Active Bifunctional 1,3-Dimethyl-1,3-Diphenyldisiloxanes
摘要:[graphics]Functionalized Disiloxanes Have Attracted Much Attention As Versatile Synthetic Intermediates In The Preparation Of Disiloxane Containing Polymers. In This Report,A Highly Stereoselective (98% Inversion) Halogenating Cleavage Reaction Of The Silicon-Naphthyl Bond To Obtain Optically Active (S,S)-1,3-Dimethyl-1,3-Diphenyldisiloxanediol ((S,S):(R,S):(R,R) = 86:14:0) Was Demonstrated.
Doi:10.1021/ol990068N