
物理性质
- 熔点25°C
- 沸点397.8±52.0 °C at 760 mmHg
- 闪点194.4±30.7 °C
- 密度1.4±0.1 g/cm3
- PSA:85.66
- LogP:5.53
- 折射率1.580
- 蒸汽压0.0±0.9 mmHg at 25°C
- 溶解性0.07 Mg L -1 (20 °c)
- 外观形态液体
- 储存条件< 4°C
- 产品应用丙硫磷(34643-46-4)是一种不对称有机磷杀虫剂,具有广谱的生物活性,无内吸性.对按基甲酸酯和其他有机磷杀虫剂产生交抗的蚜类,粉蚧,蓟马,卷叶虫类和蠕虫类有良好效果,对多抗性品系的家蝇有较好的杀灭活性,对叶蝉科,盲蝽科和瓢虫科害虫弱效.对地下害虫的幼虫期有明显的活性,同时,它还被用于防治金针虫,地老虎和白蚁之类的重要地下害虫也有希望.乳油通常对水1000倍喷雾,蔬菜安全间隔期阴为21d,柑橘为45d.
- 性质描述丙硫磷(34643-46-4)的理化性质:其外观呈无色液体状,13.3Pa压力下沸点125~128°C,20°C蒸气压为0.3mPa,20°C密度1.31,在20°C水中溶解度为0.07mg/kg,在二氯甲烷,异丙醇,甲苯)200g/L.在缓冲溶液中DT50(22°C)120天(pH4),280天(pH7),12天(pH9).光解DT5013小时.闪点>110°C.毒性:急性经口LD50雄大鼠1569mg/kg,雌大鼠1390mg/kg,小鼠约2200mg//kg.急性经皮LD50(24小时)>5g/kg.对兔皮肤和眼睛无刺激.对皮肤有致敏作用.大鼠急性吸入LC50(4小时)>2.1/空气(气溶胶).两年饲喂试验无作用剂量为:大鼠5mg/kg饲料,小鼠1mg/kg饲料,狗0.4mg/kg饲料.对人的ADI为0.0001mg/kg体重.日本鹌鹑急性经口LD50为100~200mg/kg.鱼毒LC50(96小时):金色圆腹雅罗鱼为4~8mg/L(500g/LEC制剂);虹鳟0.5~1mg/L(500g/LEC制剂).如果在指导下应用对蜜蜂无毒害.水蚤LC50(48小时)为0.014mg/L.
欧盟法规
ECHA物质ECHA物质C&L通报REACH预注册上下游产品
O-ethyl-O-(2,4-dichlorophenyl)thiophosphor°Chloride sodium 1-propanethiolate ethanolEtafos 2,4-dichlorophenol 📜O-(2,4-二氯苯基)-O-乙基氯硫代磷酸酯,1-丙烷硫醇钠 以 乙腈,苯 作为反应溶剂,化学反应生成 丙硫磷
参考文献:O-Ethyl-S-Propyl-Dithiophosphoric Acid Phenyl Or Naphthyl Esters
标题:O-Ethyl-S-Propyl-Dithiophosphoric Acid Phenyl Or Naphthyl Esters
摘要:O-乙基-S-N-丙基-二硫代磷酸酯苯或萘酯,即o-乙基-S-N-丙基-O-或s-可选择取代的苯或萘-磷酰硫醚或二硫代醇酯,其化学式如下:X为氧或硫原子,Z为以下结构的基团:Y为卤素原子或较低的烷基,烷氧基,烷基硫醇基,烷基磺酰基,硝基,氰基或苯基,M为0,1,2或3,具有杀虫,杀螨和杀线虫作用.
海关参考信息
- 2903919090-氯苯
2908191000-对氯苯酚
2908999090-其他酚的硝化衍生物
2918290000-其他含酚基羧酸 - 💡 提示:海关信息按照顺序优先匹配,如需确认的海关信息,请参考相关资料。
- 详情请参考:📖 海关编码查询和海关进出口税则
专利信息
专利号:WO-2025056767-A1
优先权日:2023-09-15
标题 :Process for the preparation of enantiomerically enriched aliphatic amines
发明人:BOU HAMDAN FARHAN; GODINEAU EDOUARD; SMEJKAL TOMAS; DUMEUNIER RAPHAEL; BOUSSEMGHOUNE MOHAMED ABDELOUAHAB; BLUM MATHIAS
权利人:SYNGENTA CROP PROTECTION AG
摘要:The present invention relates to a process for the preparation of enantiomerically enriched cyclobutylamines of formula (I) from α-tertiary cyclobutanones and reacting said enantiomerically enriched cyclobutylamines to enantiomerically enriched cyclobutylamides. Such compounds are useful intermediates in the synthesis of microbiocidal thiazole compounds.
专利号:US-2007232495-A1
优先权日:2006-03-24
标题:Compositions and methods to add value to plant products, increasing the commercial quality, resistance to external factors and polyphenol content thereof
发明人:NAPPA ALVARO O; LORENZINI FELIPE C; SANHUEZA ANDRES L
权利人:NAPPA ALVARO O; LORENZINI FELIPE C; SANHUEZA ANDRES L
摘要:The invention is related to compositions and methods that naturally protect plant tissues against ultraviolet radiation and temperature, thus giving protection against sunburn to plants, plant parts, fruits and/or flowers during their development. The invention is also related to compositions and methods to naturally improve the color of plants, plant parts, fruits and/or flowers by inducing the natural synthesis of flavonoids and anthocyanins present in plants. Likewise, the present invention is directed to improving the nutritional value of plants, plant parts, fruits and/or flowers by increasing the normal levels of polyphenolic compounds, especially flavonoids, present therein. Additionally, the present invention is related to compositions and methods that give more resistance to plants, plant parts, fruits and/or flowers against pathogens as bacteria and fungi. Finally, the present invention is related to plants, plant parts, fruits, flowers and/or propagating material treated with the compositions described in the present document.
专利号:WO-2021074309-A1
优先权日:2019-10-16
标 题:1-(3-quinolyl)-3,4-dihydroisoquinoline derivatives as fungicides for combating specific phytopathogens
发明人:WEISS MATTHIAS; QUARANTA LAURA; BOU HAMDAN FARHAN; MAHAJAN ATUL; WILLIAMS SIMON; KILARU JAGADEESH; SEN INDIRA; BIERI STEPHANE; DIGGELMANN MARTIN
权利人:SYNGENTA CROP PROTECTION AG
摘要:1-(3-quinolyl)-3,4-dihydroisoquinoline derivatives of formula (I) as well as a method of combating, preventing or controlling the phytopathogens Mycosphaerella graminicola (Septoria tritici), Fusarium culmorum, Gibberella zeae (Fusarium graminearum) and Monographella nivalis (Microdochium nivale), which comprises applying to the phytopathogen, to the locus of the phytopathogen, or to a plant susceptible to attack by the phytopathogen, or to propagation material thereof, a fungicidally effective amount of a 1-(3-quinolyl)-3,4-dihydroisoquinoline derivative of formula (I). The present description discloses the synthesis of exemplary compounds, formulation examples, relevant biological data (antifungal activity against Mycosphaerella graminicola (Septoria tritici), Fusarium culmorum, Gibberella zeae (Fusarium graminearum) and Monographella nivalis (Microdochium nivale) when spayed on plants), as well as comparative data against three prior art compounds (e.g. pages 52 to 85; formulation examples; examples A1 to A3; table E; compounds E.01 to E.187; biological examples). Exemplary compounds are e.g.: 5-bromo-1-(8-fluoro-3-quinolyl)spiro[4H-isoquinoline-3,1'- cyclopropane] (example A1) 5-bromo-1-(8-fluoro-3-quinolyl)-3,3-dimethyl-4H-isoquinoline (example A2) 1-(8-fluoro-3-quinolyl)-3,3-dimethyl-4H-isoquinoline-5-carbonitrile (example A3)
专利号:WO-2021074311-A1
优先权日:2019-10-16
标题:1-(3-quinolyl)-1,2,3,4-tetrahydroisoquinoline derivatives as fungicides for combating specific phytopathogens
发明人:WEISS MATTHIAS; QUARANTA LAURA; BOU HAMDAN FARHAN; MAHAJAN ATUL; WILLIAMS SIMON; KILARU JAGADEESH; BIERI STEPHANE; DIGGELMANN MARTIN
权利人:SYNGENTA CROP PROTECTION AG
摘要:1-(3-quinolyl)-1,2,3,4-tetrahydroisoquinoline derivatives of formula (I) as well as a method of combating, preventing or controlling the phytopathogens Mycosphaerella graminicola (Septoria tritici), Fusarium culmorum, Gibberella zeae (Fusarium graminearum) and Monographella nivalis (Microdochium nivale), which comprises applying to the phytopathogen, to the locus of the phytopathogen, or to a plant susceptible to attack by the phytopathogen, or to propagation material thereof, a fungicidally effective amount of a 1-(3-quinolyl)-1,2,3,4-tetrahydroisoquinoline derivatives of formula (I). The present description discloses the synthesis of exemplary compounds, formulation examples, relevant biological data (antifungal activity against Mycosphaerella graminicola, Monographella nivalis, Fusarium culmorum and/or Gibberella zeae when spayed on plants) (e.g. pages 47 to 55; examples A1 and A2; compounds E.01 to E.17; table E). An exemplary compounds is e.g.: 3-(5-bromo-3,3-dimethyl-2,4-dihydro-1 H-isoquinolin-1-yl)-8-fluoro- quinoline (example A1)
专利号:US-2011230343-A1
优先权日:2008-10-24
标题 :Method for the Manufacture of Microparticles Comprising an Effect Substance
发明人:SCHROERS MICHAEL; DYLLICK-BRENZINGER RAINER; MERK MICHAEL; BARG HEIKO
权利人:BASF SE
摘要:A subject matter of the present invention is a process for the preparation of effect compound-comprising microparticles M comprising A) the formation of a crude suspension of microparticles A by means of enzymatic polyester synthesis in an inverse miniemulsion comprising enzyme, effect compound and polyester monomers; and B) the polymerization of wall monomers from the group consisting of ethylenically unsaturated monomers, polyisocyanates and polyepoxides in the crude suspension of microparticles A. Furthermore, the present invention relates to microparticles M which can be obtained by means of the process according to the invention and also to an agrochemical formulation comprising microparticles M. In addition, the present invention relates to the use of microparticles M prepared according to the invention as component in colorants, cosmetics, drugs, biocides, plant protection agents, fertilizers, additives for food or animal fodder, or auxiliaries for polymers, paper, textiles, leather, detergents or cleaners. Finally, the invention also relates to a method for combating undesirable plant growth, to a method for combating undesirable insect or acarid infestation on plants and/or for combating phytopathogenic fungi, and to seeds treated with the agrochemical formulation.
专利号:US-11213031-B2
优先权日:2017-11-13
标 题:Tetrazolylpropyl derivatives and their use as fungicides
发明人:SUDAU ALEXANDER; HOFFMANN SEBASTIAN; DAHMEN PETER; WEBSTER ROBERT ALAN; MEISSNER RUTH; GOERTZ ANDREAS; MILLER RICARDA; COQUERON PIERRE-YVES; BERNIER DAVID; NICOLAS LIONEL; BRUNET STEPHANE; KENNEL PHILIPPE; TOQUIN VALERIE; GOURGUES MATHIEU; LOQUE DOMINIQUE; THOMAS VINCENT
权利人:BAYER AG; BAYER CROPSCIENCE AG
摘要:The present invention relates to tetrazolylpropyl derivatives of formula (I) n nwherein one of V 1 and V 2 represents CR 3 and the other one of V 1 and V 2 represents N, Q represents a 6-membered aromatic cycle as defined in the specification, and R 1 , R 2 , R 3 , R 4 , and R 5 are defined as disclosed in the specification, to compositions comprising such compounds, to the use of said compounds as fungicides, as well as to particular intermediates useful in the synthesis of said tetrazolylpropyl derivatives.