CAS: 1121-66-0; Cyclohept-2-Enone

相似化合物

930-30-3 4096-38-2 1728-25-2

上下游产品

CAS号502-42-1 环庚酮 | CAS号79605-67-7 (+/-)-cyclohept... | CAS号502-41-0 环庚醇 | CAS号628-92-2 环庚烯 | CAS号1728-24-1 1,4-二噁螺[4.6]-6-十一烯 | CAS号14477-74-8 acetic acid,cyc... | CAS号22081-48-7 cyclohepten-1-y... | CAS号77256-26-9 2-iod°Cyclohept... | CAS号108168-72-5 3-propan-2-ylcy... | CAS号108062-25-5 3-(4-methoxyphe... | CAS号79605-67-7 (+/-)-cyclohept... | CAS号502-41-0 环庚醇 | CAS号502-42-1 环庚酮 | CAS号29798-82-1 2,4,6-Cyclohept... | CAS号532-24-1 托品酮 | CAS号100650-88-2 4-phenylcycloheptene | CAS号539-80-0 环庚三烯酮 | CAS号103130-97-8 3-butylcyclohep...

📜环庚烷置于2-碘苯磺酸钠,Oxone,氧气,四丁基硫酸氢铵,Palladium Diacetate,三乙胺,Sodium Iodide体系中,用 二甲基亚砜,乙腈 用作溶剂,化学反应 24.0H,反应生成2-环庚烯-1-酮
参考文献:在相转移条件下,以碘酮为末端氧化剂,邻碘苯磺酸钠催化的苄基和烷烃ch键的有效氧化†
标题:在相转移条件下,以碘酮为末端氧化剂,邻碘苯磺酸钠催化的苄基和烷烃ch键的有效氧化†
摘要:使用ibs作为催化剂,可以有效地实现苄基c-h键的催化氧化,而ibs是通过氧化而原位生成的.2-碘苯磺酸钠(1B)由环氧酮 在相转移催化剂的存在下,四正丁基铵 硫酸氢,在无水状态 乙腈在60oc下.各种烷基苯,包括甲苯和乙苯,几种氧含官能团的取代烷基苯和一个环状 苄醚可以被有效地氧化.并且,猫的试剂系统相同.1B /环氧酮/猫. 正丁基4 Nhso 4 也可用于烷烃的有效氧化.
Doi:10.1039/c0Ob00722F

专利信息

专利号:US-7910623-B2
优先权日:2005-07-22
标 题 :Synthesis of scabronines and analogues thereof
发明人：DANISHEFSKY SAMUEL J; WATERS STEPHEN P
权利人:SLOAN KETTERING INST CANCER
摘要:A novel synthesis of scabronines, which are related to a broader class of angularly fused tricyclic diterpenoids known as cyathanes, is provided. Scabronine G, its methyl ester derivative, and other analogs have been shown to have neurotrophic activity. Therefore, these compounds are particularly useful in treating neurodegenerative diseases such as Alzheimer's disease, Parkinson's disease, Huntington's diseases, etc. The invention provides for the synthesis of scabronines as well as analogs thereof. Pharmaceutical compositions and method of using the inventive compounds are also provided.

专利号:US-7964743-B2
优先权日:2005-02-17
标 题:Catalyst for asymmetric synthesis, ligand for use therein, and process for producing optically active compound through asymmetric synthesis reaction using them
发明人：MIYAURA NORIO; YAMAMOTO YASUNORI
权利人:JAPAN SCIENCE & TECH AGENCY
摘要:Compounds represented by the following general formula (1a) or (1b). n nA complex comprising a center metal of rhodium and a compound represented by the following general formula (1a) or (1b) as a ligand. A catalyst for optically active beta-substituted carbonyl compound synthesis and catalyst for asymmetric 1, 2 addition reaction being composed of the complex. A method of production of an optically active beta-aryl compound from an alpha, beta-unsaturated compound and an aryl-boronic acid derivative and method of production of an optically active aryl alcohol compound from an aldehyde compound and aryl boronic acid derivatives using the catalyst. A complex comprising a center metal of palladium and a compound represented by the following general formula (1a) or (1b) as a ligand. A catalyst for asymmetric allylic substitution reaction being composed of the complex. A method of production of an optically active dialkyl (1,3-disubstituted propeny)malonate compound from a 1,3-disubstituted ally acetate compound and a dialkyl malonate and method of production of an optically active allylamine compound from a 1,3-disubstituted ally acetate compound and an amine compound. The compounds have not only the versatility of being usable in the synthesis of wide-ranging optically active aryl compounds but also the selectivity and reactivity permitting synthesis with high yield within a short period of time under industrially advantageous mild conditions.

专利号:WO-2024105421-A1
优先权日:2022-11-17
标题 :SYNTHESIS OF α,β-UNSATURATED CARBONYLS FROM ALKENES VIA SULFONIUM INTERMEDIATES AND THEIR APPLICATION IN THE SYNTHESIS OF CONJUGATED DIENE PHEROMONES, KAIROMONES, AND RELATED COMPOUNDS
发明人：ANGYAL PÉTER; KOTSCHY ANDRÃ?S MIKLÓS; DUDÃ?S Ã?DÃ?M; SOÓS Tibor; VARGA SZILÃ?RD
权利人:TERMESZETTUDOMANYI KUTATOKOEZPONT; EOETVOES LORAND TUDOMANYEGYETEM
摘要:α,β-Unsaturated aldehydes are useful products as such in agrochemistry, but also potential intermediates for the preparation of important insect pheromones and kairomones. Until now, primarily the thermodynamically more stable (E)-α,β-unsaturated aldehydes have been identified as useful intermediates in the production of conjugated diene pheromone compounds, however, their practical and cost-effective synthesis on an industrial scale remains challenging. The problem to be solved by the present invention is to provide a method for selective oxidation of alkenes to α,β-unsaturated carbonyls which can be further transformed into pheromones and kairomones preferably without isolation and significant loss of the existing stereochemical purity.

专利号:US-2014296354-A1
优先权日:2013-04-01
标题 :Synthesis of peptoid-based small molecular gelators from multiple component reactions
发明人：WANG GUIJUN; MANGUNURU HARI P R
权利人:WANG GUIJUN; MANGUNURU HARI P R; OLD DOMINION UNIV RES FOUND
摘要:Described herein are the one-pot synthesis and characterization of a library of low molecular weight peptoid compounds that are able to form gels at room temperature. The compounds are synthesized from biologically-based starting materials, are biocompatible, and are resistant to degradation by proteases and peptidases. The compounds and gels synthesized therefrom can be used in such applications as tissue engineering, drug delivery, separation of biomolecules, and stimulus-responsive advanced materials

专利号:WO-2004096766-A1
优先权日:2003-04-29
标题 :A method of indole synthesis
发明人：BANWELL MARTIN GERHARDT; LUPTON DAVID WILLIAM
权利人:UNIV AUSTRALIAN; BANWELL MARTIN GERHARDT; LUPTON DAVID WILLIAM
摘要:The present invention relates to methods for the synthesis of indoles. In particular, the invention relates to the coupling of an a-haloenone or a-haloenal with an ortho-halonitroarene to form an ortho-(enone)nitroarene or ortho-(enal)nitroarene. Reductive cyclization of an ortho-(enone)nitroarene or ortho-(enal)nitroarene affords access to indole compounds.

专利号:US-5780603-A
优先权日:1996-11-15
标题:Combinatorial synthesis of carbohydrate libraries
发明人：HINDSGAUL OLE
权利人:SYNSORB BIOTECH INC
摘要:Disclosed are methods for synthesizing very large collections of diverse thiosaccaride derivatives optionally attached to a solid support. Also disclosed are libraries of diverse thiosaccaride derviatives.