CAS: 998-41-4; Tributylsilane

该化合物是一种该化合物是一种循环剂,有利于硅碳结质的形成.它与各种溶剂和试剂的兼容性增强了其在复杂的合成途径中的效用.此外,其相对较低的毒性和湿度敏感度有助于较安全的实验室处理,而不是替代的消毒剂.

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2929-52-4 18765-09-8 998-29-8

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    专利信息


    专利号:US-2004018598-A1
    优先权日:2000-05-30
    标题 :Bio-intermediates for use in the chemical synthesis of polyketides
    发明人:SANTI DANIEL; ASHLEY GARY; MYLES DAVID C
    摘要:The present invention relates to compounds made by a subset of modules from one or more polyketide synthase (“PKSâ€?) genes that are used as starting material in the chemical synthesis of novel molecules, particularly naturally occurring polyketides or derivatives thereof. The biologically derived intermediates (“bio-intermediatesâ€?) generally represent particularly difficult compounds to synthesize using traditional chemical approaches due to one or more stereocenters. In one aspect of the invention, an intermediate in the synthesis of epothilone is provided that feeds into the synthetic protocol of Danishefsky and co-workers. In another aspect of the invention, intermediates in the synthesis of discodermolide are provided that feed into the synthetic protocol of Smith and co-workers. By taking advantage of the inherent stereochemical specificity of biological processes, the syntheses of key intermediates and thus the overall syntheses of compounds like epothilone and discodermolide are greaty simplified.

    专利号:US-7339066-B1
    优先权日:2006-05-31
    标题 :Intermediates for the synthesis of polypropionate antibiotics
    发明人:PARKER KATHLYN; CAO HUANYAN
    权利人:UNIV NEW YORK STATE RES FOUND
    摘要:The invention relates to intermediate compounds of the formula n nwherein R 1 is H or a protecting group, R 2 and R 3 each independently represent H, methyl, or a leaving group, provided that at least one, but not both, of R 2 and R 3 is a leaving group. The intermediate compounds are useful for the synthesis of discodermolide, its derivatives, and related compounds.

    专利号:US-11554094-B2
    优先权日:2015-06-18
    标题 :Synthesis and application of microbubble-forming compounds
    发明人:MARX VANESSA M; GRUBBS ROBERT H
    权利人:CALIFORNIA INST OF TECHN
    摘要:The present disclosure is directed to fatty-acid glycerol ester derivative compounds containing a targeting bisphosphonate group. The disclosure further includes pharmaceutical or biomedical compositions comprising these compounds, and methods of using these compounds and compositions forming microbubbles. The microbubbles have affinity for metal-containing, especially calcium-containing, bodies and/or biological targets. In certain embodiments, these compositions are useful for providing targeted placement of microbubbles capable of cavitation on application of high frequency energy.

    专利号:US-7906682-B2
    优先权日:2000-08-31
    标题 :Synthesis of soluble functionalized lithium initiators
    发明人:HALASA ADEL FARHAN; HSU WEN-LIANG
    权利人:GOODYEAR TIRE & RUBBER
    摘要:This invention discloses a process for making dilithium initiators in high purity. This process can be conducted in the absence of amines which is desirable since amines can act as modifiers for anionic polymerizations. The dilithium compounds made are highly desirable because they are soluble in aromatic solvents. The present invention also discloses a tire which is comprised of a generally toroidal-shaped carcass with an outer circumferential tread, two spaced beads, at least one ply extending from bead to bead and sidewalls extending radially from and connecting said tread to said beads, wherein said tread is adapted to be ground-contacting, and wherein said tread is a cured the rubber formulation which is comprised of (a) at least one rubbery polymer containing functional groups of the structural formula: n nwherein R, R′ and R″ can be the same or different, wherein R is selected from the group consisting of hydrogen atoms, alkyl groups, aryl groups, alkaryl groups, and amino aryl groups, and wherein R′ and R″ represent alkyl groups alkyl groups that contain from 1 to 8 carbon atoms, and (b) at least one member selected from the group consisting of carbon black and silica.

    专利号:US-2021179545-A1
    优先权日:2019-03-15
    标题 :Compositions of oligoanilines and methods of making and using
    发明人:BUGARIN ALEJANDRO; YEPEZ GERARDO; NOONIKARA-POYIL ANURAG
    权利人:UNIV TEXAS
    摘要:Compositions of oligoanilines with higher purity, methods of making and using thereof, are provided. The compositions are produced in large scale with larger yield using simple purification techniques such as washing. Methods have been developed that allow large scale synthesis of oligoaniline compounds with the following benefits: (i) higher purity; (ii) larger yield of oligoaniline compounds; (iii) simple purification that does not require complicated techniques such as liquid chromatograph; (iv) lower cost; and (v) full characterization. The highly pure oligoaniline compositions can be used as reducing or oxidizing agent in a redox reaction. The oligoaniline compositions have colors and can be used as dyes, i.e. redox active dyes in a redox reaction, as intermediates for the development of conductive elastomers, or as catalysts.

    专利号:US-7833926-B2
    优先权日:2005-07-01
    标题 :Arylphenoxy catalyst system for producing ethylene homopolymer or copolymers of ethylene and α-olefins
    发明人:WOO TAE WOO; OK MYUNG AHN; HAHN JONG SOK; LEE MAL-OU; KANG SANG OOK; KO SUNG-BO; KIM TAE-JIN; KIM SUNG-KWAN
    权利人:SK ENERGY CO LTD
    摘要:The present invention relates to an arylphenoxy catalyst system producing an ethylene homopolymer or copolymers of ethylene and α-olefins, and a method of producing an ethylene homopolymer or copolymers of ethylene and α-olefins having a high molecular weight under a high temperature solution polymerization condition using the same. The catalyst system includes a group IV arylphenoxy-based transition metal catalyst and an aluminoxane cocatalyst or a boron compound cocatalyst. In the transition metal catalyst, a cyclopentadiene derivative and arylphenoxide as fixed ligands are located around the group IV transition metal, arylphenoxide is substituted with at least one aryl derivative and is located at the ortho position thereof, and the ligands are not crosslinked to each other. The catalyst includes an environmentally-friendly raw material, synthesis of the catalyst is economical, and thermal stability of the catalyst is excellent. It is useful for producing an ethylene homopolymer or copolymers of ethylene and α-olefins having various physical properties in commercial polymerization processes.

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    合成参考文献


    参考文献:10.1007/978-3-642-76937-5_2
    摘要:Sykové E. Ion-Selective Microelectrodes. 1992. In: Progress in Sensory Physiology.
    参考文献:10.1007/s004250050624
    摘要:Felle, Kondorosi, Kondorosi, Schultze. Nod factors modulate the concentration of cytosolic free calcium differently in growing and non-growing root hairs of Medicago sativa L. Planta. 1999 Aug 12;209(2):207–12. doi: 10.1007/s004250050624.
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