CAS: 850623-74-4; Potassium Trifluoro(2-(Hydroxymethyl)Phenyl)Borate
该化合物是一种有机体试剂,因其稳定性和再活性,经常用于铃木-米亚乌拉的交叉相交反应; 氢氧化硫组会提高极地溶剂溶性,便利同质反应条件; 作为三氟乙酸钾盐,它提供比碳酸更好的空气和水分稳定性,减少处理预防措施; 该化合物在制药和农用化学合成中特别有用,需要有选择地使芳香系统功能化; 其晶体形式确保了始终的纯度,使其成为复杂分子构造的可靠建筑块; 三氟乙酸混合物还尽量减少了分泌反应,提高了-催化变的产量.
- 英文名称Potassium Trifluoro(2-(Hydroxymethyl)Phenyl)Borate
- 中文名称(2-羟甲基苯基)三氟硼酸钾
- IUPAC名称potassium trifluoro(2-(hydroxymethyl)phenyl)borate
- 其它别名2-(羟甲基)苯基三氟硼酸钾; Potassium(2-Hydroxycmethylphenyl)Trifluoroborate
- CAS编号850623-74-4
- MFCD编号:MFCD04115769
- 分子式:C7H7BF3KO分子量:214.04
- 产品CID: 1843778
- 产品分类有机原料→分子砌块→芳环类化合物→苯类化合物
MSDS等安全信息
合成工艺路线路线简述
- 18982-54-2 = 850623-74-4
反应条件:1.1 Reagents: Tert-Butyllithium Solvents: Tetrahydrofuran,Hexane; -78 °C; 3 H,-78 °C1.2 Reagents: Triisopropyl Borate; -78 °C; 30 Min,-30 °C1.3 Reagents: Potassium Bifluoride Solvents: Water; Heated; 30 Min,Rt
标题:A Facile One-Pot Preparation Of Potassium Hydroxyaryl- And (Hydroxyalkyl)Aryltrifluoroborates
作者:Park,Young Hee; Ahn,Hong Ryul; Canturk,Belgin; Jeon,Sang Il; Lee,Seokjoon; Et Al
参考文献:Organic Letters 日期:2008 卷标:10(6) 页码:1215-1218
海关参考信息
- 2902300000-甲苯
2905110000-甲醇
2906210000-苄醇 - 💡 提示：海关信息按照顺序优先匹配，如需确认的海关信息，请参考相关资料。
- 详情请参考：📖 海关编码查询和海关进出口税则
专利信息
专利号:US-8513465-B2
优先权日:2008-02-04
标题:Potassium organotrifluoroborate derivative and a production method therefor
发明人：KANG HEONJOONG; HAM JUNGYEOB; AHN HONG RYUL; PARK YOUNG HEE
权利人:KANG HEONJOONG; HAM JUNGYEOB; AHN HONG RYUL; PARK YOUNG HEE; SNU R&DB FOUNDATION
摘要:Provided are a production method for a potassium organotrifluoroborate compound having a hydroxyl group, and a novel potassium organotrifluoroborate compound having a hydroxyl group. The production method is advantageous in that a potassium organotrifluoroborate compound can be produced in a single reaction without recourse to a process of isolating and purifying an intermediate. The novel potassium organotrifluoroborate compound having a hydroxyl group is useful as a reactant which is widely used in the total synthesis of physiologically active natural products and diverse organic synthesis reactions including halogen substitution reactions, 1,2- and 1,4-addition reactions using a rhodium (Rh) catalyst, and Suzuki coupling reactions using a palladium (Pd) catalyst.
供应商参考报价(招募中)
品牌试剂参考报价(招募中)
📌 第三方产品分析报告
合成参考文献
参考文献:10.1055/s-2008-1072781
摘要:One-Pot Preparation of Hydroxyaryl- and (Hydroxyalkyl)aryltrifluoroborates. Synfacts. 2008 May 21;2008(06):0625. doi: 10.1055/s-2008-1072781.
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