CAS: 63126-52-3; (2S,3S)-2,3-Dihydroxy-N1,N1,N4,N4-Tetramethylsuccinamide

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CAS号161344-84-9 2-丁基-1,3,2-二氧硼戊...

📜N,N,N',N'-Tetramethylfumarsaeurediamid置于potassium Osmate(Vi) Dihydrate,水,N-甲基吗啉氧化物,柠檬酸体系中,用 叔丁醇 作为反应溶剂,化学反应 72.0H,以10%的收率获得产物四甲基酒石酸胺
参考文献:Development Of An Organo-And Enzyme-Catalysed One-Pot,Sequential Three-Component Reaction
标题:Development Of An Organo-And Enzyme-Catalysed One-Pot,Sequential Three-Component Reaction
摘要:A One-Pot,Three-Component Process Is Described Which Involves Both Organo-And Enzyme-Catalysed Carbon-Carbon Bond-Forming Steps. In The First Step,An Organocatalyst Catalyses The Aldol Reaction Between Acetaldehyde And A Glyoxylamide. After Dilution With Additional Aqueous Buffer,And Addition Of Pyruvate And An Aldolase Enzyme Variant,A Second Aldol Reaction occurs To Yield A Final Product. Crucially,It Was Possible To Develop A Reaction In Which Both The Organo-And Enzyme-Catalysed Reactions Could Be Performed In The Same Aqueous Buffer System. The Reaction Described Is The First Example Of A One-Pot,Three-Component Reaction In Which The Two Carbon-Carbon Bond-Forming Processes Are Catalysed Using The Combination Of An Organocatalyst And An Enzyme. (C) 2012 Elsevier Ltd. All Rights Reserved.
DOI:10.1016/j.Tet.2012.02.010