CAS: 205-82-3; Benzo[j]Fluoranthene

该化合物是一种该化合物是一种由五个苯环组成的引信环系统,具有典型的芳香特性,该化合物主要用于研究和分析化学,因其作为燃烧过程中的污染物而成为环境和毒理学研究的参考标准,其明确的结构和稳定性使它适合用于色谱学和光谱测量,作为校准标码. 本佐[j]氟芳烃还研究其诱变和致癌潜力,作为毒理学的一个模型化合物,以了解与PAH有关的健康风险.适当处理由于其危险性质至关重要.

结构式图片

欧盟法规

[欧盟限制物质清单

上下游产品

苯并[k]荧蒽 Benzo[k]Fluoranthene 207-08-9
Benzo[j]Fluoranthen-1-Ol 62393-33-3
1,2?-联萘 1-(Naphthalen-2-yl)Naphthalene 4325-74-0
1,1'-联萘 1,1'-Binaphthyl 604-53-5

合成工艺路线路线简述

    📜1-苊酮置于四氢呋喃,吡啶,四(三苯基膦)钯,三溴化磷,四氯化钛,Potassium Carbonate,锌体系中,用 1,4-二氧六环,氯仿,水 用作溶剂,化学反应 20.0H,反应生成苯并[j]荧蒽
    参考文献:天然产物苯并[ J ]荧蒽-4,9-二醇的全合成:氧化苯并[ J ]荧蒽的合成方法
    标题:天然产物苯并[ J ]荧蒽-4,9-二醇的全合成:氧化苯并[ J ]荧蒽的合成方法
    摘要:描述了苯并[ J ]荧蒽原子核的合成序列.该过程的关键步骤包括在适当取代的2-溴-Ena基-1-甲醛与2-甲酰基苯硼酸酯之间进行suzuki偶联,然后进行mcmurry闭环.该合成代表了苯并[ J ]荧蒽环系统的一种新方法,并特别提供了一种快速制备不同取代的衍生物的方法.按照这一策略,对最近分离出的天然产物苯并[ J ]荧蒽-4,9-二醇进行了首次全合成.
    Doi:10.1021/jo401887T

    海关参考信息

    专利信息


    专利号:US-2003162992-A1
    优先权日:2001-12-14
    标 题 :Preparation of intermediates useful in the synthesis of antiviral nucleosides
    发明人:WATANABE KYOICHI A; DU JINFA
    摘要:The present invention is an efficient process for the manufacture of α-acyloxyacetaldehyde, a key intermediate in the synthesis of 1,3-oxathiolane and 1,3-dioxolane nucleosides.

    专利号:US-9469603-B2
    优先权日:2012-03-12
    标 题 :Reaction product of hydrazine derivatives and carbon dioxide
    发明人:HUR NAM HWI; LEE BYEONG NO
    权利人:UNIV SOGANG RES FOUNDATION
    摘要:The present invention relates to the synthesis of a novel compound, in which liquid hydrazine and the derivatives thereof react with excess carbon dioxide to enable the carbon dioxide to chemically bond to the hydrazine and the derivatives thereof. To this end, high-pressure carbon dioxide is used to synthesize hydrazine and the derivatives thereof to which the carbon dioxide is bonded in a pure form with no water and no by-product. Furthermore, the present invention provides a method for utilizing the above-described compounds by reacting the compounds with carbonyl compounds.

    专利号:WO-2021129102-A1
    优先权日:2019-12-27
    标 题 :Heterocyclic compound, synthesis method therefor, organic electroluminescent device and electronic apparatus
    发明人:WANG JINPING; XUE ZHEN; CHEN ZHIWEI
    权利人:SHAANXI LIGHTE OPTOELECTRONICS MAT CO LTD
    摘要:Disclosed are a heterocyclic compound, a synthesis method therefor, an organic electroluminescent device and an electronic apparatus. The heterocyclic compound has a chemical structural formula as shown in formula 1, wherein M is selected from the groups shown in formula 1-A. The compound can improve the properties of the organic electroluminescent device.

    专利号:WO-2008127396-A2
    优先权日:2006-11-02
    标 题 :A solution synthesis of carbon nanotube/metal-containing nanoparticle conjugated assemblies

    专利号:US-9023308-B2
    优先权日:2011-03-15
    标题:Facile synthesis of graphene, graphene derivatives and abrasive nanoparticles and their various uses, including as tribologically-beneficial lubricant additives

    专利号:US-2007069198-A1
    优先权日:2003-09-29
    标题:Synthesis of phenyl-substituted fluoranthenes by a diesel-alder reaction and the use thereof

    供应商参考报价(招募中)

    品牌试剂参考报价(招募中)

    📌 第三方产品分析报告

    ✅ COA系统入驻 | 共享模式

    合成参考文献


    摘要:Suna, E.; Shubin, K., Science of Synthesis: Cross Coupling and Heck-Type Reactions, (2012) 3, 715.
    摘要:Hopia A et al; JAOCS 63: 889-93 (1986)
    摘要:Malins DC et al; Carcinogenesis 6: 1463-9 (1985)
    摘要:American Conference of Governmental Industrial Hygienists TLVs and BEIs. Threshold Limit Values for Chemical Substances and Physical Agents and Biological Exposure Indices. Cincinnati, OH 2016, p. 118
    摘要:Otson R et al; pp. 667-85 in Polynucl Aromat Hydrocarbons: Meas, Means, and Metabolism, Int Symp, 11th, Cooke M et al, eds, Columbus, OH: Battelle Press: (1991)
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