CAS: 12020-65-4; Sulfanylideneeuropium

该化合物是一种无机化合物,由铀和硫组成,具有独特的特性和应用特征,通常看起来像是灰色的黑固体,以其半导体行为著称,在各种电子应用中具有价值.EuS展示了面向立方晶体结构,在室温下具有共磁性,在较低温度下过渡到铁磁状态.该化合物在水中溶解,但可与酸反应以释放硫化氢气.硫化铀还因其发光特性而引人注目,特别是在紫外线光下,用于磷应用.此外,由于磁性特性,它有可能用于脊椎装置.处理EuS需要谨慎行事,因为如果浸入或吸入,可能会有危险,因此应采取适当的安全措施来尽量减少接触.

结构式图片

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上下游产品

hydrogen sulfide europium(III) chloride carbon disulfide diethylammonium diethyldithi°Carbamatedisulfur sulfur 1.9EuS1.9

合成工艺路线路线简述

    专利信息


    专利号:US-8541571-B2
    优先权日:2008-03-03
    标题:Homogeneous synthesis of cellulose ethers in ionic liquids
    发明人:MOELLMANN EUGEN; HEINZE THOMAS; LIEBERT TIM; KOEHLER SARAH
    权利人:MOELLMANN EUGEN; HEINZE THOMAS; LIEBERT TIM; KOEHLER SARAH; SE TYLOSE GMBH & CO KG
    摘要:The invention is directed to a simple and new method for the homogeneous synthesis of cellulose ethers. Ionic liquids are not only used as solvent, but also as reaction media for the homogeneous etherification of cellulose. The dissolved cellulose is treated with the etherification agent in the absence of organic and/or inorganic bases and in the absence and/or in the presence of moderate amounts of water. The obtained cellulose ethers show new distributions of substitution on the polymer chain, resulting in new properties and applications.

    专利号:US-2010191010-A1
    优先权日:2007-07-02
    标题 :Process for the synthesis of carbamates using co2
    发明人:BOSMAN JORIS KAREL PETER; CARR ROBERT HENRY
    权利人:HUNTSMAN INT LLC
    摘要:Process for the synthesis of non cyclic carbamate derivatives from amine compounds, alcohols and CO 2 in the presence of ionic liquids and optionally in the presence of a base.

    专利号:US-2007100184-A1
    优先权日:2005-10-27
    标题 :Alkylation of aromatic compounds
    发明人:HARMER MARK A; JUNK CHRISTOPHER P; VICKERY JEMMA
    权利人:HARMER MARK A; JUNK CHRISTOPHER P; VICKERY JEMMA
    摘要:The present invention relates to the synthesis of alkylated aromatic compounds using ionic liquids as the solvent. Alkylated aromatic compounds are synthesized by reacting an aromatic compound with a monoolefin in the presence of an acid catalyst.

    专利号:US-11760707-B2
    优先权日:2019-11-13
    标题 :Process for the synthesis of 2,3,3,3-tetrafluoropropene
    发明人:ZHOU CHANGYUE; WANG YONG
    权利人:FUJIAN YONGJING TECH CO LTD
    摘要:The present invention pertains to a novel process of manufacturing the compound 2,3,3,3-tetrafluoropropene (1234yf). The compound 1234yf is the newest refrigerant with zero OPD (Ozone Depleting Potential) and zero GWP (Global Warming Potential). Thus, the invention relates to a process, involving a carbene generation route, for the manufacture of the compound 2,3,3,3-tetrafluoropropene (1234yf), of the compound 243db (2,3-dichloro-1,1,1-trifluoropropane), and optionally of the compound 2-chloro-1,1,1-trifluoropropene (1233xf) via carbene route and compound 243db (2,3-dichloro-1,1,1-trifluoropropane). The invention also relates to a process for the manufacture of the compound 2,3,3,3-tetrafluoropropene (1234yf), wherein the compound 243db (2,3-dichloro-1,1,1-trifluoropropane) serves as a starting material, for the manufacture of the compound 2,3,3,3-tetrafluoropropene (1234yf). Further, the invention relates to a process for the manufacture of the compound 2,3,3,3-tetrafluoropropene (1234yf), and of the compound 243db (2,3-dichloro-1,1,1-trifluoropropane), the initial starting materials are selected from the group consisting of com-pound 123 (2,2-dichloro-1,1,1-trifluoroethane), compound 124 (2-chloro-1,1,1,2-tetrafluoroethane), and compound 125 (pentafluoroethane).

    专利号:WO-2012065002-A1
    优先权日:2010-11-10
    标题:Synthesis of lactic acid and alkyl lactate from carbohydrate-containing materials

    专利号:EP-2098539-B1
    优先权日:2008-03-03
    标 题:Homogeneous synthesis of cellulose ethers in ionic liquids
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    合成参考文献


    参考文献:10.1007/bf00795076
    摘要:Gordienko SP. Composition of the vapor and the energy characteristics of vaporization of rare-earth metal monochalcogenides and monopnyctides. Powder Metallurgy and Metal Ceramics. 1991 Jun;30(6):497–500. doi: 10.1007/bf00795076.
    参考文献:10.1007/s11237-016-9437-y
    摘要:Selishchev AV, Pavlishchuk VV. Luminescence and Spectral Characteristics of Zinc Sulfide Nanoparticles Doped with Eu2+. Theoretical and Experimental Chemistry. 2016 Jan;51(6):366–74. doi: 10.1007/s11237-016-9437-y.
    参考文献:10.1134/s0036023609100027
    摘要:Ignat’eva NI, Shkvarin AS, Osotov VI, Finkel’shtein LD. Europium valence state in europium monoxide-iron (Cobalt) magnetic composites. Russian Journal of Inorganic Chemistry. 2009 Oct 13;54(10):1517. doi: 10.1134/s0036023609100027.
    参考文献:10.1007/bf02166645
    摘要:Amano R, Shiokawa Y. Preparation of lanthanide sulfide films by chemical vapor deposition using β-diketone chelates. Journal of Radioanalytical and Nuclear Chemistry Letters. 1991 Oct;155(3):201–10. doi: 10.1007/bf02166645.
    参考文献:10.1007/bf02100955
    摘要:Bibliography section. Journal of Thermal Analysis and Calorimetry. 1972 Jun;4(1):95–111. doi: 10.1007/bf02100955.
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