CAS: 940-06-7; 3,5-Dinitropyridine

该化合物是一种硝酸pyridine衍生物,其特征是,在环的3和5个位置上存在两个硝基组,该化合物主要用作有机合成的中间体,特别是用于制备药品,农用化学品和高能材料,其高反应性和电衰竭性使它成为核生殖性替代反应的宝贵建筑块.对称替代模式加强了合成应用的稳定性和可预测性. 3,5-二硝基丙烯也具有对材料科学的兴趣,因为它有可能用于开发高能量密度化合物. 妥善处理由于其潜在的爆炸性,是至关重要的.

结构式图片

相似化合物

934-59-8 4318-78-9 1220040-21-0

物理性质

MSDS等安全信息

上下游产品

CAS号2578-45-2 2-氯-3,5-二硝基吡啶 | CAS号5418-51-9 2-羟基-5-硝基吡啶 | CAS号2980-33-8 2-羟基-3,5-二硝基吡啶 | CAS号13250-43-6 3,5-dinitro-pyr... | CAS号55106-97-3 N,N'-bis-(3,5-d... | CAS号10425-70-4 4-氯-3,5-二硝基吡啶 | CAS号4318-78-9 吡啶-3,5-二胺

合成工艺路线路线简述

  • 13250-43-6 = 940-06-7
    反应条件:1.1 Reagents: Silver Nitrate Solvents: Water; Rt -> 80 °C; 1 - 2 H,80 °C
    标题:Reactions Of 3-R-5-Nitropyridines With Nucleophiles: Nucleophilic Substitution Vs Conjugate Addition
    作者:Bastrakov,Maxim A.; Nikol'Skiy,Vladislav V.; Starosotnikov,Alexey M.; Fedyanin,Ivan V.; Shevelev,Svyatoslav A.; Et Al
    参考文献:Tetrahedron 日期:2019 卷标:75(47)]

    13250-43-6 = 940-06-7
    反应条件:1.1 Reagents: Silver Acetate Solvents: Methanol,Water; Overnight,Reflux
    标题:Preparation Of 3-(Heterocyclylmethoxy)Pyridines As Nicotinic Cholinergic Agonists
    参考文献:United States]

    13250-43-6 = 940-06-7
    反应条件:1.1 Reagents: Silver Acetate Solvents: Methanol,Water; Overnight,Reflux
    标题:Preparation Of Heterocyclic Ethers As Neuronal Nicotinic Receptor Ligands
    参考文献:World Intellectual Property Organization]

    = 940-06-7
    反应条件:1.1 Reagents: Nitrogen Dioxide
    标题:Ozone-Mediated C-Nitration Of Pyridine And Methylpyridines With Nitrogen Dioxide
    作者:Suzuki,Hitomi; Kozai,Iku; Murashima,Takashi
    参考文献:Journal Of Chemical Research 日期:1993 卷标:(4) 页码:156-7]

    13250-43-6 = 940-06-7
    反应条件:1.1 Reagents: Acetic Acid,Silver Salt Solvents: Water
    标题:Synthesis Of 3,5-Dinitropyridine
    作者:Plazek,Edwin
    参考文献:Recueil Des Travaux Chimiques Des Pays-Bas Et De La Belgique 日期:1953 卷标:72 页码:569-75]

    2578-45-2 = 940-06-7
    反应条件:1.1 Reagents: Hydrazine Solvents: Dichloromethane; 0 °C; 18 H,Rt1.2 Reagents: Silver Nitrate Solvents: Water; 3 H,Reflux; Reflux -> Rt1.3 Solvents: Tert-Butyl Methyl Ether; Rt
    标题:3,5-Pyridyne-A Heterocyclic Meta-Benzyne Derivative
    作者:Winkler,Michael; Cakir,Bayram; Sander,Wolfram
    参考文献:Journal Of The American Chemical Society 日期:2004 卷标:126(19) 页码:6135-6149]

    13250-43-6 = 940-06-7
    反应条件:1.1 Reagents: Silver Nitrate Solvents: Water; Rt; Rt -> Reflux; 5 H,Reflux
    标题:Electron-Deficient Heteroarenium Salts: An Organocatalytic Tool For Activation Of Hydrogen Peroxide In Oxidations
    作者:Sturala,Jiri; Bohacova,Sona; Chudoba,Josef; Metelkova,Radka; Cibulka,Radek
    参考文献:Journal Of Organic Chemistry 日期:2015 卷标:80(5) 页码:2676-2699]

    2578-45-2 = 940-06-7
    反应条件:1.1 Reagents: Hydrazine Hydrate (1:1) Solvents: Methanol; 10 Min,0 °C; Overnight,Rt1.2 Reagents: Silver Acetate Solvents: Water; 3 H,Reflux1.3 Reagents: Sodium Hydroxide Solvents: Water; Ph 9,Reflux -> Rt
    标题:Lewis Acidic Boranes,Lewis Bases,And Equilibrium Constants: A Reliable Scaffold For A Quantitative Lewis Acidity/basicity Scale
    作者:Mayer,Robert J.; Hampel,Nathalie; Ofial,Armin R.
    参考文献:Chemistry - A European Journal 日期:2021 卷标:27(12) 页码:4070-4080]

    14080-32-1 = 940-06-7 [标题:Reaction Conditions
    标题:Product Class 1: Pyridines
    作者:Spitzner,D.
    参考文献:Science Of Synthesis 日期:2005 卷标:15 页码:11-284]

    = 940-06-7 [标题:Reaction Conditions
    标题:Thermal Decomposition Pathways Of 1,3,3-Trinitroazetidine (Tnaz),Related 3,3-Dinitroazetidium Salts,And 15N,13C,And 2H Isotopomers
    作者:Oxley,Jimmie; Smith,James; Zheng,Weiyi; Rogers,Evan; Coburn,Michael
    参考文献:Journal Of Physical Chemistry A 日期:1997 卷标:101(24) 页码:4375-4383]

    = 940-06-7 [标题:Reaction Conditions
    标题:Preparation Of 2-(3-Pyridyloxyalkyl)Azetidines And -Pyrrolidines As Nicotinic Receptor Ligands
    参考文献:World Intellectual Property Organization]

    = 940-06-7 [标题:Reaction Conditions
    标题:Mineral Acid-Free Preparation Of Nitro Compounds From Pyridine Or Its Derivatives
    参考文献:Japan]

    = 940-06-7 [标题:Reaction Conditions
    标题:Pyrimidines. Lxiv. Ring Transformations In Reactions Of Heterocyclic Compounds With Nucleophiles. Xx. Conversion Of 5-Nitropyrimidine Into 3,5-Dinitropyridine. A Novel Ring Transformation
    作者:Van Der Plas,H. C.; Jongejan,H.; Koudijs,A.
    参考文献:Journal Of Heterocyclic Chemistry 日期:1978 卷标:15(3) 页码:485-7]

    100-52-7 + 181294-58-6 = 940-06-7 + 1845711-80-9
    反应条件:1.1 Reagents: P-Toluenesulfonic Acid Solvents: Ethanol; 20 H,80 °C
    标题:Construction Of 3,5-Dinitrated 1,4-Dihydropyridines Modifiable At 1,4-Positions By A Reaction Of β-Formyl-β-Nitroenamines With Aldehydes
    作者:Asahara,Haruyasu; Hamada,Mai; Nakaike,Yumi; Nishiwaki,Nagatoshi
    参考文献:Rsc Advances 日期:2015 卷标:5(110) 页码:90778-90784
📜2-羟基-5-硝基吡啶置于乙醇,五氯化磷,硫酸,三氧化硫,水,硝酸,Silver(I) Acetate,一水合肼,三氯氧磷体系中,化学反应 2.0H,反应生成 3,5-二硝基吡啶
参考文献:Plazek,Recueil Des Travaux Chimiques Des Pays-Bas,1953,Vol. 72,P. 569,573
标题:Plazek,Recueil Des Travaux Chimiques Des Pays-Bas,1953,Vol. 72,P. 569,573

海关参考信息

专利信息


专利号:CN-111556872-A
优先权日:2017-11-01
标题 :Synthesis of boronic ester derivatives and uses thereof

专利号:JP-2011505360-A
优先权日:2007-11-27
标 题 :Synthesis of diaminodinitropyridine and diaminodinitrobenzene.

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合成参考文献


摘要:Spitzner, D., Science of Synthesis, (2005) 15, 124.
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