CAS: 312619-41-3; Iron(Iii) 4-Methylbenzenesulfonate Hexahydrate

该化合物是一种协调化合物,其特点是,在+3氧化状态下存在铁,与聚二苯乙烯硫酸离心和六水分子相协调,作为水化.该化合物一般是一种固体,由于含铁成分,通常呈现红褐色;由于六氢酸盐形式的水利生物性质,极地溶解剂特别是水是可溶性的. P-甲酸盐离心管有助于化合物的稳定性和溶解性,而六氢酸盐形式表明,它在某些条件下释放水分子.铁(III) P-甲酸盐六氢酸盐在各种应用中被使用,包括催化和有机合成中的试剂.其特性,例如热稳定性和反应性,可能受到全氟辛烷磺酸组的存在和水化状态的影响.在处理该化合物时,应当注意安全防范,因为如果受到污染,可能会对健康构成风险.

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    专利信息


    专利号:US-8815343-B2
    优先权日:2007-07-09
    标 题 :Highly conductive and stable transparent conducting polymer films
    发明人:CHEN LICHUN; BRADLEY DONAL DONAT CONOR
    权利人:CHEN LICHUN; BRADLEY DONAL DONAT CONOR; IMP INNOVATION LTD
    摘要:The invention relates to a process for the synthesis of conducting polymer films by vapor phase polymerization. The invention relates particularly to the synthesis of polymerized thiophene films, for example poly(3,4-ethylenedioxythiophene) (PEDOT) films.

    专利号:WO-2023095555-A1
    优先权日:2021-11-25
    标题:Method for producing (meth)acryloyl group-containing organopolysiloxane
    发明人:TSUCHIDA OSAMU; SHIRAKAMI Kento
    权利人:SHINETSU CHEMICAL CO
    摘要:[Problem] The present invention provides a novel synthesis technique by applying esterification that does not use protonic acid to a silicon-containing compound such as an organopolysiloxane. The purpose of the present invention is to provide a method for producing, through a novel esterification method, an organopolysiloxane that contains a (meth)acryloyl group. [Solution] A method for producing a (meth)acryloyl group-containing organopolysiloxane, the method being characterized by including a step for obtaining the (meth)acryloyl group-containing organopolysiloxane by causing a reaction between (A) a hydroxyl group-containing organopolysiloxane represented by average formula (1) [Chemical Formula 1] (In the formula, the R1s each independently represent a substituted or unsubstituted alkoxy group or monovalent hydrocarbon group having 1 -10 carbon atoms, or a monovalent hydrocarbon group or (poly)oxyalkylene alkyl group having a hydroxyl group at the end (hereinafter collectively referred to as the hydroxyl group-containing group), at least one among the R1s is a hydroxyl-group containing group, a is a positive number of 2 or more, b is 0 or a positive number, c is 0 or a positive number, d is 0 or a positive number, and 2 ≤ a+b+c+d ≤ 1,000.) and (B) (meth)acrylic acid in an amount where the molar ratio relative to the hydroxyl group of the (A) component is 1.0 or greater, said reaction being caused in the presence of (C) an iron compound in an amount where the molar ratio relative to the hydroxyl group of the (A) component is 0.005-0.1.

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    合成参考文献


    参考文献:10.1007/s10965-023-03497-w
    摘要:Saeed PA, Juraij K, Saharuba PM, Sujith A. A one-pot water mediated process for developing conductive composites with segregated network of poly(3,4-ethylenedioxythiophene) on spherical poly(methyl methacrylate) particles. J Polym Res. 2023 Feb 24;30(3). doi: 10.1007/s10965-023-03497-w.
    参考文献:10.1007/s42114-023-00665-w
    摘要:Serafin A, Culebras M, Oliveira JM, Koffler J, Collins MN. 3D printable electroconductive gelatin-hyaluronic acid materials containing polypyrrole nanoparticles for electroactive tissue engineering. Adv Compos Hybrid Mater. 2023 May 20;6(3). doi: 10.1007/s42114-023-00665-w.
    参考文献:10.1007/s42114-023-00689-2
    摘要:Escobar A, Serafin A, Carvalho MR, Culebras M, Cantarero A, Beaucamp A, Reis RL, Oliveira JM, Collins MN. Electroconductive poly(3,4-ethylenedioxythiophene) (PEDOT) nanoparticle-loaded silk fibroin biocomposite conduits for peripheral nerve regeneration. Adv Compos Hybrid Mater. 2023 May 30;6(3). doi: 10.1007/s42114-023-00689-2.
    参考文献:10.1007/s13233-023-00188-9
    摘要:So J, Kim T, Shin J, Kim D, Kim FS. Ionogel-gated organic transistors and artificial synapses based on a composite of tosylate-doped poly(3,4-ethylenedioxythiophene) and insulating polyvinylpyrrolidone. Macromol. Res. 2023 Aug 14;31(11):1095–104. doi: 10.1007/s13233-023-00188-9.
    参考文献:10.1007/s42242-024-00272-8
    摘要:De Nitto S, Serafin A, Karadimou A, Schmalenberger A, Mulvihill JJE, Collins MN. Development and characterization of 3D-printed electroconductive pHEMA-co-MAA NP-laden hydrogels for tissue engineering. Bio-des. Manuf. 2024 Apr 25;7(3):262–76. doi: 10.1007/s42242-024-00272-8.
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