CAS: 301-01-9; Methyl Docosa-4,7,10,13,16,19-Hexaenoate

该化合物是多科萨赫甲基乙酸的一种衍生物,一种具有重大生化相关性的欧美加-3脂肪酸,这种甲基酯形式可以提高溶性性和稳定性,适合分析和合成应用,由于染色谱学和质谱测量结构纯度高,因此通常用作该物质的参考标准.该化合物在脂质研究中也具有价值,是研究脂肪酸代谢和膜膜动力学的前体,其酯化形式有利于处理和储存,同时保留DHA的生物活动,成为实验室使用的一种实际选择.

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2734-47-6 301-00-8 873108-81-7

物理性质

MSDS等安全信息

欧盟法规

C&L通报

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    专利信息


    专利号:US-10252972-B2
    优先权日:2015-06-30
    标 题 :Synthesis of long-chain unsaturated fatty acid by chemical reaction of carbon chain extension
    发明人：BAMBA NAOMICHI; MISAWA YOSHIHISA; TABATA HIROSHI; SHIMIZU YOSHIO
    权利人:BIZEN CHEMICAL CO LTD
    摘要:A method of chemically extending a carbon chain of an unsaturated fatty acid for conversion into a different unsaturated fatty acid has been reported. The present invention shortens reaction steps of conventional methods, and completes a carbon chain extending reaction in a shorter time. The present invention provides a method of extending a carbon chain of an unsaturated fatty acid by two carbons, comprising steps of four stages including a short-path conversion reaction of an unsaturated fatty chain obtained from an unsaturated fatty acid into a malonic ester derivative, and heating of the malonic ester derivative to reflux in a lower fatty acid solution. The method of the present invention can complete a carbon chain extending reaction in a shorter time.

    专利号:US-9006472-B2
    优先权日:2011-11-17
    标 题 :Methods for the synthesis of 13C labeled plasmalogen
    发明人：KHAN M AMIN; WOOD PAUL L; GOODENOWE DAYAN
    权利人:PHENOMENOME DISCOVERIES INC
    摘要:A method for preparing 13 C labeled plasmalogens as represented by Formula B: n n n n n n n n n n The method involves producing a 13 C labeled cyclic plasmalogen precursor of Formula A: n nand conversion of the precursor to a plasmalogen of Formula B.

    专利号:CN-104910009-A
    优先权日:2015-06-25
    标题 :A kind of method of ionic liquid catalyzed synthesis of pletil alcohol ester

    专利号:CN-109731607-B
    优先权日:2019-02-18
    标 题:Preparation method of propyl sulfonic group modified SBA-15 and application of propyl sulfonic group modified SBA-15 in synthesis of structured phospholipid

    专利号:JP-7204240-B2
    优先权日:2015-06-30
    标 题 :Synthesis of long-chain unsaturated fatty acids by chemical carbon chain elongation

    专利号:US-2014012024-A1
    优先权日:2011-03-23
    标题 :Method for the synthesis of dha

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    合成参考文献


    参考文献:10.1007/bf02609286
    摘要:Noble AC, Nawar WW. The autoxidation of highly unsaturated fatty acids: Methyl 4,7,10,13,16,19‐docosahexaenoate. J Americ Oil Chem Soc. 1971 Dec;48(12):800–3. doi: 10.1007/bf02609286.
    参考文献:10.1007/bf02676134
    摘要:Bannon CD, Craske JD, Hilliker AE. Analysis of fatty acid methyl esters with high accuracy and reliability. V. Validation of theoretical relative response factors of unsaturated esters in the flame lonization detector. J Americ Oil Chem Soc. 1986 Jan;63(1):105–10. doi: 10.1007/bf02676134.
    参考文献:10.1007/s10811-024-03350-7
    摘要:Gupta A, Rakhasiya B, Depani P, Bhagiya BK, Kaushik A, Bodar PA, Jaiswar S, Yadav DS, Mantri VA. Effect of Ascophyllum extract on cell division, proximate composition, antioxidant response and internal plant hormone composition in green seaweed Ulva ohnoi (Chlorophyta). J Appl Phycol. 2024 Sep 26;36(6):3623–36. doi: 10.1007/s10811-024-03350-7.
    参考文献:10.1007/s12257-025-00236-4
    摘要:Kang MH, Hwang YS, Kim SH, Han MH, Lee SH, Kim JW. Bone enhancement effect of microalgae-derived unsaponifiable matters on osteoblast through differentiation regulation. Biotechnol Bioproc E. 2025 Nov 27;30(6):979–93. doi: 10.1007/s12257-025-00236-4.
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