CAS: 2725-82-8; 1-Bromo-3-Ethylbenzene

上下游产品

CAS号587-02-0 3-乙基苯胺 | CAS号2039-86-3 间溴苯乙烯 | CAS号7787-70-4 溴化亚铜 | CAS号108-36-1 1,3-二溴苯 | CAS号75-03-6 碘乙烷 | CAS号2142-63-4 3-溴代苯乙酮 | CAS号3663-34-1 N-(4-乙基苯基)乙酰胺 | CAS号33098-65-6 2-乙基乙酰苯胺 | CAS号52780-14-0 3-溴-Alpha-甲基苯甲醇 | CAS号3132-99-8 间溴苯甲醛 | CAS号34136-57-7 3-乙基苯腈 | CAS号90555-65-0 3-乙基苯硼酸 | CAS号17988-51-1 (3-ethylphenyl)... | CAS号619-20-5 3-乙基苯甲酸 | CAS号585-76-2 3-溴苯甲酸 | CAS号13049-38-2 1-ethyl-3-(3-et... | CAS号2142-63-4 3-溴代苯乙酮 | CAS号676133-28-1 Cyclohexanol,1-... | CAS号3026-54-8 1-(3-ethylpheny... | CAS号62154-77-2 3-乙基苯硫醇

3-溴苯乙烯置于甲醇,Palladium Diacetate,频那醇硼烷体系中,用 二氯甲烷 用作溶剂,化学反应 12.0H,以99%的收率获得1-溴-3-乙基苯
参考文献:广义化学选择性转移加氢/氢化氘
标题:广义化学选择性转移加氢/氢化氘
摘要:使用hbpin和各种质子试剂作为氢源,已经开发了一种普遍,简单而有效的不饱和键转移加氢方法.包括烯烃,炔烃,芳族杂环,醛,酮,亚胺,偶氮,硝基,环氧和腈化合物在内的所有底物均应用于该催化体系.可以容忍在pd / C / H 2组合下无法生存的各种基团.研究了反应物的活性,其变化趋势为:苯乙烯>二苯基甲亚胺>苯甲醛>偶氮苯>硝基苯>喹啉>苯乙酮>苄腈.还研究了带有两个或多个不同不饱和键的底物,并以优异的化学选择性发生了转移氢化.由pd(oac)2和hbpin生成的二氧化钛极大地提高了th效率.此外,使用d 2 O和hbpin通过原位hd生成和区分,实现了末端芳族烯烃的化学选择性抗markovnikov加氢氘.
Doi:10.1002/adsc.202000759

专利信息

专利号:US-6608196-B2
优先权日:2001-05-03
标题 :Process for solid supported synthesis of pyruvate-derived compounds
发明人：WANG BING; JANAGANI SATYANARAYANA; CALLAWAY WYETH B; SESSLER JONATHAN L
权利人:GALILEO PHARMACEUTICALS INC
摘要:Provided are processes for synthesizing structurally diverse pyruvate-derived compounds using a parallel approach on a solid phase support. Examples of such a solid phase support include resins which have also been used in solid phase peptide synthesis.

专利号:US-9328061-B2
优先权日:2012-03-01
标题:Simple organic molecules as catalysts for practical and efficient enantioselective synthesis of amines and alcohols
发明人：HOVEYDA AMIR H; SILVERIO DANIEL L; PILYUGINA TATIANA; TORKER SEBASTIAN; ROBBINS DANIEL
权利人:TRUSTEES BOSTON COLLEGE
摘要:The present invention provides organic molecules and methods thereof for reactions between organoboron reagents and double bonds, such as imines or carbonyls, to stereoselectively provide chiral products including amines and alcohols, entities useful for the preparation of biologically active molecules.

专利号:US-5786448-A
优先权日:1996-11-07
标题:Combinatorial libraries of cyclic urea and cyclic thiourea derivatives and compounds therein
发明人：NEFZI ADEL; OSTRESH JOHN M; HOUGHTEN RICHARD
权利人:TREGA BIOSCIENCES INC
摘要:The invention provides a rapid approach for combinatorial synthesis and screening of libraries of cyclic urea and cyclic thiourea compounds. The present invention further provides the compounds made by the combinatorial synthesis.

专利号:US-7078568-B2
优先权日:2002-11-12
标 题 :Phosphine compounds, transition metal complexes with the compounds contained as ligands therein, and asymmetric synthesis catalysts containing the complexes
发明人：SHIMIZU HIDEO; SAITO TAKAO; NAGASAKI IZURU
权利人:TAKASAGO PERFUMERY CO LTD
摘要:Phosphine compounds represented by the following formula (1): n nwherein R 1 , R 2 , R 3 , R 4 , R 5 , R 6 and R 7 represent substituents, and asymmetric synthesis catalysts containing transition metal phosphine complexes with the compounds contained as ligands therein.n n The novel phosphine compounds according to the present invention are useful especially as ligands in transition metal complexes. The transition metal phosphine complexes are useful as catalysts for asymmetric synthetic reactions. The novel phosphine compounds useful as ligands can be prepared by a relatively economical preparation process. Further, use of these catalysts can afford hydrogenated products with high optically purity and is also extremely useful from the industrial standpoint.

专利号:US-6809202-B2
优先权日:1996-11-07
标 题 :Diketodiazacyclic compounds, diazacyclic compounds and combinatorial libraries thereof
发明人：NEFZI ADEL; OSTRESH JOHN M; HOUGHTEN RICHARD A
权利人:TORREY PINES INST
摘要:The synthesis of individual di- and tri-substituted-1,4-diazacyclic compounds having 6- to 8-atoms in the cyclic ring, their corresponding 1,6-diketo-2,5-diazacyclic compounds and similar 1,4-diazacyclic ring compounds having one ring carbonyl gorup and 6-8 atoms in the ring is disclosed, as are libraries of such compounds. Methods of preparing and using the libraries of compounds as well as individual compounds of the libraries are also disclosed.

专利号:US-2003100750-A1
优先权日:2001-05-03
标 题:Process for solid supported synthesis of pyruvate-derived compounds