CAS: 20710-47-8; Iodomethane-13C,D3

相似化合物

865-50-9 865-43-0

上下游产品

CAS号32479-98-4 甲醇-13C,d4 | CAS号73488-65-0 L-甲硫氨酸-(甲基-13C,d3)

📜甲醇-13C,D4置于氢碘酸体系中,用 水 用作溶剂,以73%的收率获得碘甲烷-13C,D3
参考文献:A Practical Laboratory Route To The Synthesis Of Trideuteriomethyl-[13C] Iodide
标题:A Practical Laboratory Route To The Synthesis Of Trideuteriomethyl-[13C] Iodide
摘要:本文介绍了一条实用的实验室合成路线,即从四氘代-[13C]-甲醇和氢碘酸合成三氘代甲基-[13C]碘化物(13Cd3I).我们对实验方案以及使用水作为 "添加剂 "来提高合成产量进行了评论.Copyright © 2003 John Wiley & Sons,Ltd. All Rights Reserved.
Doi:10.1002/jlcr.666

专利信息

专利号:US-6713044-B2
优先权日:2002-02-13
标题 :Synthesis of [2H1, 13C], [2H2, 13C] and [2H3, 13C]methyl aryl sulfides
发明人：MARTINEZ RODOLFO A; ALVAREZ MARC A; SILKS III LOUIS A; UNKEFER CLIFFORD J
权利人:UNIV CALIFORNIA
摘要:The present invention is directed to labeled compounds, [ 2 H 1 , 13 C], [ 2 H 2 , 13 C] and [ 2 H 3 , 13 C]methyl aryl sulfides wherein the 13 C methyl group attached to the sulfur of the sulfide includes exactly one, two or three deuterium atoms and the aryl group is selected from the group consisting of 1-naphthyl, substituted 1-naphthyl, 2-naphthyl, substituted 2-naphthyl, and phenyl groups with the structure n wherein R 1 , R 2 , R 3 , R 4 , and R 5 are each independently, hydrogen, a C 1 -C 4 lower alkyl, a halogen, an amino group from the group consisting of NH 2 , NHR and NRR′ where R and R′ are each a C 1 -C 4 lower alkyl, a phenyl, or an alkoxy group. The present invention is also directed to processes of preparing [ 2 H 1 , 13 C], [ 2 H 2 , 13 C] and [ 2 H 3 , 13 C]methyl aryl sulfides wherein the 13 C methyl group attached to the sulfur of the sulfide includes exactly one, two or three deuterium atoms. The present invention is also directed to the labeled compounds of [ 2 H 1 , 13 C]methyl iodide and [ 2 H 2 , 13 C]methyl iodide.

专利号:US-2003153789-A1
优先权日:2002-02-13
标题 :Synthesis of [2H1, 13C], [2H2, 13C] and [2H3, 13C]methyl aryl sulfides

专利号:WO-03068737-A2
优先权日:2002-02-13
标 题 :Synthesis of [2h1, 13c], [2h2, 13c], and [2h3, 13c]methyl aryl sulfides