CAS: 1888-71-7; 1-Propene, 1,1,2,3,3,3-Hexachloro-

该化合物是合成有机化合物,其特点是氯化结构,是无色的,淡黄色液体,有刺破的气味,表明其卤化性质,该化合物主要用作各种化学品合成的中间体,在农药和其他农用化学物的生产中具有应用,其分子结构具有多种附于一个丙烯脊柱的氯原子,这极大地影响其反应性和稳定性. 1,1,2,3,3,3, 3-六氯-1-丙烯因其环境持久性和潜在毒性而闻名无色,需要小心处理和管制.该化合物被归类为一种危险物质,接触可构成健康风险,包括呼吸和皮肤刺激.由于其化学特性,必须管理其使用和处置,以尽量减少环境影响.总体而言,这一化合物说明了工业应用中氯化有机化学品的复杂性.

结构式图片

欧盟法规

ECHA物质C&L通报REACH预注册

上下游产品

chloroform 1,1,1,2,3,3,3-heptachloropropane 1,1,1,2,2,3,3-heptachloropropane 2-fluoropentachloropropylene hexachlor°Cyclopentadiene 1,1,2-trichloro-3,3,3-trifluoropropene 2,3,3-trichloroacrylic acid tetrachloromethane

合成工艺路线路线简述

  • 5689-41-8 + 27013-18-9 = 1888-71-7 + 813-76-3
    反应条件:1.1 14.5 H,180 °C
    标题:Reaction Of Methyl Esters Of P(Iv) Acids With Polychlorinated Hydr°Carbons
    作者:Gazizov,M. B.; Et Al
    参考文献:Russian Journal Of General Chemistry (Translation Of Zhurnal Obshchei Khimii) 日期:2004 卷标:74(8) 页码:1295-1296
📜四氯化五烯置于氯体系中,化学反应生成六氯丙烯
参考文献:Hoever,H.,Chemische Berichte,1967,Vol. 100,P. 456-463
标题:Hoever,H.,Chemische Berichte,1967,Vol. 100,P. 456-463

海关参考信息

专利信息


专利号:US-5670465-A
优先权日:1993-01-08
标题 :Preparation of p-fuchsones and synthesis of p-dihydroxylated aromatic compounds therefrom
发明人:COSTANTINI MICHEL; MANAUT DANIEL; MICHELET DANIEL
权利人:RHONE POULENC CHIMIE
摘要:p-Dihydroxylated aromatic compounds are prepared via the oxidation of p-fuchsones, the latter advantageously being synthesized by reacting a phenolic compound having at least one hydrogen atom in the para-position to the hydroxyl function with a non-enolizable ketonic compound, in the presence of a catalytically effective amount of an acid catalyst and, optionally, a cocatalytically effective amount of an ionizable sulfur-containing compound.

专利号:US-5068472-A
优先权日:1989-12-19
标 题 :Multistep synthesis of hexafluoropropylene
发明人:WEBSTER JAMES L; TROFIMENKO SWIATOSLAW; RESNICK PAUL R; BRUHNKE DOUGLAS W; LEROU JAN J; MANOGUE WILLIAM H; MANZER LEO E; MCCANN ELREY L; SWEARINGEN STEVEN H; TRAINHAM JAMES A; BONIFAZ CRISTOBAL
权利人:DU PONT
摘要:The present invention relates to multistep syntheses of hexafluoropropylene from hexachloropropylene. In all these syntheses the first step is a fluorination of the starting material; later steps convert the initial products to CF 3 --CFCl--CF 3 , which is dehalogenated to the desired product.

专利号:US-5220083-A
优先权日:1989-12-19
标题:Synthesis of perfluoropropane
发明人:WEBSTER JAMES L; SWEARINGEN STEVEN H; BRUHNKE DOUGLAS W; MANZER LEO E; MCCANN ELREY L
权利人:DU PONT
摘要:The present invention relates to syntheses of perfluoropropane- .e., octafluoropropane-from acyclic three-carbon hydrocarbons or partially or totally halogenated acyclic three-carbon hydrocarbons.

专利号:US-8742045-B2
优先权日:2009-06-03
标题:Polymerization initiator for living radical polymerization
发明人:GOTO ATSUSHI; KIM JEONG SIK; TSUJII YOSHINOBU; FUKUDA TAKESHI
权利人:GOTO ATSUSHI; KIM JEONG SIK; TSUJII YOSHINOBU; FUKUDA TAKESHI; UNIV KYOTO
摘要:Provided is a method of living radical polymerization which does not necessitate complicated and intricate synthesis of a dormant species and which is highly efficient. A halogenated derivative compound is used as a dormant species for initiating living radical polymerization. The derivative compound is obtained by halogenating an alcohol compound having a non-conjugated structure or an amine compound having a non-conjugated structure with a halogenating agent capable of halogenating an alcohol or amine. A radical produced by elimination of halogen from the halogenated derivative compound is allowed to react with the unsaturated bond of the monomer. Thus, the monomer, which has a radical-reactive unsaturated bond, is polymerized by living radical polymerization. Preferably, the halogenating agent is a compound (NIS or the like) which also has a function as a catalyst.

专利号:US-12209104-B1
优先权日:2018-07-11
标 题:Metal complexes and methods of making the same
发明人:KIPLINGER JAQUELINE; BEATTIE ROSS; PAGANO JUSTIN; ERICKSON KARLA
权利人:TRIAD NAT SECURITY LLC
摘要:Disclosed herein are embodiments of metal complexes and methods of making the same. The disclosed method embodiments provide a one-step approach to making metal complexes, such as complexes comprising lanthanide metals, rare earth metals, transition metals, main group metals, and/or actinide metals that can be used various applications, such as in separations technology, catalysis (e.g., catalysts for pharmaceutical synthesis and/or catalysts for biomass conversion), nuclear chemistry, LED phosphors, scintillator materials, magnetic materials, and nuclear fuels.

专利号:US-9018325-B2
优先权日:2011-08-25
标题 :Catalyst for living radical polymerization and polymerization method
发明人:GOTO ATSUSHI; KAJI HIRONORI
权利人:GOTO ATSUSHI; KAJI HIRONORI; UNIV KYOTO
摘要:A nonmetallic compound having an ionic bond with a halide ion is used as a catalyst for living radical polymerization. Even if a radical initiator is not used, a monomer can be subjected to a radical polymerization to obtain a polymer having narrow molecular weight distribution. The cost of the living radical polymerization can be remarkably reduced, and it is made possible to prevent adverse effects of using a radical initiator (such as side reactions). The present invention is significantly more environmentally friendly and economically excellent than conventional living radical polymerization methods, due to advantages such as low toxicity of the catalyst, low amount of the catalyst necessary, high solubility of the catalyst, mild reaction conditions, and no coloration/no odor, etc. The catalyst can be applied to various monomers and enables synthesis of high molecular weight polymers.

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品牌试剂参考报价(招募中)

📌 第三方产品分析报告

✅ COA系统入驻 | 共享模式

合成参考文献


摘要:Sano, H.; Nishimura, J., Science of Synthesis, (2010) 45, 485.
摘要:40 CFR 240-280, 300-306, 702-799 (7/1/90)
摘要:Meylan WM et al; Environ Sci Technol 28: 459-65 (1992)
摘要:NIOSH; National Occupational Exposure Survey (NOES) (1983)
摘要:Deskant W et al; Environ Health Perspect 88: 107-10 (1990)
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