CAS: 94125-34-5; Prosulfuron

该化合物是一种广泛用于包括小麦和大麦在内的谷物作物选择性出血后杂草控制的灭蚁灵,它通过抑制乙醇综合酶(ALS)来发挥作用,该酶是环环氨酸生物合成物中的关键酶,有效针对宽叶草和一些草种.Prosulfon因其应用率低而得到重视,通常从10-20克活性成分/公顷不等,确保成本效益和最小的环境影响.它的系统性活动可以彻底抑制除草,即使是在难以控制的物种中也是如此.除草剂在作为定向使用时展示作物安全性,并展示残留活动,提供扩展保护.Prosulfon与罐体混合相容,提高综合杂草管理方案的灵活性.

结构式图片

欧盟法规

[欧盟农药活性物质

合成工艺路线路线简述

  • 94125-42-5 + 1668-54-8 = 94125-34-5
    反应条件:1.1 Reagents: Sodium Methoxide,Hydrochloric Acid Solvents: Water; 3 H,Rt1.2 Reagents: 1,8-Diazabicyclo[5.4.0]Undec-7-Ene Solvents: Acetonitrile; 1 Min,Rt; 1.5 H,Rt1.3 Reagents: Hydrochloric Acid Solvents: Water
    标题:Process For The Preparation Of Prosulfuron
    参考文献:China]

    = 94125-34-5 [标题:Reaction Conditions
    标题:N-Phenylsulfonyl-N'-Pyrimidinyl- And -Triazinylureas
    参考文献:European Patent Organization]

    94125-44-7 + 1668-54-8 = 94125-34-5 [标题:Reaction Conditions
    标题:Green Preparation Of Prosulfuron Drug
    参考文献:China]

    94125-42-5 + 1668-54-8 = 94125-34-5
    反应条件:1.1 Catalysts: Cyclohexyl Isocyanate Solvents: Chlorobenzene1.2 Solvents: Chlorobenzene
    标题:Process For The Preparation Of Substituted Benzenes And Benzenesulfonic Acids And Derivatives Thereof And A Process For The Preparation Of N,N'-Substituted Ureas
    参考文献:European Patent Organization
N-[2-(3,3,3-Trifluoro-1Propen-1yl)Phenylsulfonyl]-N'-(4-Methoxy-6Methyl-1,3,5-Triazin-2-yl)Urea,氢气置于钯 Acetone-Ether,氟磺隆体系中,用 乙酸乙酯 作为反应溶剂,化学反应 16.0H,反应生成 氟磺隆
参考文献:Phenylsulfonyl Isocyanates And Thioisocyanates
标题:Phenylsulfonyl Isocyanates And Thioisocyanates
摘要:化合物i的n-苯磺酰-N'-嘧啶基和-三嗪基脲的通式如下:##str1## 其中a为3,3,3-三氟丙基或3,3-二氟丁基,R1为氢,卤素,硝基,氰基,C1-C4烷基,C1-C4卤代烷基,C1-C4烷氧基,C1-C4烷基硫基,C1-C4烷基磺酰基,C1-C4烷基磺酰基,--Co--R6,--Nr7R8,--Co--Nr9R10或--So2--Nr11R12,R2为氢,卤素,C1-C4烷基,C1-C4烷氧基,C1-C4烷基硫基,C1-C4烷基磺酰基或c1-C4烷基磺酰基,R3和r4各自独立地为氢,卤素,C1-C4烷基,C1-C4卤代烷基,C2-C4卤代烷氧基,C1-C4烷基硫基,C1-C4卤代烷基硫基,C2-C4烷氧基烷基,C1-C4烷氧基或--Nr13R13,R5为氢,C1-C4烷基或c1-C4烷氧基,R6为c1-C4烷氧基,C1-C4卤代烷氧基,C1-C4烷基硫基,C2-C6烷氧基烷氧基,氢,C1-C4烷基或c1-C4卤代烷基,R7,R8,R9,R10,R11,R12和r13各自独立地为氢或c1-C4烷基,E为氮或甲基桥,Z为氧或硫;以及这些化合物的盐.

海关参考信息

专利信息


专利号:WO-2025056767-A1
优先权日:2023-09-15
标题 :Process for the preparation of enantiomerically enriched aliphatic amines
发明人:BOU HAMDAN FARHAN; GODINEAU EDOUARD; SMEJKAL TOMAS; DUMEUNIER RAPHAEL; BOUSSEMGHOUNE MOHAMED ABDELOUAHAB; BLUM MATHIAS
权利人:SYNGENTA CROP PROTECTION AG
摘要:The present invention relates to a process for the preparation of enantiomerically enriched cyclobutylamines of formula (I) from α-tertiary cyclobutanones and reacting said enantiomerically enriched cyclobutylamines to enantiomerically enriched cyclobutylamides. Such compounds are useful intermediates in the synthesis of microbiocidal thiazole compounds.

专利号:WO-2024256370-A1
优先权日:2023-06-13
标 题 :Synthesis of glufosinate using an amidase-based process
发明人:ZIMMERMANN GUNTHER; POTT MORITZ STEFAN
权利人:BASF SE
摘要:The present invention relates to a method of preparing glufosinate, comprising the steps of hydrolysing an N-carbamoyl glufosinate amide with an Amidase enzyme to form an N- carbamoyl amino acid compound followed by cleaving off the carbamoyl moiety of said N- carbamoyl amino acid compound.

专利号:US-2025120400-A1
优先权日:2021-12-10
标题:Synthesis of glufosinate using a hydantoinase-based process
发明人:DITRICH KLAUS; BREUER MICHAEL; POTT MORITZ STEFAN; ZIMMERMANN GUNTHER; SEEMAYER STEFAN
权利人:BASF SE
摘要:The present invention relates to a method of manufacturing glufosinate, comprising the steps of hydrolysing a hydantoin with a Hydantoinase enzyme to form a N-carbamoyl amino acid compound followed by cleaving off the carbamoyl moiety of said N-carbamoyl amino acid compound.

专利号:WO-2021130756-A1
优先权日:2019-12-25
标题:Combinations of non-protein amino acids and acetolactate synthase enzyme inhibitors
发明人:KLIPCAN LIRON; VAN-OSS PINHASI RUTH
权利人:THE STATE OF ISRAEL MINISTRY OF AGRICULTURE & RURAL DEVELOPMENT AGRICULTURAL RES ORGANIZATION ARO VO
摘要:The present invention provides compositions and methods for disrupting protein synthesis in plant cells.

专利号:US-11919928-B2
优先权日:2016-03-16
标题 :Method for producing dihydrotentoxin
发明人:KUBO TAKASHI; MACHIDA MASAYUKI; FUJIOKA TOMONORI; YAMAGUCHI Shigenari; KAWAI KIYOSHI
权利人:KUMIAI CHEMICAL INDUSTRY CO
摘要:An object of the present invention is to identify an enzyme having activity of synthesizing dihydrotentoxin that is a tentoxin precursor and an enzyme having activity of synthesizing tentoxin using dihydrotentoxin as a substrate. The present invention concerns a tentoxin synthesis-related gene encoding a protein comprising the amino acid sequence of SEQ ID NO: 16 and having activity of nonribosomal peptide synthesis of dihydrotentoxin and a tentoxin synthesis-related gene encoding a protein comprising the amino acid sequence of SEQ ID NO: 18 and having activity of converting dihydrotentoxin to tentoxin.

专利号:US-2021386068-A1
优先权日:2018-11-07
标题 :Compositions comprising pyridine carboxylate herbicides and very long chain fatty acid (vlcfa) synthesis inhibitor herbicides
发明人:KISTER JEREMY; SATCHIVI NORBERT M
权利人:CORTEVA AGRISCIENCE LLC
摘要:Disclosed herein are compositions comprising (a) a pyridine carboxylate herbicide or an agriculturally acceptable N-oxide, salt, or ester thereof and (b) a VLCFA synthesis inhibitor herbicide. Also disclosed herein are methods of controlling undesirable vegetation, comprising applying to vegetation or an area adjacent the vegetation or applying in soil or water to control the emergence or growth of vegetation (a) a pyridine carboxylate herbicide or an agriculturally acceptable N-oxide, salt, or ester thereof, and (b) a VLCFA synthesis inhibitor herbicide.
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合成参考文献


摘要:Andersson, C.-M.; Andersson, M., Science of Synthesis: Cross Coupling and Heck-Type Reactions, (2012) 3, 66.
摘要:40 CFR 180.481(a) (USEPA); U.S. National Archives and Records Administration's Electronic Code of Federal Regulations. Available from, as of June 17, 2018:
摘要:Franke C et al; Chemosphere 29: 1501-14 (1994)
摘要:USEPA/Office of Preventions, Pesticides and Toxic Substances; Prosulfuron. REVISED Human Health Risk Assessment for the Proposed Establishment of Permanent Tolerances for Uses in/on Cereal Grains (Crop Group 15), Except Rice, Docket # EPA-HQ-OPP-2008-0276-0008, p.36 (October 20, 2009). Available from, as of July 13, 2018:
摘要:S109 | PARCEDC | List of 7074 potential endocrine disrupting compounds (EDCs) by PARC T4.2 | DOI:10.5281/zenodo.10944198
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