CAS: 69839-68-5; 16-Mercaptohexadecanoic Acid

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71310-21-9 600730-11-8 1679-53-4

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CAS号2536-35-8 16-溴十六烷酸 | CAS号506-13-8 16-羟基十六烷酸 | CAS号21964-51-2 16碳二烯酸 | CAS号7735-42-4 1,16-十六烷二醇 | CAS号59101-28-9 16-溴-1-十六烷醇 | CAS号114896-32-1 16-巯基十六烷-1-醇 | CAS号93404-47-8 16-(ethyldisulf...

📜16-溴-1-十六烷醇置于chromium(Vi) Oxide,Hydroxide体系中,化学反应生成 16-巯基十六烷基酸
参考文献:Multiple Electron Tunneling Paths Across Self-Assembled Monolayers Of Alkanethiols With Attached Ruthenium(Ii/iii) Redox Centers
标题:Multiple Electron Tunneling Paths Across Self-Assembled Monolayers Of Alkanethiols With Attached Ruthenium(Ii/iii) Redox Centers
摘要:Alkanethiol Monolayers With Pendant Redox Centers Are Deposited On Gold Electrolytes By Self-Assembly. The Monolayers Are Composed Of Both An Electroactive Thiol,Hs(Ch2)(N)C(O)Nhch(2)Pyru(Nh3)(5)(2+/3+),With 10-15 Methylene Groups,And A Diluent Thiol,Hs(Ch2)Mcooh,Also With 10-15 Methylene Groups. The Monolayers Are Classified As ''Matched'' (N = M),''Exposed'' (N = 15,M = 10-14),And ''Buried'' (N = 10,M = 11-15) According To The Relative Position Of The Redox Center. Cyclic Voltammograms In Aqueous Na2So4 Indicate That The Monolayers Are Close-Packed With The Redox Centers Residing In The Aqueous Phase In All But The Most Buried Cases. Measurements Of Electron Transfer Kinetics By Several Methods (Cyclic Voltammetry,Ac Impedance Spectroscopy,Chronoamperometry) Yield An Internally Consistent Set Of Kinetic Parameters,The Standard Rate Constant K Degrees,And The Reorganization Energy Lambda Of The Redox Centers. The Reorganization Energies Are In Good Agreement With The Theoretically Predicted Value Of 1.0 Ev For The Pyru(Nh3)(5) Redox Centers. Plots Of Ln(K Degrees) Vs M Are Linear In All Three Cases. The Slopes Of The Linear Regression Fit Provide Tunneling Parameters (Beta,Where K Degrees Approximate To E(-Beta M)) Of 0.97 +/-0.03 (Matched Cases),0.83 +/-0.03 (Exposed Cases) And 0.16 +/-0.02 (Buried Cases) Per Methylene. This Pattern Of Beta'S Is Interpreted In Terms Of Electronic Coupling Between The Redox Center And The Electrode Via Both The Redox Thiol And The Proximate Diluent Thiols,With The Coupling Via The Diluent Thiols Dominating In The Exposed Cases.
DOI:10.1021/jp962831Q

专利信息

专利号:US-11180507-B2
优先权日:2016-07-08
标题:Synthesis of functionalizable or functionalized poly(3,4-ethylenedioxythiphene)-based polymers and monomers therefor
发明人：CUI XINYAN; CAO BIN
权利人:UNIV PITTSBURGH COMMONWEALTH SYS HIGHER EDUCATION; UNIV OF PITTSBURGH—OF THE COMMONWEALTH SYSTEM OF HIGHER EDUCATION
摘要:A method of forming a compound having the formula (I′): (I′) includes the reaction: (II′) in the presence of a base, wherein X is a halo atom selected from the group consisting of Cl, Br and I.

专利号:US-2024352312-A1
优先权日:2021-06-25
标题:Microemulsion template assisted synthesis of cadmium-free near-infrared quantum dots based on i-iii-vi ternary semiconductors
发明人：WANG JUN
权利人:QUANTUM TECH GROUP
摘要:A method for making ternary core-shell semiconductor nanoparticles includes providing an emulsion including droplets dispersed in a continuous phase of a non-polar solvent. The droplets include a solution of ions of a Group I element and ions of a Group III element in a polar solvent, and are encapsulated by an interfacially active material. The emulsion is exposed to ions of a Group VI element to cause a reaction, thereby forming nanoparticles in the droplets. The nanoparticles in the droplets are with a first precursor to grow a shell on the nanoparticles, thereby forming core-shell nanoparticles. The core-shell nanoparticles are extracted from the emulsion; thermally annealed; and reacted with a second precursor to further grow the shell on the nanoparticles, thereby forming ternary core-shell semiconductor nanoparticles.

专利号:US-2025143061-A1
优先权日:2023-09-13
标题 :Molecular diode utilizing the characteristic of inducing electrically inactive organic molecules into molecules with electrical properties
发明人：YOON HYO JAE; KONG GYUDON
权利人:UNIV KOREA RES & BUS FOUND
摘要:Disclosed is a molecular diode using the assignment of electrical properties to inactive organic molecules when a self-assembled monolayer (SAM) thin film including an electrically inactive organic molecule is formed without synthesizing a separate organic molecule having electrical activity. The disadvantage of the instability of a conventional SAM can be overcome, a function can be extended, and electrical properties, such as a rectification characteristic in a non-functional molecule, can be induced even without the design and synthesis of organic molecules for introducing a functional molecule. Accordingly, the embodiments of the present disclosure can be usefully used in various technical fields in which an SAM is used, in particular, wide fields such as electronics, an organic display (OLED), solar cells, sensors, non-uniform catalysts, frictional electricity, cell growth surfaces, and a heat transfer control film.

专利号:US-2015328616-A1
优先权日:2014-05-13
标题:Surface mediated synthesis of polynucleotides, polypeptides and polysaccharides and related materials, methods and systems
发明人：GETHERS MATTHEW; GODDARD III WILLIAM A; WEISS PAUL S; RANDALL JOHN
权利人:CALIFORNIA INST OF TECHN
摘要:Surface mediated polymer synthesizing methods and related systems and materials are described where monomers are attached to monomer binding regions on a surface and subsequently form chemical bonds with adjacent monomers on the surface to form linear polymers selected from polynucleotide, polypeptides and polysaccharides.

专利号:US-2005218540-A1
优先权日:2004-03-31
标 题:Process for preparing micron/nano size inorganic particles
发明人：SASTRY MURALI; RAUTARAY DEBABRATA; SINHA KAUSTAV
权利人:COUNCIL SCIENT IND RES
摘要:The present invention discloses methods for making micron/nano sized (2 nm to 5 μm) particles of various inorganic materials such as mineral/oxides/sulphides/metals/ceramics using aqueous foam, Aqueous foams of various anionic, cationic, non-ionic surfactant, casein proteins and their mixtures has been used for the preparation of suitable inorganic materials growth. Large scale synthesis of advanced inorganic materials such as various ceramics, minerals, oxides, sulphides and metal micron/nanoparticles of controlled shape and size can be obtained by mixing appropriate metal ions with the suitable cationic/anionic/non-ionic/casein protein/their mixtures, which is bubbled by air to form aqueous foams and thereafter their reduction/reaction to form the final product.

专利号:US-2023132381-A9
优先权日:2016-07-08
标 题 :Synthesis of functionalizable or functionalized poly(3,4-ethylenedioxythiphene)-based polymers and monomers therefor