CAS: 544-97-8; Dimethylzinc

该化合物是室内温度为无色,易燃液体,有独特的气味,反应性很强,特别是湿气和空气,形成氧化锌,在接触水时释放甲烷气,这种反应性使它成为有机合成的有用试剂,特别是在通过诸如 Grignard反应等反应形成碳-碳联结方面;二甲基辛基在二乙醚和四氢呋喃等有机溶剂中溶解,但水中溶解;由于其交火性性质,它自发在空气中燃烧,需要在惰性大气中(通常是氮或芳香)进行谨慎处理;在安全方面,它构成重大危险,包括毒性和易燃性,需要采取适当的安全措施,包括使用个人防护设备和适当的储存条件;其应用范围扩大到生产各种有机锡衍生物,以及在含锌的薄膜沉积的半导体工业中.

结构式图片

欧盟法规

统一分类与标签压力设备指令-第1组危险流体ECHA物质工作场所安全标识要求ECHA物质C&L通报REACH预注册废弃物危险特性清单

上下游产品

CAS号74-88-4 碘甲烷 | CAS号75-16-1 甲基溴化镁 | CAS号7646-85-7 氯化锌 | CAS号917-64-6 甲基碘化镁 | CAS号7440-66-6 锌标准溶液 | CAS号917-54-4 甲基锂 | CAS号1000391-90-1 | CAS号593-74-8 二甲基汞 | CAS号557-34-6 醋酸锌 | CAS号75-24-1 三甲基铝 | CAS号1068-19-5 4,4-二甲基庚烷 | CAS号104849-66-3 triphenyltin,zinc | CAS号10499-08-8 2H-1-Benzopyran... | CAS号37669-78-6 乙基2,4-二甲基吡啶-3-羧化物 | CAS号557-34-6 醋酸锌 | CAS号563-16-6 3,3-二甲基己烷 | CAS号34136-57-7 3-乙基苯腈 | CAS号620-22-4 间甲基苯腈 | CAS号5521-56-2 2-氨基-6-甲基吡嗪 | CAS号39627-61-7 7-甲基-1-茚酮

合成工艺路线路线简述

  • 合成目标产物 Dimethylzinc 主要起始原料 Trimethylaluminium And Zinc Chloride
  • (文献来源)合成步骤主要原料 Trimethylaluminium 和 Zinc Chloride

专利信息


专利号:US-7615169-B2
优先权日:2004-09-20
标题 :Method for synthesis of colloidal nanoparticles
发明人:STROUSE GEOFFREY FIELDING; GERBEC JEFFREY A; MAGANA DONNY
权利人:UNIV CALIFORNIA
摘要:A method for synthesis of high quality colloidal nanoparticles using comprises a high heating rate process. Irradiation of single mode, high power, microwave is a particularly well suited technique to realize high quality semiconductor nanoparticles. The use of microwave radiation effectively automates the synthesis, and more importantly, permits the use of a continuous flow microwave reactor for commercial preparation of the high quality colloidal nanoparticles.

专利号:US-2006247457-A1
优先权日:2003-02-27
标题 :Method for the synthesis of methyl-tri-oxo-rhenium
发明人:TURCHETTA STEFANO; PIETRO MASSARDO; ANGELA TUOZZI
权利人:TURCHETTA STEFANO; PIETRO MASSARDO; ANGELA TUOZZI
摘要:A method for the synthesis of methyltrioxorhenium is described, wherein 0.5-1.5 moles of dirhenium heptaoxide are reacted with 1-3 moles of tetramethyl tin in the presence of 1-3 moles of chlorotrimethyl silane. The synthesis is carried out in the dark for approximately 24 hours in a polar aprotic organic solvent, preferably in acetonitrile.

专利号:US-7927516-B2
优先权日:2004-09-20
标题 :Method for synthesis of colloidal nanoparticles
发明人:STROUSE GEOFFREY F; GERBEC JEFFREY A; MAGANA DONNY
权利人:UNIV CALIFORNIA
摘要:A method for synthesis of high quality colloidal nanoparticles using comprises a high heating rate process. Irradiation of single mode, high power, microwave is a particularly well suited technique to realize high quality semiconductor nanoparticles. The use of microwave radiation effectively automates the synthesis, and more importantly, permits the use of a continuous flow microwave reactor for commercial preparation of the high quality colloidal nanoparticles.

专利号:US-7692019-B2
优先权日:2000-12-04
标 题:Methods for the stereoselective synthesis of substituted piperidines
发明人:AQUILA BRIAN M; BANNISTER THOMAS D; CUNY GREGORY D; HAUSKE JAMES R; HEFFERNAN MICHELE L R; HOEMANN MICHAEL Z; KESSLER DONALD W; SHAO LIMING; WU XINHE; XIE ROGER L
权利人:SEPRACOR INC
摘要:One aspect of the present invention relates to methods of synthesizing substituted piperidines. A second aspect of the present invention relates to stereoselective methods of synthesizing substituted piperidines. The methods of the present invention will find use in the synthesis of compounds useful for treatment of numerous ailments, conditions and diseases that afflict mammals, including but not limited to addiction and pain. An additional aspect of the present invention relates to the synthesis of combinatorial libraries of the substituted piperidines using the methods of the present invention. An additional aspect of the present invention relates to enantiomerically substituted pyrrolidines, piperidines, and azepines.

专利号:US-2011130591-A1
优先权日:2009-06-03
标 题:Steroselective synthesis of certain trifluoromethyl-substituted alcohols
发明人:FANDRICK DANIEL R; REEVES JONATHAN T; SONG JINHUA J
权利人:BOEHRINGER INGELHEIM INT
摘要:A process for synthesis of a compound of Formula (X) n n n n n n n n n n wherein:n R 1 is an aryl group substituted with one to three substituent groups,n wherein each substituent group of R 1 is independently C 1 -C 5 alkyl, aminocarbonyl, alkylaminocarbonyl, dialkylaminocarbonyl, halogen, carboxy, cyano, or trifluoromethyl,n wherein each substituent group of R 1 is optionally independently substituted with one to three substituents selected from C 1 -C 3 alkyl, C 1 -C 3 alkoxy, phenyl, and alkoxyphenyl; and n n R 2 and R 3 are each independently C 1 -C 5 alkyl.

专利号:US-2023002805-A1
优先权日:2021-06-25
标 题 :Use of organic cationic compounds to accelerate nucleic acid hybridization, synthesis, and amplification
发明人:RABBANI ELAZAR; COLEMAN JACK
权利人:ENZO BIOCHEM INC
摘要:The invention provides methods for accelerated synthesis of nucleic acids, and related compositions which involve the use of organic amines in the nucleic acid synthesis reaction mixture. The invention also provides methods for reducing processing steps associated with nucleic acid synthesis. The invention further provides methods for screening compounds that have positive benefits on the synthesis of nucleic acids.
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合成参考文献


摘要:Toyota, S.; Iwanaga, T., Science of Synthesis, (2010) 45, 815.
摘要:Negishi, E.; Wang, G., Science of Synthesis, (2009) 46, 300.
摘要:Negishi, E.; Wang, G., Science of Synthesis, (2009) 46, 290.
摘要:Negishi, E.; Wang, G., Science of Synthesis, (2010) 47, 971.
摘要:Negishi, E.; Wang, G., Science of Synthesis, (2010) 47, 962.
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