CAS: 3100-04-7; 1-Methylcyclopropene

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CAS号563-47-3 3-氯-2-甲基-1-丙烯(MAC) | CAS号130894-83-6 1,1,2-tribromo-... | CAS号920-46-7 甲基丙烯酰氯 | CAS号653605-61-9 1,2-diiodo-1-me... | CAS号21981-33-9 1,1,1,3,3-penta... | CAS号35911-17-2 1-Propene,1,3-d... | CAS号39185-82-5 1,1,3,3-Tetrach... | CAS号2465-56-7 methanediyl | CAS号74-99-7 丙炔 | CAS号105842-98-6 acetic acid,3-b... | CAS号14309-32-1 1,2-dimethylcyc... | CAS号6142-73-0 亚甲基环丙烷 | CAS号598-25-4 3-甲基-1,2-丁二烯 | CAS号78-79-5 异戊二烯 | CAS号503-17-3 2-丁炔 | CAS号590-19-2 1,2-丁二烯 | CAS号106-99-0 丁二烯 | CAS号820-71-3 甲基丙烯醇乙酸酯 | CAS号563-47-3 3-氯-2-甲基-1-丙烯(MAC)

📜1-Methyl-1-(Methanesulfonyloxy)-2-(Trimethylsilyl)Cyclopropane置于四丁基氟化铵体系中,用 二乙二醇二甲醚 作为反应溶剂,化学反应生成 1-甲基环丙烯
参考文献:Cyclopropenes-Generating Devices To Control Ripening Processes Of Agricultural Products
标题:Cyclopropenes-Generating Devices To Control Ripening Processes Of Agricultural Products
摘要:提供的是一种用于反应生成环丙烯化合物的装置,能够实现环丙烯化合物的直接原位制备和应用,从而抑制乙烯的作用,乙烯会加速植物的成熟过程.该装置包括用于存储环丙烯化合物前体("环丙烯前体"的第一存储部分,用于存储将环丙烯前体通过化学反应转化为环丙烯衍生物的反应试剂的第二存储部分,以及用于喷洒由环丙烯前体和反应试剂之间的化学反应产生的环丙烯衍生物的喷雾部分.

专利信息

专利号:US-7429658-B2
优先权日:2003-09-11
标题 :Synthesis of protected pyrrolobenzodiazepines
发明人：HOWARD PHILIP; MASTERSON LUKE
权利人:SPIROGEN LTD
摘要:A method of synthesis of a N-10 protected PBD compound of formula (I): n nvia an intermediate of formula (II) or formula (V):

专利号:US-7557099-B2
优先权日:2004-03-01
标题 :Pyrrolobenzodiazepines as key intermediates in the synthesis of dimeric cytotoxic pyrrolobenzodiazepines
发明人：HOWARD PHILIP WILSON; KANG GYOUNG-DONG
权利人:SPIROGEN LTD
摘要:Compounds and a method of synthesis of compounds of formula (Ia) or (Ib): and salts, solvates, and chemically protected forms thereof, wherein the dotted lines indicate the optional presence of a double bond between C1 and C2 or C2 and C3; R 2 and R 3 are independently selected from —H, â•?O, â•?CH 2 , —CN, —R, OR, halo, â•?CH—R, O—SO 2 —R, CO 2 R and COR; R 10 is a carbamate-based nitrogen protecting group; and R 11 is an oxygen protecting group.

专利号:US-9006425-B2
优先权日:2009-03-18
标题:Aluminum complexes and their use in the synthesis of cyclic carbonates
发明人：NORTH MICHAEL
权利人:NORTH MICHAEL; UNIV YORK
摘要:Dimeric aluminum catalysts of formula I: and their use in catalyzing the synthesis of cyclic carbonates from epoxides and carbon dioxide.

专利号:US-6313068-B1
优先权日:1998-08-20
标 题:Synthesis methods, complexes and delivery methods for the safe and convenient storage, transport and application of compounds for inhibiting the ethylene response in plants
发明人：DALY JAMES; KOURELIS BOB
权利人:AGROFRESH INC
摘要:The present invention generally relates to the regulation of plant physiology, in particular to methods for inhibiting the ethylene response in plants or plant products, and has three embodiments. The first embodiment relates to methods of minimizing impurities capable of reversibly binding to plant ethylene receptor sites during the synthesis of cyclopropene and its derivatives such as methylcyclopropene, thereby avoiding the negative effects these impurities have on plants treated with cyclopropene and its derivatives. The second embodiment relates to complexes formed from molecular encapsulation agents such as cyclodextrin, and cyclopropene and its derivatives such as methylcyclopropene, in addition to cyclopentadiene and diazocyclopentadiene and their derivatives, thereby providing a convenient means for storing and transporting these compounds capable of inhibiting the ethylene response in plants, which are reactive gases and highly unstable because of oxidation and other potential reactions. The third embodiment relates to convenient methods of delivering to plants these compounds capable of inhibiting the ethylene response in the plants in order to extend their shelf life.

专利号:US-8829184-B2
优先权日:2010-04-15
标题:Intermediates useful for the synthesis of pyrrolobenzodiazepines
发明人：HOWARD PHILIP WILSON; MASTERSON LUKE; TIBERGHIEN ARNAUD
权利人:HOWARD PHILIP WILSON; MASTERSON LUKE; TIBERGHIEN ARNAUD; SPIROGEN SARL
摘要:A compound of formula (I): which is substantially free of any of the corresponding compound of formula (IB): methods of making such compounds, and the further transformation of such compounds.

专利号:EP-1597968-B1
优先权日:1999-12-17
标题:Complexes and delivery methods for the safe and convenient storage, transport and application of compounds for inhibiting the ethylene response in plants
发明人：DALY JAMES; KOURELIS BOB
权利人:AGROFRESH INC
摘要:The present invention generally relates to the regulation of plant physiology, in particluar to methods for inhibiting the ethylene response in plants or plant products, and has three embodiments. The first embodiment relates to methods of minimizing impurities capable of reversibly binding to plant ethylene receptor sites during the synthesis of cyclopropen and its derivatives such as methylcyclopropene thereby avoiding the negative effects these impurities have on plants treated with with cyclopeopene and its derivatives. The second embodiment relates to complexes formed from molecular encapsulation agents such as cyclodextrin, and cyclopropenes and its derivatives such as methylcyclopropene, in addition to cyclopentadiene and diazocyclopentadiene and their derivatives, thereby providing a convenient means for storing and transporting these compounds capable of inhibiting the ethylene response in plants, which are reactive gases and highly unstable because of oxidation and other potential reactions. The third embodiment relates to convenient methods of delivering to plants these compounds capable of inhibiting the ethylene response in the plants in order to extend their shelf life.