CAS: 2046-17-5; Methyl 4-Phenylbutanoate

该化合物是一种酯类化合物,其特征是芳香苯基和丁基骨干;它是有机合成的多用途中间体,特别是在生产药品,香料和香料剂方面.该化合物在普通有机溶剂中表现出有利的稳定性和溶性,便于其在各种化学反应中使用.其独特的芳香特征使其在香水中具有价值,它提供了甜甜果调料.此外,甲基四苯基在研究中被用作较复杂的分子的前体.该酯的清晰结构和一贯纯度确保了工业和实验室应用的可靠性能.

结构式图片

上下游产品

CAS号67-56-1 甲醇 | CAS号1821-12-1 4-苯基丁酸 | CAS号300-57-2 烯丙基苯 | CAS号292638-85-8 丙烯酸甲酯 | CAS号120790-93-4 dimethyl 2-(2-p... | CAS号25333-24-8 3-苯甲酰丙酸甲酯 | CAS号77903-44-7 c-2-Phenyl-t-2-... | CAS号100-39-0 溴化苄 | CAS号74-88-4 碘甲烷 | CAS号10473-01-5 4-methoxybutylb... | CAS号4830-93-7 1-氯-4-苯基丁烷 | CAS号18093-53-3 3-[3-[4-(benzen... | CAS号104-51-8 丁基苯 | CAS号529-34-0 1-四氢萘酮 | CAS号768-56-9 4-苯基-1-丁烯 | CAS号1821-12-1 4-苯基丁酸 | CAS号119-64-2 1,2,3,4-四氢萘(THN) | CAS号2979-69-3 4,4-二甲基-3,4-二氢萘... | CAS号3360-41-6 4-苯基-1-丁醇

合成工艺路线路线简述

    📜1-苯基-3-丁烯-2-醇置于氯化亚砜,三甲基铝体系中,用 正己烷,二氯甲烷 用作溶剂,化学反应 31.0H,反应生成4-苯丁酸甲酯
    参考文献:The Regiochemistry Of The Protodesilylation Of Some Cyclopropylmethylsilanes Derived From Allylsilanes
    标题:The Regiochemistry Of The Protodesilylation Of Some Cyclopropylmethylsilanes Derived From Allylsilanes
    摘要:烯丙基硅烷的 Simmons-Smith 型甲烯化反应,然后是原代硅烷化反应,可用于实现甲基基团对硅烷基团的 Se2'置换.环丙基甲基硅烷 11,17,20 和 23 亚甲基碳上的质子化具有非常好的区域选择性,但形成环丙基甲基硅烷 26 的立体选择性较低,而且不能进行干净的原代甲硅烷基化,因此该方法的用途有限.
    Doi:10.1055/s-1992-34186

    海关参考信息

    专利信息


    专利号:US-8779207-B2
    优先权日:2012-08-31
    标题 :Method for synthesis of [6,6]-phenyl-C61-butyric acid methyl ester (PCBM) and fullerene derivatives
    发明人:NG KA MING; ZHUANG JIANLE; TSENG NAI WEN; YU YONG
    权利人:NG KA MING; ZHUANG JIANLE; TSENG NAI WEN; YU YONG; NANO & ADVANCED MATERIALS INST LTD
    摘要:The present subject matter relates to methods for the synthesis of [6,6]-phenyl-C 61 -butyric acid methyl ester (PCBM) and fullerene derivatives in a yield of at least 40%.

    专利号:US-2019276389-A1
    优先权日:2015-12-18
    标题:Synthesis of aryl cyclohexane ester derivatives useful as sensates in consumer products
    发明人:WOS JOHN AUGUST; YELM KENNETH EDWARD; BUNKE GREGORY MARK; FREDERICK HEATH ALAN; REILLY MICHAEL; HAUGHT JOHN CHRISTIAN; SREEKRISHNA KOTI TATACHAR; LIN YAKANG
    权利人:PROCTER & GAMBLE
    摘要:Personal care compositions, such as oral care and skin care compositions containing a flavor/perfume system comprising one or more coolants. The pleasant cool sensation provided by a coolant is enhanced in terms of quicker onset, greater intensity, impact or longer duration, which improves appeal and acceptability of the compositions to consumers.

    专利号:US-2017246690-A1
    优先权日:2014-06-20
    标 题:Stabilizing agent-free metal nanoparticle synthesis and uses of metal nanoparticles synthesized therefrom
    发明人:MURPHY RYAN J; DREYFUS REMI; HOUGH LAWRENCE ALAN; MALASSIS LUDIVINE; MURRAY CHRISTOPHER; DONNIO BERTRAND
    权利人:RHODIA OPERATIONS; CENTRE NAT RECH SCIENT; UNIV PENNSYLVANIA
    摘要:Described herein are methods of synthesizing metal nanoparticles and the metal nanoparticles synthesized therefrom. Further described in the present disclosure are methods of modifying the surfaces of metal nanoparticles and the metal nanoparticles modified thereby. Also described herein are uses of such metal nanoparticles.

    专利号:US-2006171882-A1
    优先权日:2005-02-01
    标 题 :Method for the use of [11C] carbon monoxide in labeling synthesis of 11C-labelled compounds by thermally induced free radical carbonylation

    专利号:US-2008226555-A1
    优先权日:2005-06-08
    标题 :Method for the Use of [11C] Carbon Monoxide in Labeling Synthesis of 11C-Labelled Esters and Acids by Sensitized Photo-Induced Free Radical

    专利号:US-2006165590-A1
    优先权日:2004-12-17
    标 题 :Method for the use of [11C] carbon monoxide in labeling synthesis of 11C-labelled esters by photo-induced free radical carbonylation

    供应商参考报价(招募中)

    品牌试剂参考报价(招募中)

    📌 第三方产品分析报告

    ✅ COA系统入驻 | 共享模式

    合成参考文献


    摘要:Chen, P.; Liu, G., Science of Synthesis: Catalytic Oxidation in Organic Synthesis, (2017) 1, 204.
    摘要:Zhang, F.-L.; Wang, Y.-F., Science of Synthesis: Advances in Organoboron Chemistry towards Organic Synthesis, (2019) 1, 359.
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