BPAepichlorohydrin1-chloro-3-[4-[2-[4-(3-chloro-2-hydroxypropoxy)phenyl] propan-2-yl]phenoxy]propan-2-olbisphenol A diallyl ether2,2-bis-[4-(2,3-diacetoxy-propoxy)-phenyl]-propane5,5′-(((propane-2,2-diylbis(4,1-phenylene))bis(oxy))bis-(methylene))bis(3-(p-tolyl)oxazolidin-2-one)3,3'-dibutyl-5,5'-[4,4'-(1-methyl-ethane-1,1-diyl)-bis-phenoxymethyl]-bis-oxazolidin-2-one1-[Benzyl-(1,4,6-trioxa-spiro[4.4]non-2-ylmethyl)-amino]-3-{4-[1-(4-{3-[benzyl-(1,4,6-trioxa-spiro[4.4]non-2-ylmethyl)-amino]-2-hydroxy-propoxy}-phenyl)-1-methyl-ethyl]-phenoxy}-propan-2-ol
合成工艺路线路线简述
合成目标产物 Bisphenol A Diglycidyl Ether Resin 主要起始原料 Bisphenol A And Epichlorohydrin
专利号:US-11897860-B2 优先权日:2022-03-14 标题 :Direct synthesis of cyclic carbonates using choline chloride as catalyst under mild conditions 发明人:CARRASCO ANALETTE; WEERS JERRY J; BLACKWELL CATHERINE C; MURUGESAN SANKARAN; WANG XIAOFENG; NUGENT DOUGLAS; ROBERTS CORBY A 权利人:BAKER HUGHES OILFIELD OPERATIONS LLC 摘要:A method for direct synthesis of cyclic carbonates is achieved by reacting at least one epoxide with carbon dioxide in the presence of a choline catalyst, such as choline chloride, under mild conditions such as a temperature between about 25° C. to 150° C. and a pressure of from about atmospheric to 75 psi (0.52 MPa), in a cyclic carbonate solvent. The choline catalyst may be the only catalyst used, and a co-catalyst or hydrogen bond donor is not necessary. The concentration of choline catalyst in the solvent ranges from about 0.5 mol % to about 10 mol %, based on the epoxide.
专利号:US-9617396-B2 优先权日:2012-02-22 标 题:Method for in-situ synthesis of silicon nanoparticles 发明人:SCHUBERT CHLOÉ; PONCELET OLIVIER 权利人:COMMISSARIAT ENERGIE ATOMIQUE 摘要:The invention relates to a method for in-situ synthesis of silicon nanoparticles in a thermosetting polymeric matrix, the thermosetting and thermoset matrices obtained in this way and a material including same. The method includes the following steps: a) forming an aqueous-phase/organic-phase inverse emulsion, wherein the aqueous phase includes at least a basic catalyst and the organic phase includes at least a non-cross-linked (co)polymer precursor chosen from an aliphatic, cycloaliphatic or aromatic epoxy resin precursor, a polyester-imide precursor, an unsaturated/epoxy polyester (co)polymer precursor, a polyether/epoxy (co)polymer precursor and a polyurethane precursor; b) introducing, into the inverse emulsion formed in step a), at least one silicon precursor forming a complete network whereof the rate of hydrolysis is greater than the cross-linking speed of the (co)polymer and c) stirring the mixture obtained in step b) and heating to a temperature between 20° C. and 70° C.
专利号:WO-2015017140-A1 优先权日:2013-07-31 标题:Foam-free synthesis of co-polyhydroxyaminoether 发明人:MEZA CESAR E; HOYLES STEPHEN M; MAYNARD SHAWN J; SOLIS JUAN G; CASTILLO FLOR A 权利人:DOW GLOBAL TECHNOLOGIES LLC 摘要:A process includes an initial synthesis including mixing an epoxy and an aqueous amine solution to form a reaction mixture and addition of water to the reaction mixture while mixing. The amine includes: where R 5 is hydrocarbyl, R 6 is hydrogen, methyl, hydrocarbyl or mixtures thereof, and q is one to 1000; at least 90 mole-percent of the epoxy molecules have a reactive functionality in a range of one to two and an average reactive functionality of two or less; at least 90 mole- percent of the amine molecules have a number of reactive protons in a range of one to two and an average number of reactive protons of two or less; the amine is present at an excess mole ratio of reactive sites relative to epoxy reactive sites; and the temperature of the reaction mixture during the water addition is maintained between zero and 68 degrees Celsius.
专利号:US-5189184-A 优先权日:1990-08-30 标题:2-(3'-butenyl)-3,4-dihydro-2h-pyrans, their synthesis and use 发明人:SCHAEFER DIETMAR; WEIER ANDREAS; WEITEMEYER CHRISTIAN; WEWERS DIETMAR 权利人:GOLDSCHMIDT AG TH 摘要:2-(3'-butenyl)-3,4-dihydro-2H-pyrans of the general formula wherein R is a hydrogen group or an alkyl group with 1 to 6 carbon atoms. Methods for the synthesis of these compounds and their use as reactive modifiers or diluents for cationically curable monomers or polymers.
专利号:US-5073643-A 优先权日:1990-08-30 标 题 :High yield synthesis of hydroxyl-containing cationic photoinitiators 发明人:CRIVELLO JAMES V 权利人:POLYSET CORP 摘要:Synthesis use of a new class of diaryliodonium salt photo and thermal polymerization initiators in which the aryl groups are substituted with alkoxy group bearing hydroxy groups. Good to excellent yields are obtained of diaryliodonium salts in which the aryl groups are substituted with long chain alkoxy groups, which alkoxy groups also possess at least one hydroxyl moiety attached at the 2-position of an alkoxy group. The resultant salts have enhanced solubility when compared with their lower molecular weight counterparts. The hydroxyl groups serve as chain transfer agents; and, in cross linking UV-induced cationic polymerizations, the hydroxyl groups effect marked accelertion on polymerization rates. The salts also have excellent compatability with nonpolar monomers such as epoxidized oil and poly(1,2-butadience oxide) and provide further benefits when they are used along with copper cocatalysts in thermally curable polymer systems. In the latter form of cases, the secondary hydroxyl group serves as a reducing agent for the copper (II) complex.
专利号:US-11884772-B2 优先权日:2020-08-21 标题:Phenylphosphine oxide and oxygen stable epoxy polymers and methods of synthesis 发明人:FUCHS WITOLD K; WIGGINS JEFFREY 权利人:THE UNIV OF SOUTHERN MISSISSIPPI 摘要:A polymer formed of at least one phenylphosphine oxide functional epoxide crosslinked with at least one phenylphosphine oxide amine such that the polymer has phosphorous concentrations of at least about 8 percent by weight, at least about 8.5 percent by weight, or any value or range of values therebetween.
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合成参考文献
参考文献:10.1007/s11010-011-0989-9 摘要:Kim KY, Ahn JH, Cheon HG. Anti-angiogenic action of PPARγ ligand in human umbilical vein endothelial cells is mediated by PTEN upregulation and VEGFR-2 downregulation. Molecular and Cellular Biochemistry. 2011 Jul 17;358(1-2):375. doi: 10.1007/s11010-011-0989-9.