CAS: 1675-54-3; 2,2-Bis(4-Glycidyloxyphenyl)Propane

该化合物是一种化学化合物,其结构特征包括两组来自bookyol A的氧化物.它通常用作环氧树脂的活性稀释剂,增强树脂的特性,如灵活性,粘合性和化学抗药性.BADGE一般是没有色的,可粉黄,其粘合剂和合成物的粘合剂不易使用,因此适合涂层,粘合剂和合成物的各种应用.它的再活动允许它参与交叉反应,这对环氧系统治愈过程至关重要.然而,人们对它的潜在健康影响提出了关切,因为它会释放二酚A,一种与内分泌干扰有关的化合物.监管机构监测其使用情况,特别是在食品接触材料和消费品中的使用情况.适当的处理和安全措施至关重要,因为它具有潜在的刺激性,而且在使用期间需要适当的通风.总的来说,工业应用中重视环氧化合物的提高性能特性,同时需要仔细考虑健康和安全影响.

结构式图片

相似化合物

2210-72-2 3101-60-8 61578-04-9

欧盟法规

统一分类与标签REACH注册ECHA物质工作场所安全标识要求ECHA物质C&L通报REACH预注册废弃物危险特性清单

上下游产品

BPA epichlorohydrin 1-chloro-3-[4-[2-[4-(3-chloro-2-hydroxypropoxy)phenyl] propan-2-yl]phenoxy]propan-2-ol bisphenol A diallyl ether2,2-bis-[4-(2,3-diacetoxy-propoxy)-phenyl]-propane 5,5′-(((propane-2,2-diylbis(4,1-phenylene))bis(oxy))bis-(methylene))bis(3-(p-tolyl)oxazolidin-2-one) 3,3'-dibutyl-5,5'-[4,4'-(1-methyl-ethane-1,1-diyl)-bis-phenoxymethyl]-bis-oxazolidin-2-one 1-[Benzyl-(1,4,6-trioxa-spiro[4.4]non-2-ylmethyl)-amino]-3-{4-[1-(4-{3-[benzyl-(1,4,6-trioxa-spiro[4.4]non-2-ylmethyl)-amino]-2-hydroxy-propoxy}-phenyl)-1-methyl-ethyl]-phenoxy}-propan-2-ol

合成工艺路线路线简述

  • 合成目标产物 Bisphenol A Diglycidyl Ether Resin 主要起始原料 Bisphenol A And Epichlorohydrin
  • (文献来源)合成步骤主要原料 Bisphenol A 和 Epichlorohydrin
双酚 A 二(3-氯-2-羟丙基)醚 反应生成2,2-双-(4-甘胺氧苯)丙烷
参考文献:
标题:

海关参考信息

专利信息


专利号:US-11897860-B2
优先权日:2022-03-14
标题 :Direct synthesis of cyclic carbonates using choline chloride as catalyst under mild conditions
发明人:CARRASCO ANALETTE; WEERS JERRY J; BLACKWELL CATHERINE C; MURUGESAN SANKARAN; WANG XIAOFENG; NUGENT DOUGLAS; ROBERTS CORBY A
权利人:BAKER HUGHES OILFIELD OPERATIONS LLC
摘要:A method for direct synthesis of cyclic carbonates is achieved by reacting at least one epoxide with carbon dioxide in the presence of a choline catalyst, such as choline chloride, under mild conditions such as a temperature between about 25° C. to 150° C. and a pressure of from about atmospheric to 75 psi (0.52 MPa), in a cyclic carbonate solvent. The choline catalyst may be the only catalyst used, and a co-catalyst or hydrogen bond donor is not necessary. The concentration of choline catalyst in the solvent ranges from about 0.5 mol % to about 10 mol %, based on the epoxide.

专利号:US-9617396-B2
优先权日:2012-02-22
标 题:Method for in-situ synthesis of silicon nanoparticles
发明人:SCHUBERT CHLOÉ; PONCELET OLIVIER
权利人:COMMISSARIAT ENERGIE ATOMIQUE
摘要:The invention relates to a method for in-situ synthesis of silicon nanoparticles in a thermosetting polymeric matrix, the thermosetting and thermoset matrices obtained in this way and a material including same. The method includes the following steps: a) forming an aqueous-phase/organic-phase inverse emulsion, wherein the aqueous phase includes at least a basic catalyst and the organic phase includes at least a non-cross-linked (co)polymer precursor chosen from an aliphatic, cycloaliphatic or aromatic epoxy resin precursor, a polyester-imide precursor, an unsaturated/epoxy polyester (co)polymer precursor, a polyether/epoxy (co)polymer precursor and a polyurethane precursor; b) introducing, into the inverse emulsion formed in step a), at least one silicon precursor forming a complete network whereof the rate of hydrolysis is greater than the cross-linking speed of the (co)polymer and c) stirring the mixture obtained in step b) and heating to a temperature between 20° C. and 70° C.

专利号:WO-2015017140-A1
优先权日:2013-07-31
标题:Foam-free synthesis of co-polyhydroxyaminoether
发明人:MEZA CESAR E; HOYLES STEPHEN M; MAYNARD SHAWN J; SOLIS JUAN G; CASTILLO FLOR A
权利人:DOW GLOBAL TECHNOLOGIES LLC
摘要:A process includes an initial synthesis including mixing an epoxy and an aqueous amine solution to form a reaction mixture and addition of water to the reaction mixture while mixing. The amine includes: where R 5 is hydrocarbyl, R 6 is hydrogen, methyl, hydrocarbyl or mixtures thereof, and q is one to 1000; at least 90 mole-percent of the epoxy molecules have a reactive functionality in a range of one to two and an average reactive functionality of two or less; at least 90 mole- percent of the amine molecules have a number of reactive protons in a range of one to two and an average number of reactive protons of two or less; the amine is present at an excess mole ratio of reactive sites relative to epoxy reactive sites; and the temperature of the reaction mixture during the water addition is maintained between zero and 68 degrees Celsius.

专利号:US-5189184-A
优先权日:1990-08-30
标题:2-(3'-butenyl)-3,4-dihydro-2h-pyrans, their synthesis and use
发明人:SCHAEFER DIETMAR; WEIER ANDREAS; WEITEMEYER CHRISTIAN; WEWERS DIETMAR
权利人:GOLDSCHMIDT AG TH
摘要:2-(3'-butenyl)-3,4-dihydro-2H-pyrans of the general formula wherein R is a hydrogen group or an alkyl group with 1 to 6 carbon atoms. Methods for the synthesis of these compounds and their use as reactive modifiers or diluents for cationically curable monomers or polymers.

专利号:US-5073643-A
优先权日:1990-08-30
标 题 :High yield synthesis of hydroxyl-containing cationic photoinitiators
发明人:CRIVELLO JAMES V
权利人:POLYSET CORP
摘要:Synthesis use of a new class of diaryliodonium salt photo and thermal polymerization initiators in which the aryl groups are substituted with alkoxy group bearing hydroxy groups. Good to excellent yields are obtained of diaryliodonium salts in which the aryl groups are substituted with long chain alkoxy groups, which alkoxy groups also possess at least one hydroxyl moiety attached at the 2-position of an alkoxy group. The resultant salts have enhanced solubility when compared with their lower molecular weight counterparts. The hydroxyl groups serve as chain transfer agents; and, in cross linking UV-induced cationic polymerizations, the hydroxyl groups effect marked accelertion on polymerization rates. The salts also have excellent compatability with nonpolar monomers such as epoxidized oil and poly(1,2-butadience oxide) and provide further benefits when they are used along with copper cocatalysts in thermally curable polymer systems. In the latter form of cases, the secondary hydroxyl group serves as a reducing agent for the copper (II) complex.

专利号:US-11884772-B2
优先权日:2020-08-21
标题:Phenylphosphine oxide and oxygen stable epoxy polymers and methods of synthesis
发明人:FUCHS WITOLD K; WIGGINS JEFFREY
权利人:THE UNIV OF SOUTHERN MISSISSIPPI
摘要:A polymer formed of at least one phenylphosphine oxide functional epoxide crosslinked with at least one phenylphosphine oxide amine such that the polymer has phosphorous concentrations of at least about 8 percent by weight, at least about 8.5 percent by weight, or any value or range of values therebetween.
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主要参考文献

[参考文献]: A A Martinez, Et Al. Activation Of Ppar Gamma Receptors Reduces Levodopa-Induced Dyskinesias In 6-Ohda-Lesioned Rats. Neurobiol Dis. 2015 Feb:74:295-304.
[参考文献]: Jean-Christophe Deloulme, Et Al. Microtubule-Associated Protein 6 Mediates Neuronal Connectivity Through Semaphorin 3E-Dependent Signalling For Axonal Growth. Nat Commun. 2015 Jun 3:6:7246.
[参考文献]: Jie Ma, Et Al. Transplantation Of Human Neural Progenitor Cells Expressing Igf-1 Enhances Retinal Ganglion Cell Survival. Plos One. 2015 Apr 29;10(4):E0125695.
[参考文献]: Jin-Zhi Zhang, Et Al. Involvements Of Pcd And Changes In Gene Expression Profile During Self-Pruning Of Spring Shoots In Sweet Orange (Citrus Sinensis). Bmc Genomics. 2014 Oct 13;15(1):892.
[参考文献]: Konstantin Astafurov, Et Al. Oral Microbiome Link To Neurodegeneration In Glaucoma. Plos One. 2014 Sep 2;9(9):E104416.

合成参考文献


参考文献:10.1007/s11010-011-0989-9
摘要:Kim KY, Ahn JH, Cheon HG. Anti-angiogenic action of PPARγ ligand in human umbilical vein endothelial cells is mediated by PTEN upregulation and VEGFR-2 downregulation. Molecular and Cellular Biochemistry. 2011 Jul 17;358(1-2):375. doi: 10.1007/s11010-011-0989-9.
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