CAS: 940-41-0; Trichloro(Phenylethyl)Silane

该化合物是一种有机硅化合物,其特征是乙基链中有一个附属于乙基链的三氯硅基化合物,该化合物与苯环进一步相连.该化合物一般是无色的,无色的,黄色的液体,由于三氯硅基功能组的存在,它具有反应性而闻名.三氯硅基功能组在水分条件下可以随时水解,释放盐酸并形成硅醇物种.其结构具有疏水和脂类特性,在各种应用中有用,包括作为聚合化学中的混合剂和硅酮材料合成中的前体.此外,该化合物的活性允许它参与交叉联系反应,增强材料的机械特性.在处理该物质时,应当注意安全防范措施,因为它在接触时可能具有腐蚀性和危害性.

结构式图片

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18035-33-1 58274-32-1 211925-40-5

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CAS号292638-84-7 phenylene-ethylene | CAS号536-74-3 苯乙炔 | CAS号6233-20-1 2-氯乙基三氯硅烷 | CAS号71-43-2 苯 | CAS号10025-78-2 三氯氢硅 | CAS号75-94-5 乙烯基三氯硅烷 | CAS号7787-82-8 三氯-1-氯乙基甲硅烷 | CAS号690-18-6 trichloro(2-chl... | CAS号7446-70-0 氯化铝 | CAS号18292-20-1 (1-phenyl-ethyl... | CAS号18292-22-3 2-phenylethylsilane | CAS号785-78-4 4-乙酰基联苄 | CAS号60-12-8 苯乙醇 | CAS号772-64-5 trimethyl-phene...

合成工艺路线路线简述

  • 6233-20-1 = 940-41-0
    反应条件:1.1 Catalysts: Aluminum Chloride1.2 Reagents: Phosphorus Oxychloride
    标题:Effect Of The Substituents At The Silicon Of (ω-Chloroalkyl)Silanes On The Alkylation To Benzene
    作者:Yoo,B. R.; Hyun Kim,J.; Lee,H.-J.; Lee,K.-B.; Nam Jung,I.
    参考文献:Journal Of Organometallic Chemistry 日期:2000 卷标:605(2) 页码:239-245]

    = 940-41-0
    反应条件:1.1 Reagents: Aluminum Chloride
    标题:Halogenation Of Aromatic Silanes. Xxxi. Chlorination Of Aromatic Silanes Of The C6H5(Ch2)Nsicl3 Series (N = 1-4)
    作者:Motsarev,G. V.; Kolbasov,V. I.; Inshakova,V. T.; Rozenberg,V. R.; Alikhanov,P. P.
    参考文献:Zhurnal Obshchei Khimii 日期:1984 卷标:54(4) 页码:890-5]

    690-18-6 = 940-41-0 [标题:Reaction Conditions
    标题:Some Chemical Properties Of Chlorovinyl- And Ethynylsilanes
    作者:Sheludyakov,V. D.; Zhun,V. I.; Lakhtin,V. G.; Bochkarev,V. N.; Slyusarenko,T. F.; Et Al
    参考文献:Zhurnal Obshchei Khimii 日期:1984 卷标:54(3) 页码:640-6]

    = 940-41-0 + 7726-28-5
    反应条件:1.1 Reagents: Trichlorosilane Catalysts: Phenylacetonitrile,Chloroplatinic Acid
    标题:Hydrogen Hexachloroplatinate(Iv)
    作者:Sibi,Mukund P.
    参考文献:E-Eros Encyclopedia Of Reagents For Organic Synthesis 日期:2001 卷标:1 页码:1-8]

    = 940-41-0 + 7726-28-5
    反应条件:1.1 Catalysts: Chloro(Triphenylphosphine)Rhodium,1-Butyl-3-Methylimidazolium Hexafluorophosphate Solvents: Nitrogen,1-Butyl-3-Methylimidazolium Hexafluorophosphate; 0.5 H,70 °C1.2 Reagents: Trichlorosilane; 5 H,70 °C
    标题:Method For Hydrosilylation Of Olefin
    参考文献:China]

    = 940-41-0 + 7726-28-5
    反应条件:1.1 Reagents: Trichlorosilane Catalysts: Platinum (Zeolite-Bound)
    标题:Metalized Zeolites As A Catalysts For Hydrosilylation
    作者:Kopylova,L. I.; Kharlamov,V. V.; Pukhnarevich,V. B.; Voronkov,M. G.
    参考文献:Zhurnal Obshchei Khimii 日期:1994 卷标:64(10)]

    672-65-1 = 940-41-0 + 7726-28-5
    反应条件:1.1 Reagents: Trichlorosilane Catalysts: Tetrabutylphosphonium Chloride; 6 H,150 °C
    标题:Phosphonium Chloride-Catalyzed Dehydrochlorinative Coupling Reactions Of Alkyl Halides With Hydridochlorosilanes
    作者:Kang,Seung-Hyun; Han,Joon Soo; Yoo,Bok Ryul; Lee,Myong Euy; Jung,Il Nam
    参考文献:Organometallics 日期:2003 卷标:22(3) 页码:529-534]

    = 940-41-0
    反应条件:1.1 Reagents: Trichlorosilane Catalysts: Chloroplatinic Acid Solvents: Tetrahydrofuran; Rt -> 80 °C; 6 H,80 °C
    标题:Potassium Alkylpentafluorosilicates,Primary Alkyl Radical Precursors In The C-1 Alkylation Of Tetrahydroisoquinolines
    作者:Wang,Teng; Wang,Dong-Hui
    参考文献:Organic Letters 日期:2019 卷标:21(11) 页码:3981-3985]

    = 940-41-0
    反应条件:1.1 Reagents: Trichlorosilane Catalysts: Nickel Solvents: Tetrahydrofuran
    标题:Hydrosilylation Catalyzed By Activated Nickel
    作者:Boudjouk,Philip; Han,Byung Hee; Jacobsen,John R.; Hauck,Brian J.
    参考文献:Journal Of The Chemical Society 日期:1991 卷标:(20) 页码:1424-5]

    = 940-41-0 + 7726-28-5
    反应条件:1.1 Catalysts: Phenylacetonitrile,Trichlorosilane,Chloroplatinic Acid
    标题:Hydrogen Hexachloroplatinate(Iv)
    作者:Sibi,Mukund P.
    参考文献:E-Eros Encyclopedia Of Reagents For Organic Synthesis 日期:2001]

    = 940-41-0
    反应条件:1.1 Reagents: Trichlorosilane Solvents: Tetrahydrofuran,Benzene-D6; -196 °C; 7 H,100 °C
    标题:Process For The Stepwise Synthesis Of Silahydrocarbons
    参考文献:European Patent Organization]

    = 940-41-0
    反应条件:1.1 Reagents: Trichlorosilane Catalysts: Tetrakis(Triphenylphosphine)Palladium Solvents: Dimethylformamide; 5 H,115 °C
    标题:Hydrosilylation Conditions Applied On Alkenyl Benzylated Xyloses: Selective Reduction And Isomerization
    作者:Hadad,Caroline; Bouquillon,Sandrine; Harakat,Dominique; Muzart,Jacques
    参考文献:Applied Organometallic Chemistry 日期:2009 卷标:23(4) 页码:161-164]

    = 940-41-0
    反应条件:1.1 Reagents: Trichlorosilane Catalysts: Chloroplatinic Acid
    标题:Synthesis And Properties Of Azo Reagents Chemically Bonded With A Silica Surface
    作者:Markin,S. V.; Kudryavtsev,G. V.; Yudin,A. V.; Vertinskaya,T. E.; Lisichkin,G. V.
    参考文献:Zhurnal Obshchei Khimii 日期:1985 卷标:55(12) 页码:2761-7]

    = 940-41-0
    反应条件:1.1 Reagents: Trichlorosilane
    标题:Atranes. Lii. 1-Ethynylsilatrane And β-Substituted 1-Ethynyl- And 1-Vinylsilatranes
    作者:Voronkov,M. G.; Yarosh,O. G.; Shchukina,L. V.; Tsetlina,E. O.; Tandura,S. N.; Et Al
    参考文献:Zhurnal Obshchei Khimii 日期:1979 卷标:49(3) 页码:614-17]

    = 940-41-0 [标题:Reaction Conditions
    标题:Hydrosilylation Catalyzed By Transition Metal Complexes Coordinately Bound To Inorganic Supports
    作者:Capka,Martin; Hetflejs,Jiri
    参考文献:Collection Of Czechoslovak Chemical Communications 日期:1974 卷标:39(1) 页码:154-66]

    = 940-41-0 + 3401-10-3
    反应条件:1.1 Reagents: Trichlorosilane,Silicon Tetrachloride Catalysts: Tetrabutylphosphonium Chloride; 4 H,180 °C
    标题:Double Silylation Of Olefin With Hsicl3 In The Presence Of Bu4Pcl. New Synthetic Method For α,β-Bis(Trichlorosilyl)Alkanes
    作者:Kang,Seung-Hyun; Han,Joon Soo; Lim,Weon Cheol; Jung,Il Nam; Lee,Myong Euy; Et Al
    参考文献:Organometallics 日期:2006 卷标:25(2) 页码:318-319]

    = 940-41-0 + 3401-10-3
    反应条件:1.1 Reagents: Trichlorosilane Catalysts: Phosphonium,Tetraethyl-,Chloride (1:1); 2 H,180 °C
    标题:Method For Preparation Of Organosilicon Compounds By Double Silylation Of Unsaturated Compounds With Trichlorosilane
    参考文献:Japan]

    = 940-41-0 + 7726-28-5
    反应条件:1.1 Reagents: Trichlorosilane Catalysts: Palladium,Dichlorobis[[1-(Dimethylamino)Ethyl]Ferrocene]- (Supported On Benzaldehyde-Functionalized Polystyrene); 48 H,70 °C
    标题:Polymer-Supported Ferrocene Derivatives. Catalytic Hydrosilylation Of Olefins By Supported Palladium And Platinum Complexes
    作者:Cullen,William R.; Han,Nam Fong
    参考文献:Journal Of Organometallic Chemistry 日期:1987 卷标:333(2) 页码:269-80]

    = 940-41-0 + 7726-28-5
    反应条件:1.1 Reagents: Acetic Acid,Trichlorosilane Catalysts: 1,3-Divinyltetramethyldisiloxane (Platinum Complexes)
    标题:Method Of Preparation Of Aromatic Chlorosilane Compound By A Hydrosilation Reaction
    参考文献:European Patent Organization
📜苯乙烯置于镍 三氯硅烷体系中,用 四氢呋喃 作为反应溶剂,以88%的收率获得产物2-苯乙基三氯化硅烷
参考文献:Hydrosilylation Catalysed By Activated Nickel
标题:Hydrosilylation Catalysed By Activated Nickel
摘要:活化镍通过锂还原碘化镍并在超声作用下制备,能够在温和条件下有效催化己烯,苯乙烯,乙烯基丁基醚和丙烯腈的氢硅烷化反应.
DOI:10.1039/c39910001424

海关参考信息

专利信息


专利号:US-2023192731-A1
优先权日:2020-05-29
标 题 :Process for the stepwise synthesis of silahydrocarbons
发明人：AUNER NORBERT; STURM ALEXANDER G; SANTOWSKI TOBIAS; FELDER THORSTEN
权利人:MOMENTIVE PERFORMANCE MAT INC
摘要:The invention relates to a process for the stepwise synthesis of silahydrocarbons bearing up to four different organyl substituents at the silicon atom, wherein the process includes at least one step a) of producing a bifunctional hydridochlorosilane by a redistribution reaction, selective chlorination of hydridosilanes with an ether/HCl reagent, or by selective chlorination of hydridosilanes with SiCl 4 , at least one step b) of submitting a bifunctional hydridochloromonosilane to a hydrosilylation reaction, at least one step c) of hydrogenation of a chloromonosilane, and a step d) in which a silahydrocarbon compound is obtained in a hydrosilylation reaction.

专利号:US-11033507-B2
优先权日:2013-12-19
标 题 :Method of synthesis of silica vesicles and use thereof
发明人：YU CHENGZHONG; MITTER NEENA; ZHANG JUN
权利人:UNIV QUEENSLAND
摘要:The invention relates, in part, to a method of producing silica vesicles including under controlled conditions to thereby heavily influence the morphology and characteristics of the vesicles. The vesicles are shown to be effective as delivery agents for chemical and biological agents. They are also shown to be useful in methods of treatment and as components of an immunogenic composition.

专利号:US-6395825-B1
优先权日:1999-06-09
标题 :Process for synthesis of silicone resin
发明人：BECKER GREGORY SCOTT; CARPENTER II LESLIE EARL; KING RUSSELL KEITH; MICHINO TETSUYUKI; MOYER ERIC SCOTT; YEAKLE CRAIG ROLLIN
权利人:DOW CORNING; DOW CORNING ASIA LTD
摘要:A method for hydrolyzing chlorosilanes having at least three chlorine atoms bonded to each silicon atom to form silicone resins. The method comprises adding at least one of hydridotrichlorosilane, tetrachlorosilane, or organotrichlorosilane to a two-phase mixture comprising a non-polar organic solvent, an aqueous phase comprising 0 to about 43 weight percent hydrochloric acid, and a surface active compound selected from the group consisting of organosulfates described by formula R2SO4H and alkali metal salts thereof, where R2 is selected from the group consisting of alkyl groups comprising about 4 to 16 carbon atoms and alkylphenyl groups comprising 7 to about 22 carbon atoms.

专利号:US-2022355262-A1
优先权日:2019-07-22
标题 :System and method for manufacturing water-based hydrophobic aerogels and aerogel composites
发明人：SACHITHANADAM MAHESH; KHORASGANI SOGHRATI ELMIRA; NATARAJAN GAYATHRI
权利人:KROSSLINKER PTE LTD
摘要:Embodiments of the present invention provide users with a system and method for manufacturing water-based hydrophobic aerogels and aerogel composites. The system and method can be carried out in a manner which is more rapid than typical ways and can be readily scalable. The method of manufacture is useful for producing water based hydrophobic aerogels and aerogel composites on a large scale with good homogeneity and consistency. Advantageously, the method of manufacture also has the benefit of a shorter processing time due to the vacuum homogenizing and mixing processes, the use of microwave assisted vacuum freeze drying for ease of synthesis of water-based hydrophobic aerogels.

专利号:US-2018193278-A1
优先权日:2013-12-19
标题 :Method of synthesis of silica vesicles and use thereof

专利号:EP-3083765-A1
优先权日:2013-12-19
标题:Method of synthesis of silica vesicles and use thereof

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主要参考文献

参考标题: Process For The Stepwise Synthesis Of Silahydrocarbons Procédé De Synthèse Séquentielle De Silahydrocarbures
摘要:The Invention Relates To A Process For The Stepwise Synthesis Of Silahydrocarbons Bearing Up To Four Different Organyl Substituents At The Silicon Atom, Wherein The Process Includes At Least One Step A) Of Producing A Bifunctional Hydridochlorosilane By A Redistribution Reaction, Selective Chlorination Of Hydridosilanes With An Ether/hci Reagent, Or By Selective Chlorination Of Hydridosilanes With Sici4, At Least One Step B) Of Submitting A Bifunctional Hydridochloromonosilane To A Hydrosilylation Reaction, At Least One Step C) Of Hydrogenation Of A Chloromonosilane, And A Step D) In Which A Silahydrocarbon Compound Is Obtained In A Hydrosilylation Reaction.

合成参考文献


摘要:American Industrial Hygiene Association Journal., 23(95), 1962 []
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