CAS: 90069-81-1; Thiophene-3,4-Diamine Dihydrochloride

该化合物是电益替代反应,可导致形成各种衍生物;此外,3,4-Diminothophene 二氯化物可能展示生物活动,使其对药物研究感兴趣;安全数据表明,与许多氨一样,该化合物应谨慎处理,因为它在接触皮肤或眼睛时可能会引起刺激;适当的储存条件对于保持其稳定性和防止降解至关重要.

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CAS号52431-30-8 2,5-二溴-3,4-二硝基噻吩 | CAS号19985-45-6 3,4-dinitrothiophene | CAS号272-43-5 1,3-二溴-5-十二烷基-4... | CAS号78637-85-1 3,4-二氨基噻吩 | CAS号78648-59-6 2,3-dimethylthi...

合成工艺路线路线简述

  • 合成目标产物 3,4-Diaminothiophene Dihydrochloride 主要起始原料 2,5-Dibromo-3,4-Dinitrothiophene
  • 52431-30-8 = 90069-81-1
    反应条件:1.1 Reagents: Tin,Hydrochloric Acid Solvents: Water; 0 °C; 3 H,23 °C
    标题:A Chain-Growth Mechanism For Conjugated Polymer Synthesis Facilitated By Dinuclear Complexes With Redox-Active Ligands
    作者:King,Andrew J.; Zhukhovitskiy,Aleksandr V.
    参考文献:Angewandte Chemie 日期:2022 卷标:61(29)]

    52431-30-8 = 90069-81-1
    反应条件:1.1 Reagents: Tin,Hydrochloric Acid; 30 Min,25 - 30 °C; 6 H,30 °C
    标题:An N-Type Narrow-Bandgap Organoboron Polymer With Quinoidal Character Synthesized By Direct Arylation Polymerization
    作者:Dong,Changshuai; Meng,Bin; Liu,Jun; Wang,Lixiang
    参考文献:Journal Of Materials Chemistry C: Materials For Optical And Electronic Devices 日期:2022 卷标:10(7) 页码:2718-2723]

    52431-30-8 = 90069-81-1
    反应条件:1.1 Reagents: Tin,Hydrochloric Acid Solvents: Water; 20 - 25 °C; 25 °C
    标题:Iron(Ii) Complexes Containing Thiophene-Substituted "Bispicen" Ligands - Spin-Crossover,Ligand Rearrangements,And Ferromagnetic Interactions
    作者:Cheng,Haojin; Djukic,Brandon; Jenkins,Hilary A.; Gorelsky,Serge I.; Lemaire,Martin T.
    参考文献:Canadian Journal Of Chemistry 日期:2010 卷标:88(9) 页码:954-963]

    52431-30-8 = 90069-81-1
    反应条件:1.1 Reagents: Hydrochloric Acid Solvents: Water; Rt -> 0 °C1.2 Reagents: Tin; 1 H,< 25 °C; 2 H,Rt; 1 H,-18 °C
    标题:Donor-Acceptor-Donor Thienopyrazines Via Pd-Catalyzed C-H Activation As Nir Fluorescent Materials
    作者:Mcnamara,Louis E.; Liyanage,Nalaka; Peddapuram,Adithya; Murphy,J. Scott; Delcamp,Jared H.; Et Al
    参考文献:Journal Of Organic Chemistry 日期:2016 卷标:81(1) 页码:32-42]

    52431-30-8 = 90069-81-1
    反应条件:1.1 Reagents: Tin,Hydrochloric Acid Solvents: Water; 2 H,0 °C; 0 °C -> Rt; 2.5 H,Rt
    标题:Photocontrolled Synthesis Of N-Type Conjugated Polymers
    作者:Woods,Eliot F.; Berl,Alexandra J.; Kalow,Julia A.
    参考文献:Chemrxiv 日期:2019 卷标:1 页码:1-14]

    52431-30-8 = 90069-81-1
    反应条件:1.1 Reagents: Tin,Hydrochloric Acid
    标题:Tin
    作者:Steel,Peter J.
    参考文献:E-Eros Encyclopedia Of Reagents For Organic Synthesis 日期:2006 卷标:1 页码:1-7]

    52431-30-8 = 90069-81-1
    反应条件:1.1 Reagents: Tin,Hydrochloric Acid Solvents: Water
    标题:Synthesis And Characterization Of New Self-Assembled Metallo-Polymers Containing Electron-Withdrawing And Electron-Donating Bis(Terpyridine) Zinc(Ii) Moieties
    作者:Schluetter,Florian; Wild,Andreas; Winter,Andreas; Hager,Martin D.; Baumgaertel,Anja; Et Al
    参考文献:Macromolecules (Washington 日期:2010 卷标:43(6) 页码:2759-2771

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主要参考文献

[参考文献]: Rocío Ponce Ortiz, Et Al. Organic N-Channel Field-Effect Transistors Based On Arylenediimide-Thiophene Derivatives. J Am Chem Soc. 2010 Jun 23;132(24):8440-52.

合成参考文献


参考文献:10.1007/s10118-022-2661-0
摘要:He Z, Zhang Q, Li C, Han H, Lu Y. Synthesis of Thieno[3,4-b]pyrazine-based Alternating Conjugated Polymers via Direct Arylation for Near-infrared OLED Applications. Chinese Journal of Polymer Science. 2022 Jan 01;40(2):138–46. doi: 10.1007/s10118-022-2661-0.
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