CAS: 6294-31-1; Di-N-Hexylsulfide

相似化合物

2690-08-6 872-10-6 2469-45-6

上下游产品

CAS号111-25-1 1-溴代正己烷 | CAS号111-31-9 1-己硫醇 | CAS号64-19-7 冰醋酸 | CAS号2180-20-3 1-hexylsulfinyl... | CAS号16823-61-3 DI-N-HEXYL SULFONE | CAS号592-41-6 1-己烯 | CAS号10490-43-4 Di(2-chlorohexy... | CAS号100-99-2 三异丁基铝 | CAS号110-05-4 二叔丁基过氧化物 | CAS号42512-17-4 hexane-1-thiol,... | CAS号355-42-0 全氟己烷 | CAS号307-59-5 全氟十二烷 | CAS号1423-20-7 PERFLUOROHEXYLS... | CAS号2180-20-3 1-hexylsulfinyl... | CAS号16823-61-3 DI-N-HEXYL SULFONE | CAS号110-54-3 正己烷 | CAS号111-31-9 1-己硫醇

溴己烷置于18-冠醚-6,三甲基-三甲基锡烷基硫基锡烷,Cesium Fluoride体系中,用 乙腈 作为反应溶剂,化学反应 1.0H,以99%的收率获得产物己硫醚
参考文献:氰基和氟去甲锡烷基化:使用一些强大的硫转移试剂,即有机锡硫化物的新方法
标题:氰基和氟去甲锡烷基化:使用一些强大的硫转移试剂,即有机锡硫化物的新方法
摘要:氟化物和氰化物离子destannylate双(芳烷基)锡硫化物[r 3 Snssnr 3]和三烷基锡硫化物[r 3 Snsr'(r =烷基)]给出,在多种烷基的存在和活化的卤化物,相应的硫醚衍生物,收率极高.条件温和,中性和无水;注意到强烈的溶剂作用.对后处理程序提出了特别的意见.
DOI:10.1016/s0040-4039(00)96513-4

专利信息

专利号:US-6756199-B1
优先权日:1994-02-23
标题:Peptide nucleic acid combinatorial libraries and improved methods of synthesis
发明人：COOK PHILLIP DAN; KIELY JOHN; SPRANKLE KELLY
权利人:ISIS PHARMACEUTICALS INC
摘要:New sub-monomer synthetic methods for the preparation of peptide nucleic acid oligomeric structures are disclosed that provide for the synthesis of both predefined sequence peptide nucleic acid oligomers as well as random sequence peptide nucleic acid oligomers. Further these methods also provide for the incorporation of peptide nucleic acid units or strings of such units with amino acids or strings of amino acids in chimeric peptide nucleic acid-amino acid compounds. Further disclosed are method of making random libraries of peptide nucleic acids using the fully preformed monomers. Chimeric oligomers and libraries of the same are also disclosed.

专利号:US-6111110-A
优先权日:1996-10-30
标 题 :Synthesis of benzo[f]quinolinones
发明人：BRENNAN JOHN; DOECKE CHRISTOPHER WILLIAM; HEATH PERRY CLARK; PATTERSON LAWRENCE EDWARD; UDODONG UKO EFFIONG; WEIGEL LELAND OTTO
权利人:LILLY CO ELI
摘要:A process for preparing intermediates and benzoquinolin-3-one pharmaceuticals, such pharmaceuticals are effective in treating conditions consequent on 5α-reductase.

专利号:WO-2006027069-A1
优先权日:2004-09-07
标 题 :Method for producing heterocyclic quaternary ammonium and/or guanidinium compounds
发明人：DEGEN GEORG; EBEL KLAUS
权利人:BASF AG; DEGEN GEORG; EBEL KLAUS
摘要:The invention relates to a method for producing an intermediate product containing a heterocyclic quarternary ammonium and/or guanidium cation, for the synthesis of heterocyclic quaternary ammonium and/or guanidium compounds. According to said method, heterocyclic quaternary ammonium and/or guanidium carboxylates are oxidised with an oxidising agent in the presence of a metal from groups 8 to 10 of the periodical table, at a temperature of between 0 and 250 °C and a pressure of between 0.05 and 20 MPa abs.

专利号:WO-9965878-A1
优先权日:1998-06-18
标题 :Synthesis of benzo[f]quinolinones
发明人：HEATH PERRY CLARK
权利人:LILLY CO ELI; HEATH PERRY CLARK
摘要:A process for preparing intermediates and benzoquinolin-3-one pharmaceuticals, such pharmaceuticals are effective in treating conditions consequent on 5α-reductase.

专利号:CN-1867544-A
优先权日:2003-09-19
标 题:Process for enantioselective synthesis of single enantiomers of modafinil by asymmetric oxidation

专利号:EP-0839807-A1
优先权日:1996-10-30
标题:Synthesis of benzo(f)quinolinones