CAS: 5848-64-6; Hexa-N-Propylphosphoroustriamide

英文名称Hexa-N-Propylphosphoroustriamide
中文名称六(正丙基)磷三胺
IUPAC名称N,N,N',N',N'',N''-hexapropylphosphanetriamine
其它别名P(N(N-C3H7)2)3; Phosphine, Tris(Dipropylamino)-; Tris(N,N-Di-N-Propylamino)Phosphine; Tris(Dipropylamino)Phosphine; Hexa-N-Propyl Phosphorous Triamide; Hexaisopropylphosphorus Triamide; Tris(Di-N-Propylamino)Phosphine
CAS编号5848-64-6
MFCD编号:MFCD00015205
EINECS号:666-863-6
分子式:C18H42N3P分子量:331.53
产品CID: 1559656
产品分类有机原料 → 氨基化合物 → 无环单胺、多胺及其衍生物和盐

相似结构搜索
产品信息参考;;
InChIKey: KPDXRSBWIPGWLS-UHFFFAOYSA-N
InChI=1S/C18H42N3P/c1-7-13-19(14-8-2)22(20(15-9-3)16-10-4)21(17-11-5)18-12-6/h7-18H2,1-6H3
计算化学: 氢键受体数3.0氢键供体数0.0可旋转键数15.0

MSDS等安全信息

危险类别水生慢性毒性类别4
危险描述H413 |可能对水生生物造成长期有害影响.
防范说明P273, and P501
安全声明S26-S36
危险类别码R36/38

欧盟法规

ECHA物质C&L通报

上下游产品

dipropyl-amidophosphoric acid-dichloride di-n-propylamine 24H56N4P(1+)*I(1-)C24H56N4P(1+)*I(1-)2-Dipropylamino-benzo[1,3,2]oxazaphosphole-3-carboxylic acid phenylamide N-phenyl-N',N'-di(n-propyl)urea 1-(1-Dipropylamino-6-phenyl-thiazolo[3,2-d][1,2,4,3]triazaphosphol-2-yl)-ethanone 26H48N6P2SC26H48N6P2S

合成工艺路线路线简述

合成目标产物 Hexa-N-Propyl Phosphorous Triamide 主要起始原料 Phosphorus(1+), Tetrakis(N-Propyl-1-Propanaminato)-, Iodide, (T-4)- (9CI)
(文献来源)合成步骤主要原料 Phosphorus(1+), Tetrakis(N-Propyl-1-Propanaminato)-, Iodide, (T-4)- (9Ci)

📜二正丙胺置于三氯化磷体系中,用正己烷作为反应溶剂,化学反应 2.0H,以60%的收率获得产物六(正丙基)磷三胺
参考文献:Synthesen Und Kristallstrukturen Von Tris(Di-N-Propylamino)-P-Brombenzylphosphonium-Bromiden: [(C3H7)2N]3Pch2C6H4Br+br-Und [(C3H7)2N]3Pch2C6H4Br+br3-/syntheses And Crystal Structures Of Tris(Di-N-Propylamino)-P-Bromobenzyl-Phosphonium Bromides: [(C3H7)2N]3Pch2C6H4Br+br-And [(C3H7)2N]3Pch2C6H4Br+br3-
标题:Synthesen Und Kristallstrukturen Von Tris(Di-N-Propylamino)-P-Brombenzylphosphonium-Bromiden: [(C3H7)2N]3Pch2C6H4Br+br-Und [(C3H7)2N]3Pch2C6H4Br+br3-/syntheses And Crystal Structures Of Tris(Di-N-Propylamino)-P-Bromobenzyl-Phosphonium Bromides: [(C3H7)2N]3Pch2C6H4Br+br-And [(C3H7)2N]3Pch2C6H4Br+br3-
摘要:三(正丙基胺)-对溴苯基磷酸铵溴化物[(C3H7)2N]3Pch2C6H4Br+-Br-(1)是通过三(正丙基胺)磷与对溴苯甲溴反应于氯甲烷中制备的.无色晶体呈单斜晶系,空间群p21,Z = 2,A = 930.2(3),B = 1501.2(3),C = 1093.5(2) Pm,β = 105.97(4)°.晶格中含有br-阴离子和[(C3H7)2N]3Pch2C6H4Br+阳离子.[(C3H7)2N]3Pch2C6H4Br+br-(2)是通过在氯甲烷溶液中处理1和等摩尔量的元素溴制备的.2的黄红色晶体呈三斜晶系,空间群p1̄,Z = 2,A = 1069.5(3),B = 1267.7(7),C = 1273.7(3) Pm,α= 87.27(3),β = 82.67,γ = 67.15°,由[(C3H7)2N]3Pch2C6H4Br+阳离子和线性br3-阴离子组成.2中阳离子的三个n原子是平面的.
DOI:10.1515/znb-1999-0121