专利号:US-10611864-B2 优先权日:2015-09-22 标 题:Synthesis of substituted amidobenzoate compounds, the compounds obtained and the use thereof as phthalate free internal electron donor for polymerization of olefins 发明人:ZUIDEVELD MARTIN ALEXANDER; SAINANI JAIPRAKASH BRIJLAL; AL-HUMAIDAN OSAMAH; PADMANABHAN SUDHAKAR R; SHINGE PRASHANT SUKUMAR; SHETTY SHARANKUMAR G; SHAIKH ABBAS-ALLI GHUDUBHAI 权利人:SABIC GLOBAL TECHNOLOGIES BV 摘要:The present invention relates to a compound according to Formula (I) wherein R 1 is a hydrocarbyl group selected from the group consisting of alkyl, alkenyl, aryl, aralkyl, and alkylaryl groups, and one or more combinations thereof; wherein R 2 is a hydrogen atom, an aryl group or an alkyl group; and wherein R 3 , R 4 , R 5 and R 6 , are the same or different and are each independently a hydrogen atom, a halogen atom, a cyano group, an amino group, a hydrocarbyl group selected from the group consisting of alkyl, alkenyl, aryl, aralkyl, and alkylaryl groups or an alkoxy group, and one or more combinations thereof as internal electron donor and to a process for the synthesis of a compound according to Formula (I), wherein R 1 is a hydrocarbyl group selected from the group consisting of alkyl, alkenyl, aryl, aralkyl, alkoxycarbonyl and alkylaryl groups, and one or more combinations thereof; wherein R 2 is a hydrogen atom or an alkyl group; wherein R 3 , R 4 , R 5 and R 6 , are the same or different and are each independently selected from a group consisting of a hydrogen atom; a hydrocarbyl, preferably, said process comprising the step of reacting a compound according to Formula (II) [R 1 —C(â•?O)Cl] with a compound according to Formula (III) to obtain the compound according to Formula (I) and to the use of these compounds as internal donor in Ziegler-Natta catalysis of lefins.
专利号:WO-2017050870-A1 优先权日:2015-09-22 标题 :Synthesis of substituted amidobenzoate compounds, the compounds obtained and the use thereof as phthalate free internal electron donor for polymerization of olefins
专利号:US-2018273661-A1 优先权日:2015-09-22 标题 :Synthesis of substituted amidobenzoate compounds, the compounds obtained and the use thereof as phthalate free internal electron donor for polymerization of olefins
专利号:EP-3353146-A1 优先权日:2015-09-22 标题 :Synthesis of substituted amidobenzoate compounds, the compounds obtained and the use thereof as phthalate free internal electron donor for polymerization of olefins
专利号:EP-3353146-B1 优先权日:2015-09-22 标 题:Synthesis of substituted amidobenzoate compounds, the compounds obtained and the use thereof as phthalate free internal electron donor for polymerization of olefins
专利号:CN-108349873-B 优先权日:2015-09-22 标题:Synthesis of substituted amidobenzoate compounds and their use as phthalate-free internal electron donors