CAS: 17082-70-1; 4-[2-(Trichlorosilyl)Ethyl]Pyridine

相似化合物

85673-15-0 120277-01-2 28148-48-3

上下游产品

4-vinylpyridine

📜4-乙烯基吡啶置于三氯硅烷体系中,用 乙腈 用作溶剂,化学反应 2.0H,反应生成4-[2-(三氯硅基)乙基]嘧啶
参考文献:调整离子纳米粒子网络中的光致发光性质
标题:调整离子纳米粒子网络中的光致发光性质
摘要:为了研究离子纳米粒子网络(inn)的原始和有前途的发光特性,研究了各种材料成分.在这项工作中,用于使二氧化硅纳米颗粒形成网络的连接基发生了变化.提出了许多取代或未取代的咪唑,吡唑和吡啶鎓连接基.在inn杂化材料上进行的光致发光实验表明,在光谱的可见光区域内,很宽的范围内都具有很强的发射带.由于π-π堆积相互作用,使咪唑单元之间的芳族连接基发生变化,导致最大发射峰出现明显的位移,直至100 Nm.在芳族单元上引入的取代基的立体位阻和诱导效应,通过修饰咪唑环之间的π-π堆积,也强烈影响了材料的发光性能.小和广角x射线散射(saxs,Waxs)实验揭示了所获得的结构参数(短程有序参数和杂化材料中芳族单元的距离)与inn材料的发光量子产率之间存在明显的趋势.
Doi:10.1002/chem.201400392

专利信息

专利号:US-4638032-A
优先权日:1983-12-12
标 题 :Magnetic particles as supports for organic synthesis
发明人：BENNER STEVEN A
权利人:GENETICS INST
摘要:A support system for organic synthesis comprising magnetic particles in a dispersion medium covalently attached to functional groups having affinity for polymer subunits, and methods for making and using the support system, e.g. for synthesis of oligodeoxynucleotides and polypeptides.

专利号:WO-2008148560-A1
优先权日:2007-06-07
标题 :New hybrid compounds of nucleobases and organic redox molecules and their use
发明人：ASAFTEI SIMONA CARMEN
权利人:UNIV OSNABRUECK; ASAFTEI SIMONA CARMEN
摘要:The present invention relates to new compounds as well as methods for the synthesis of the same, said compounds comprise a redox active group, e.g. a 4,4-bipyridine (viologen), a 1,2-di(4-pyridyl)ethane, a 2,7-diazapyrene or 2,9-diazaperylene group and a N-heterocyclic nucleobase (HB), also referred to as base.

专利号:WO-2012075074-A1
优先权日:2010-11-30
标 题 :Layer-by-layer deposed multimetallic catalysts on a support
发明人：BARTHE PHILIPPE J; VANZUTPHEN STEVEN
权利人:CORNING INC; BARTHE PHILIPPE J; VANZUTPHEN STEVEN
摘要:This disclosure relates to a new metallic structure. This structure comprises a substrate (10) to which is bonded at least one first metallic layer (30) comprising at least one first metal, and is characterized in that the first metallic layer (30) comprises at least said first metal in the oxidized state bonded chemically to said substrate, a bifunctional organic layer (40) being bonded chemically via a first function suitable for bonding chemically to said first metal of the first metallic layer (30), and a second metallic layer (50), comprising at least one second metal in the oxidized state bonded chemically to said organic layer (40) via a second function suitable for bonding chemically to said second metal of the second metallic layer. This disclosure enables improvements in chemical synthesis by heterogeneous catalysis.