CAS: 14259-45-1; ((2As,2A1S,4As,5S)-1-Oxo-5-(((2S,3R,4S,5S,6R)-3,4,5-Trihydroxy-6-(Hydroxymethyl)Tetrahydro-2H-Pyran-2-yl)Oxy)-2A,2A1,4A,5-Tetrahydro-1H-2,6-Dioxacyclopenta[cd]Inden-4-yl)Methyl Acetate
该化合物是自然形成的甘蓝表面,主要来自各种植物物种,包括鲁比切埃家族的植物,其特征是化学结构,由与甘蓝,典型的酚类化合物相连的葡萄糖味组成,典型的酚类化合物,以其潜在的药理特性而著称,包括抗炎,抗氧化剂和抗微生物活动.该物质经常因其在传统医学及其潜在治疗用途中的作用而进行研究.就物理特性而言,甲状腺素通常在极地溶剂中溶解,反映其甘蓝性质.其稳定性可能受到诸如pH和温度等因素的影响,这些因素在自然和合成环境中都是重要的考虑因素.此外,对甲状腺素的研究突出了其在植物化学学中的重要性及其在各种与健康有关的应用中作为生物活性化合物的潜力.
- 英文名称((2As,2A1S,4As,5S)-1-Oxo-5-(((2S,3R,4S,5S,6R)-3,4,5-Trihydroxy-6-(Hydroxymethyl)Tetrahydro-2H-Pyran-2-yl)Oxy)-2A,2A1,4A,5-Tetrahydro-1H-2,6-Dioxacyclopenta[cd]Inden-4-yl)Methyl Acetate
- 中文名称车叶草苷
- IUPAC名称((2aS,2a1S,4aS,5S)-1-oxo-5-(((2S,3R,4S,5S,6R)-3,4,5-trihydroxy-6-(hydroxymethyl)tetrahydro-2H-pyran-2-yl)oxy)-2a,2a1,4a,5-tetrahydro-1H-2,6-dioxacyclopenta[cd]inden-4-yl)methyl acetate
- 其它别名Unii-V3Cfi02X39; Ibipgywnobgemh-Dilzhrmzsa-N; (2As,4As,5S,7Bs)-4-((Acetyloxy)Methyl)-5-(Beta-D-Glucopyranosyloxy)-2A,4A,5,7B-Tetrahydro-1H-2,6-Dioxacyclopent(Cd)Inden-1-One; [(2As,4As
- CAS编号14259-45-1
- MFCD编号:MFCD02094172
- EINECS号:238-137-5
- FDA UNII编号:V3CFI02X39
- 分子式:C18H22O11分子量:414.36
- 产品CID: 651094
- 产品分类天然产物 → 环烯醚萜衍生物
物理性质
MSDS等安全信息
欧盟法规
ECHA物质C&L通报REACH预注册合成工艺路线路线简述
海关参考信息
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2901220000-丙烯
2905122000-异丙醇
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专利信息
专利号:US-4410710-A
优先权日:1981-09-25
标题 :Conversion of iridoids to prostaglandins
发明人：BERKOWITZ WILLIAM F; CHOUDHRY SATISH C; HRABIE JOSEPH A
权利人:UNIV CITY
摘要:Naturally occurring iridoids provide the starting material for a unique synthesis sequence to produce prostaglandin intermediates. The iridoid lactone is hydrogenated, converted to an acetal, and rings opened to introduce the carbonyl octenyl side chain in six steps. The intermediate can be converted to prostaglandin as previously demonstrated.
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合成参考文献
参考文献:10.1021/np50026a002
摘要:Guiso M, Martino C. 6-Deoxylamioside, A New Iridoid Glucoside From Lamium amplexicaule. J. Nat. Prod. 1983 Mar;46(2):157–60. doi: 10.1021/np50026a002.
参考文献:10.1002/hlca.200900158
摘要:Kikuchi M, Onoguchi R, Yaoita Y. Three New Monoterpene Glucosides from Lamium amplexicaule. Helvetica Chimica Acta. 2009 Oct;92(10):2063–70. doi: 10.1002/hlca.200900158.
参考文献:10.3719/weed.38.97
摘要:Komai K, Omori S, Shimizu M, Hamada M. Isolation of Iridoid Glucosides from Paederia scandens and Assay of Biological Activities. J. Weed Sci. Tech. 1993;38(2):97–102. doi: 10.3719/weed.38.97.
参考文献:10.1515/znc-2002-7-807
摘要:Caliş I, Kirmizibekmez H, Tasdemir D, Sticher O, Ireland CM. Sugar esters from Globularia orientalis. Z Naturforsch C J Biosci. 2002 Jul;57(7-8):591–6. doi: 10.1515/znc-2002-7-807.
参考文献:10.1016/s0031-9422(00)84093-5
摘要:Uesato S, Ueda M, Inouye H, Kuwajima H, Yatsuzuka M, Takaishi K. Iridoids from Galium mollugo. Phytochemistry. 1984 Jan;23(11):2535–7. doi: 10.1016/s0031-9422(00)84093-5.
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