CAS: 112-30-1; Decan-1-Ol

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110-38-3 110-42-9 334-48-5

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癸烷置于recombinant Alcanivorax Borkumensis Sk2 A13-Red,还原型辅酶ii(Nadph)四钠盐,Sodium Chloride体系中,用 乙酸丁酯 用作溶剂,化学反应生成癸醇
参考文献:温和条件下烷烃活化的区域选择性生物催化剂
标题:温和条件下烷烃活化的区域选择性生物催化剂
摘要:走向绿色:烷烃羟基化的化学方法涉及有毒,危险的试剂,选择性不高.在基于人工自给自足的细胞色素p450的生化替代方法中,在温和条件下可以对正构烷烃进行高度选择性和高效的末端羟基化(请参阅方案; Nadph是烟酰胺腺嘌呤二核苷酸磷酸(nadp +)的还原形式) .
Doi:10.1002/anie.201005597

专利信息

专利号:US-7247752-B2
优先权日:2004-10-01
标 题 :Methods for the synthesis of astaxanthin
发明人：LOCKWOOD SAMUEL F; TANG PENG CHO; NADOLSKI GEOFF; JACKSON HENRY L; FANG ZHIQIANG; DU YISHU; YANG MIN; GEISS WILLIAM; WILLIAMS RICHARD; BURDICK DAVID
权利人:CARDAX PHARMACEUTICALS INC
摘要:A method used for synthesizing intermediates for use in the synthesis of carotenoids and carotenoid analogs, and/or carotenoid derivatives. In some embodiments, the invention includes methods for synthesizing optically active intermediates useful for the synthesis of optically active carotenoids. Synthesis of optically active carotenoids, in one embodiment, may be accomplished by forming an optically active dihydroxy intermediate from ketoisopherone. The optically active dihydroxy intermediate may be converted into optically active astaxanthin derivatives.

专利号:US-2010099894-A1
优先权日:2006-10-09
标 题 :Method for the Synthesis of Cyclic Acetals by the Reactive Extraction of a Polyol in a Concentrated Solution
发明人：DUBOIS JEAN-LUC; IBORRA CHORNET SARA; VELTY ALEXANDRA I LUCIENNE; CORMA CANOS AVELINO
权利人:DUBOIS JEAN-LUC; IBORRA CHORNET SARA; VELTY ALEXANDRA I LUCIENNE; CORMA CANOS AVELINO
摘要:A method for the synthesis of cyclic acetals comprises reacting at least one carbonyl-function compound selected from aldehydes, ketones, and/or linear acetals, on a polyol in a concentrated aqueous solution exceeding 20 wt % in a reactor containing an acidic catalyst. The carbonyl-function compound is selected so that the cyclic acetal obtained has a water solubility lower than 20000 mg/kg. During the catalytic reaction for the cyclic acetal synthesis, at least one portion of the organic phase containing the cyclic acetal is separated. The acidic catalysis is either homogeneous when using a water-soluble strong acid, or heterogeneous when using a solid acid such as a resin, a zeolite, or any appropriately acidified solid. The extractive reaction method can be used for obtaining high conversions and selectivity.

专利号:US-3978084-A
优先权日:1973-12-03
标题 :Synthesis of biotin
发明人：CONFALONE PASQUALE NICHOLAS; USKOKOVIC MILAN RADOJE; PIZZOLATO GIACOMO
权利人:HOFFMANN LA ROCHE
摘要:Synthesis of biotin from 4-carbomethoxy-2-(4,5-dihydrothiophen-3(2H)-one)-valeric acid methyl ester, and thiophene intermediates in this synthesis.

专利号:US-9126196-B2
优先权日:2009-05-26
标题 :Composition including dialkyl tin oxide and use thereof as a transesterification catalyst for the synthesis of (meth) acrylic esters
发明人：PAUL JEAN-MICHEL; TONNELIER BORIS; AUGUSTIN FRANCIS
权利人:PAUL JEAN-MICHEL; TONNELIER BORIS; AUGUSTIN FRANCIS; ARKEMA FRANCE
摘要:The present invention relates to a composition including a dialkyl tin oxide, such as DBTO, which can be used as a transesterification catalyst for the synthesis of (meth)acrylic esters. The invention also relates to a method for the synthesis of (meth)acrylic esters by transesterification in the presence of said composition.

专利号:US-5395992-A
优先权日:1993-02-06
标 题:Synthesis of diols, for use as intermediates for polymeric materials, by starting from terminal diolefins
发明人：RICCI MARCO; GEMENTI FRANCESCO; PANELLA FRANCESCO; QUERCI CECILIA; UNGARELLI RAFFAELE
权利人:ENICHEM SPA
摘要:Disclosed is the synthesis of terminal diols, which are organic intermediates used in order to produce polymeric materials, by starting from terminal diolefins, which synthesis is based on the oxidation of diolefins to yield diepoxides, in a double-phase aqueous-organic system with hydrogen peroxide and in the presence of catalysts soluble in the organic phase, followed by a reaction of reduction of the resulting diepoxides.

专利号:US-6156885-A
优先权日:1997-10-30
标 题 :Process for the synthesis of alkylpolyglucosides
发明人：MERONI MARIA LUISA; PELLIZZON TULLIO
权利人:CONDEA AUGUSTA SPA
摘要:The process for the synthesis of an alkylpolyglucoside having the formula (I): n n H--(G).sub.n --O--R-- (I) n n wherein n R is linear or branched, saturated or unsaturated C 8 -C 20 alkyl; n G is a radical resulting from removal of a molecule of water from a monosaccharide; and n n is an integer from 1 to 5; n the process entailing reacting an alcohol with a monosaccharide or a compound capable of generating a monosaccharide in in situ, wherein the reaction is carried out in the presence of a catalyst consisting of one or more sterically hindered polyalkylarylsulfonic acids.