CAS: 100-56-1; Phenylmercury Chloride

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CAS号1956-79-2 chloromethyl(tr... | CAS号368-47-8 苯基三氟硅烷 | CAS号100-58-3 苯基溴化镁 | CAS号7727-18-6 三氯氧钒 | CAS号587-85-9 二苯基汞 | CAS号7632-51-1 四氯化钒 | CAS号603-33-8 三苯基铋 | CAS号1600-27-7 乙酸汞 | CAS号7647-14-5 氯化钠 | CAS号71-43-2 苯 | CAS号10304-81-1 2-氯丙基苯 | CAS号2887-97-0 2,6-diphenylcyc... | CAS号363-03-1 2-苯基-1,4-苯醌 | CAS号32294-60-3 联苯二碲 | CAS号4505-48-0 2-苯基茚 | CAS号92-52-4 联苯 | CAS号92-93-3 4-硝基联苯 | CAS号20195-59-9 1,2,3,4,5-penta... | CAS号994-31-0 氯化三乙基锡 | CAS号878-51-3 MONOPHENYLTRIET...

📜苯基三氟硅烷置于mercury Dichloride体系中,用 四氢呋喃 用作溶剂,以98%的收率获得氯化苯汞
参考文献:Nucleophilic Cleavage Of The Sic Bond In Organotrifluorosilanes And Diorganodifluorosilanes
标题:Nucleophilic Cleavage Of The Sic Bond In Organotrifluorosilanes And Diorganodifluorosilanes
摘要:
Doi:10.1016/0022-328X(88)89077-6

专利信息

专利号:US-8088740-B2
优先权日:2009-05-04
标题:Gold binding peptides and shape-and size-tunable synthesis of gold nanostructures
发明人：HUR HOR GIL; KIM JUNG OK; KIM DAE HEE; MYUNG NO SANG
权利人:HUR HOR GIL; KIM JUNG OK; KIM DAE HEE; MYUNG NO SANG; KWANGJU INST SCI & TECH
摘要:The present invention relates to gold binding peptides and shape- and size-tunable synthesis of gold nanostructures. The present inventions are very useful for the production of well-designed, gold-based architectures. The size- and shape-specific gold nanostructure materials prepared by the present invention may find use as: highly conductive interconnections for single-electron transistors, catalysts for the oxidation of carbon monoxide; biological and chemical sensors; and as contrasting agents for electron microscopic and medical imaging applications.

专利号:US-6737504-B2
优先权日:2001-07-30
标 题 :Synthesis of substituted poly(aniline)s
发明人：FREUND MICHAEL S; SHOJI EIICHI
权利人:CALIFORNIA INST OF TECHN
摘要:A method for preparing a wide range of substituted poly(aniline)s from a single precursor is described. The method uses a variety of reactions, including a boron activation/electrophilic displacement reaction resulting in ipso-substitution. The ability to tune the properties of poly(aniline) through the generation of new structures is useful in numerous fields ranging from polymer-based electronics to sensors.

专利号:US-4080334-A
优先权日:1968-11-22
标题:Intermediates in the total synthesis employing substituted isoxazole derivatives
发明人：SAUCY GABRIEL; SCOTT JOHN WILLIAM
权利人:HOFFMANN LA ROCHE
摘要:The intermediates and processes of this invention provide a new synthetic route for the preparation of pharmaceutically valuable 19-norsteroids. Further, the intermediates and processes of the invention provide a route for the preparation of pharmaceutically valuable estrones. The present invention provides a facile total synthesis of 19β-alkyl-C/D-trans-steroidal materials. This desirable result is obtained via a unique asymmetric induction followed by subsequent stereo-specific reaction steps. As a precursor to the steroidal Ring A, a 3,5-disubstituted-4-isoxazolylmethylene group is employed in this synthesis.

专利号:US-3985771-A
优先权日:1968-11-22
标题:Total steroid synthesis employing substituted isoxazole derivatives
发明人：SAUCY GABRIEL; SCOTT JOHN WILLIAM
权利人:HOFFMANN LA ROCHE
摘要:The novel intermediates and processes of this invention provide a new synthetic route for the preparation of pharmaceutically valuable 19-nor-steroids. Further, the intermediates and processes of the invention provide a novel route for the preparation of pharmaceutically valuable estrones. The present invention provides a facile total synthesis of 13β-alkyl-C/D-trans-steroidal materials. This desirable result is obtained via a unique asymmetric induction followed by subsequent stereo-specific reaction steps. As a precursor to the steroidal Ring A, a 3,5-disubstituted-4-isoxazolylmethylene group is employed in this synthesis.

专利号:US-4044004-A
优先权日:1968-11-22
标题 :Total steroid synthesis employing substituted isoxazole derivatives
发明人：SAUCY GABRIEL; SCOTT JOHN WILLIAM
权利人:HOFFMANN LA ROCHE
摘要:The novel intermediates and processes of this invention provide a new synthetic route for the preparation of pharmaceutically valuable 19-norsteroids. Further, the intermediates and processes of the invention provide a novel route for the preparation of pharmaceutically valuable estrones. The present invention provides a facile total synthesis of 19β-alkyl-C/D-trans-steroidal materials. This desirable result is obtained via a unique asymmetric induction followed by subsequent stereospecific reaction steps. As a precursor to the steroidal Ring A, a 3,5-disubstituted-4-isoxazolylmethylene group is employed in this synthesis.

专利号:US-4105705-A
优先权日:1976-04-30
标 题:Symmetrical biaryl synthesis via rhodium catalyzed dimerization of aryl mercuric salts
发明人：LAROCK RICHARD CRAIG
权利人:UNIV IOWA STATE RES FOUND INC
摘要:Vinyl- and arylmercuric halide salts undergo reaction with rhodium (I) and (III) catalysts, preferably in the presence of lithium chloride to provide essentially quantitative yields of the corresponding 1,3 dienes and biaryls respectively. Importantly, the reaction is stereospecific and is especially valuable for synthesis of symmetrical functionally substituted dienes, biaryls and polyenes.