专利号:US-10669425-B2 优先权日:2017-05-02 标题 :One-pot synthesis of reactive deep black 发明人:VRIEZEMA DENNIS MANUEL; KLEINE SIGRID ELISABETH; SMALLEGANGE MARTIN JAN 权利人:SPGPRINTS B V 摘要:A one-pot synthesis for preparing an aqueous reactive black mixture includes a) dissolving 2-[(4-aminophenyl)sulfonyl]ethanesulfonic acid (vinyl sulphone parabase ester) in water; b) diazotizing the dissolved vinyl sulphone parabase ester using excess nitrous acid or using excess nitrite and an acid, resulting in a diazonium salt and remaining nitrous acid; c) quenching the remaining nitrous acid with sulfamic acid; d) coupling the diazonium salt of step c) with 4-amino-5-hydroxy-2,7-naphthalenedisulfonic acid (H-acid) until the reaction is complete, resulting in Reactive Black 5 (RB 5) and remaining diazonium salt, e) coupling the remaining diazonium salt with 7-acetamido-4-hydroxy-2-naphthalenesulfonic acid (acetyl-J-acid) until the reaction is complete resulting in Reactive Orange 78 (RO 78); and f) obtaining the aqueous reactive black mixture.
专利号:WO-9108265-A1 优先权日:1989-12-02 标 题:Azo compounds and their use as dyes, 1-sulpho-6-carboxyl-amino naphthaline, its use as a diazo component and process for the production of these compounds 发明人:SPRINGER HARTMUT; HUSSONG KURT 权利人:HOECHST AG 摘要:The description relates to azo compounds corresponding to formula (1) below, having fibre-reactive properties and making valuable dyes. They can dye hydroxy and/or carbonamide group-containing synthetic and natural materials, especially fibre materials, like wool and especially cellulose fibre materials in bright colours. Formula (1) in which: M is hydrogen or a salt-forming metal like an alkaline metal; K is a residue of general formulae (2A) or (2B) in which: E is the residue of an intermediate component common in disazo dyes which can act as a coupling and as a diazo component, e.g. the residue of a 1-(aminophenyl) or -amino-naphthyl) pyrazolon, aminonaphthol, anilin or 1-amino naphthalin compound; v is the figure zero or 1; K is the residue of a water-soluble coupling component, preferably from the naphthol, aminonaphthol, anilin, pyrazolon, hydroxypyridon and acetoacetyl arylide series, whereby this coupling component contains 1 or 2 fibre-reactive groups of the vinyl sulphonate series; D is a benzol or naphthalin residue, whereby its substituents R?1 and R?2 are common ones in azo dyes, e.g. (besides hydrogen) lower alkyl, lower alkoxy, halogen, sulpho and carboxyl; the group -SO2?-Y is a fibre-reactive group of the vinyl sulphone series; a is the figure zero, 1 or 2; and k is the number 1 or 2. A description is also given of the compound 2-amino naphthaline-1-sulphonic acid-6-carboxylic acid which may be used as a pre-product in the production of dyes, e.g. as diazo component in the synthesis of dyes of general formula (1).
专利号:WO-2024133701-A1 优先权日:2022-12-22 标题:New fucosyltransferases for in vivo synthesis of complex fucosylated human milk oligosaccharides mixtures comprising lndfh-iii 发明人:PAPADAKIS MANOS 权利人:DSM IP ASSETS BV 摘要:The present disclosure relates to the production of complex fucosylated Human Milk Oligosaccharides (HMOs) and in particular to the production of complex fucosylated HMOs with five or more monosaccharide units, such as LNFP-III, LNFP-VI and LNDFH-III as well as mixtures thereof. The present disclosure also relates to genetically engineered cells and α-1,3-fucosyltransferases suitable for use in said production, as well as to methods for producing said fucosylated HMOs.
专利号:US-4521338-A 优先权日:1981-08-12 标题:Process for the preparation of low molecular weight 4,4'-diphenylmethane-uretdione-diisocyanates 发明人:GROEGLER GERHARD; KOPP RICHARD 权利人:BAYER AG 摘要:Low molecular weight 4,4'-diphenylmethane-uretdione-diisocyanates corresponding to the formula: +TR wherein n is a number from 0 to 1, are made by dimerizing diphenylmethane-4,4'-diisocyanate at a temperature of 50 DEG C. or less in a mixture of non-polar and moderately polar solvents in the presence of a dimerization catalyst. The dimerization product may then be worked up at low temperatures (i.e., =50 DEG C.). The dimerization products of diphenylmethane-diisocyanate thus obtained generally have only a small amount of oligomeric uretdione-diisocyanates present. These dimerization products may be used advantageously in the synthesis of polyurethanes.
专利号:US-6924403-B2 优先权日:2002-06-26 标题:Synthesis of hexafluoropropylene 发明人:BARNES JOHN JAMES; KELCH KENNETH PAUL; SANDBROOK THOMAS D; VAN BRAMER DAVID JOHN 权利人:DU PONT 摘要:The present invention relates to the process of pyrolyzing tetrafluoroethylene to hexafluoropropylene by carrying out the pyrolysis in a tubular reactor that is lined with either nickel or nickel alloy which contains no greater than 8 wt % chromium.
专利号:US-4719053-A 优先权日:1980-08-01 标题 :Beta-chloroethylsulfonylmethyl-benzoic halides as intermediates 发明人:SCHLAEFER LUDWIG; HAEHNLE REINHARD 权利人:HOECHST AG 摘要:New beta -chloroethylsuflonylmethyl-benzoic acid halides which can serve as fibre-reactive anchors for thesynthesis of novel organic, water-soluble compounds, preferably dyestuffs, having fibre-reactive and fibre-finishing properties, such as preferably dyestuff properties, and containing, as a fibre-reactive group, one or two beta -chloroethylsufonylmethylbenzoic acid amide groups. For the synthesis of these novel fibre-finishing compounds, said new beta -chloroethylsulfonylmethyl-benzoic acid halide compounds are reacted with an organic, water-soluble compound having fibre-finishing properties and continuing one or two amino groups. Also precursors of the fibre-finishing, fibre-reactive compounds, containing said beta -chloroethylsulfonylmethyl-benzxoic acid amid grouping, can be employed for their synthesis. The novel fibre-finishing compounds can be applied onto suitable fibre materials, such as especially cellulose fibre material and natural or synthetic polyamide fibre materials, and fixed on these fibre materials in a manner similar to application and fixation methods usual in the technique for fibre-reactive compounds. The fibre-finished material, such as dyed material, shows very good wet fastnesses.
摘要:D. D. Perrin. J. Chem. Soc. 1961, 2244. 参考文献:10.1007/s10661-005-9070-z 摘要:Parikh A, Shah V, Madamwar D. Cyanobacterial Flora from Polluted Marine Shores. Environmental Monitoring and Assessment. 2006 Jun 07;120(1-3):407–14. doi: 10.1007/s10661-005-9070-z. 参考文献:10.1007/s10661-006-7229-x 摘要:Parikh A, Shah V, Madamwar D. Cyanobacterial Flora from Polluted Industrial Effluents. Environmental Monitoring and Assessment. 2006 May;116(1-3):91–102. doi: 10.1007/s10661-006-7229-x. 参考文献:10.1007/s00894-017-3214-2 摘要:Güryel S, Alonso M, Hajgató B, Dauphin Y, Van Lier G, Geerlings P, De Proft F. A computational study on the role of noncovalent interactions in the stability of polymer/graphene nanocomposites. Journal of Molecular Modeling. 2017 Feb 02;23(2):43. doi: 10.1007/s00894-017-3214-2.