CAS: 83237-27-8; 1-(2-Hydroxyethyl)Cyclobutan-1-Ol
该化合物是一种双功能环丁烷衍生物,主要包括一个主要氢氧基组和一个附属于环丁烷环的二级氢氧基组,这种结构具有独特的反应性,使其成为有机合成的多功能中间体,特别是用于制造环和多功能化合物.存在两个氢氧基组,可以有选择地发挥作用,使药物,农用化学品和特殊聚合物的应用成为可能.其硬性环丁烷核心助长了消毒性限制,可以利用这些限制影响目标分子的相容稳定性.该化合物的平衡的氢能性和中度极性增强了其在普通有机溶剂中的溶性,促进了其在多步骤合成途径中的使用.
- 英文名称1-(2-Hydroxyethyl)Cyclobutan-1-Ol
- 中文名称1-(2-羟乙基)环丁-1-醇
- IUPAC名称1-(2-hydroxyethyl)cyclobutan-1-ol
- 其它别名1-(2-Hydroxyethyl)Cyclobutanol; 1-Hydroxy-1-(β-Hydroxyethyl)Cyclobutane; Cyclobutaneethanol, 1-Hydroxy-; 1-(2-Hydroxyethyl)Cyclobutan-1-Ol
- CAS编号83237-27-8
- MFCD编号:MFCD22056276
- EINECS号:876-323-3
- 分子式:C6H12O2分子量:116.16
- 产品CID: 1821252
- 产品分类有机原料→分子砌块→脂肪环类化合物→环丁烷类化合物
相似化合物
933695-45-5 83237-26-7 141227-29-4MSDS等安全信息
欧盟法规
C&L通报上下游产品
methanol nonane5,7-dioxaspiro3.5nonane 1-oxa-spiro[2.3]hexane-2-carboxylic acid ethyl ester diethoxyphosphoryl-acetic acid ethyl ester 2-(1-hydroxycyclobutyl)ethyl 4-methylbenzenesulfonate 4-oxa-5-phenylspiro[3.4]°Ctane合成工艺路线路线简述
- 1120-56-5 = 83237-27-8
反应条件:1.1 Reagents: Sulfuric Acid2.1 Reagents: Sulfuric Acid Catalysts: Methanol
标题:Synthesis Of 1-Vinylcyclobutene From Methylenecyclobutane Based On The Prins Reaction
作者:Finkel'Shtein,E. Sh.; Et Al
参考文献:Izvestiya Akademii Nauk Sssr 日期:1982 卷标:(7) 页码:1665-6]
73637-29-3 = 83237-27-8
反应条件:1.1 Reagents: Sulfuric Acid Catalysts: Methanol
标题:Synthesis Of 1-Vinylcyclobutene From Methylenecyclobutane Based On The Prins Reaction
作者:Finkel'Shtein,E. Sh.; Et Al
参考文献:Izvestiya Akademii Nauk Sssr 日期:1982 卷标:(7) 页码:1665-6]
73637-29-3 = 83237-27-8 + 83237-26-7
反应条件:1.1 Reagents: Methanol Catalysts: Sulfuric Acid Solvents: Methanol
标题:Electrophilic Addition To Methylenecyclobutane And Bicyclobutylidene
作者:Finkel'Shtein,E. Sh.; Et Al
参考文献:Neftekhimiya 日期:1985 卷标:25(1) 页码:48-57]
1120-56-5 = 83237-27-8 + 83237-26-7
反应条件:1.1 Catalysts: Sulfuric Acid Solvents: Water2.1 Reagents: Methanol Catalysts: Sulfuric Acid Solvents: Methanol
标题:Electrophilic Addition To Methylenecyclobutane And Bicyclobutylidene
作者:Finkel'Shtein,E. Sh.; Et Al
参考文献:Neftekhimiya 日期:1985 卷标:25(1) 页码:48-57
📜1-Oxaspiro<2.5>Hexan-2-Carbonsaeure-Ethylester,3,3-Trimethylen-Glycidsaeure-Ethyl-Ester置于lithium Aluminium Tetrahydride体系中,用 四氢呋喃,乙醚 作为反应溶剂,化学反应 7.0H,反应生成 1-(2-羟基乙基)环丁醇
参考文献:Ep2011788
标题:Ep2011788
海关参考信息
- 2905122000-异丙醇
2905143000-叔丁醇
2905399001-1,3-丙二醇
2905142000-仲丁醇 - 💡 提示：海关信息按照顺序优先匹配，如需确认的海关信息，请参考相关资料。
- 详情请参考：📖 海关编码查询和海关进出口税则
供应商参考报价(招募中)
品牌试剂参考报价(招募中)
📌 第三方产品分析报告
主要参考文献
参考标题:A New Approach To The Synthesis Of 1-Oxaspiro[4.N]Alkanes And Tetrahydrofurans By The 1,5-Ch Insertion Reaction Of Magnesium Carbenoids作者:Tsuyoshi Satoh,Tsukasa Yasoshima,Hitoshi Momochi |发布日期:2012.4
摘要:In High To Quantitative Yields Via The 1,5-Ch Insertion Reaction Of Generated Magnesium Carbenoid Intermediates. When This Procedure Was Commenced With Acyclic Ketones, Multi-Substituted Tetrahydrofurans Were Obtained In Up To A 96% Yield. This Procedure Provides A New And Good Way For The Synthesis Of 1-Oxaspiro[4.N]Alkanes And Tetrahydrofurans With The Formation Of A Carbon-Carbon Bond Between A Carbenoid
合成参考文献
参考文献:10.1007/bf00954189
摘要:Finkel'shtein ES, Yatsenko MS, Vdovin VM. Preparation of 1 -vinylcyclobutene from methylenecyclobutane by the prins reaction. Russian Chemical Bulletin. 1982 Jul;31(7):1483–4. doi: 10.1007/bf00954189.
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