CAS: 66863-43-2; (S)-2-(Tert-Butoxycarbonyl)-2,3,4,9-Tetrahydro-1H-Pyrido[3,4-B]Indole-3-Carboxylic Acid
该化合物是一种在制药和有机合成中广泛使用的有机保护的四氢-β碳基衍生物,其硬性三环结构和立体化学纯度使它成为构建复杂的生物活性分子,特别是在药用化学中,的宝贵中间体.乙氧基碳基(Boc)组在温和酸条件下增强稳定性,促进选择性的去保护.碳箱酸功能允许通过恐吓或酯化进一步衍生.这种化合物由于受限制的符合和与固相聚聚苯乙烯合成协议的兼容性,在聚苯乙烯合成协议中特别有用.高抗原纯度确保了在立体敏感应用中产生可再生效果.
- 英文名称(S)-2-(Tert-Butoxycarbonyl)-2,3,4,9-Tetrahydro-1H-Pyrido[3,4-B]Indole-3-Carboxylic Acid
- 中文名称Boc-L-1,2,3,4-四氢-β-咔啉-3-羧酸
- IUPAC名称(S)-2-(tert-butoxycarbonyl)-2,3,4,9-tetrahydro-1H-pyrido[3,4-b]indole-3-carboxylic acid
- 其它别名(S)-2-(叔丁氧羰基)-2,3,4,9-四氢-1H-吡啶并[3,4-B]吲哚-3-羧酸; N-Boc-L-1,2,3,4-Tetrahydro-Beta-Carboline-3-Carboxylic Acid
- CAS编号66863-43-2
- MFCD编号:MFCD00800580
- EINECS号:960-132-8
- 分子式:C17H20N2O4分子量:316.36
- 产品CID: 1650134
- 产品分类有机原料→分子砌块→芳杂环类化合物→吲哚类化合物
物理性质
MSDS等安全信息
上下游产品
CAS号1070-19-5 Carbonazidic ac... | CAS号42438-90-4 (S)-2,3,4,9-四氢-... | CAS号24424-99-5 二碳酸二叔丁酯 | CAS号73-22-3 L-色氨酸 | CAS号50-00-0 甲醛合成工艺路线路线简述
海关参考信息
- 2902200000-苯
2905122000-异丙醇
2905143000-叔丁醇
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专利信息
专利号:US-7138491-B2
优先权日:2003-10-08
标 题 :Carboline-3-carboxylic acid modified related sequences of Ala-Arg-Pro-Ala-Lys, their synthesis and use as thromobolytic agent
发明人：PENG SHIQI; ZHAO MING; WANG CHAO; WU YANGFEN
权利人:GUANGZHOU BAI YUN SHAN PHARMAC
摘要:The present invention relates to the protected intermediates and the deprotected products of P6A, related to the protected pseudopeptides introducing the protected intermediateds of P6A to 3S-(2-Boc)-1,2,3,4-tetrahydro-β-carboline-3-carboxylic acid and the deprotected pseudopeptides, related to the protected pseudopeptides introducing the protected intermediateds of P6A to 3S-1,2,3,4-tetrahydro-β-carboline-3-carboxylic acid benzyl ester, related to the methods for their preparation, and related to their use as the thrombolytic agents.
专利号:US-2005080015-A1
优先权日:2003-10-08
标题 :Carboline-3-carboxylic acid modified related sequences of Ala-Arg-Pro-Ala-Lys, their synthesis and use as thromobolytic agent
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合成参考文献
参考文献:10.1016/j.bmcl.2012.04.020
摘要:Zeng L, Zhang J. Design, synthesis, and evaluation of a novel class of 2,3-disubstituted-tetrahydro-β-carboline derivatives. Bioorganic & Medicinal Chemistry Letters. 2012 Jun;22(11):3718–22. doi: 10.1016/j.bmcl.2012.04.020.
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