CAS: 51591-75-4; Cis-1,3-Dibenzyl-2-Oxoimidazolidine-4,5-Dicarboxylic Acid

该化合物是一种化学化合物,其特征是其imidazolidone结构,其特点是含有氮原子的五人环.该化合物通常具有与碳酸和酰亚焦利酮有关的特性,包括极地溶剂中由于存在碳酸组而可能溶解的溶液.二苯基替代成分助长其疏水特性,影响其溶解性和与生物系统的互动.精密配置表明,苯基化合物组位于基环的同一侧,这可能会影响化合物的立体化学性和再活动.该化合物可能具有有机合成,制药或协调化学中的离心作用,但具体应用可能有所不同.其独特的结构允许生物系统中的潜在相互作用,从而引起对药用化学的兴趣.许多有机化合物的处理应当谨慎,考虑到安全数据及其使用的潜在危害.

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CAS号75-44-5 光气 | CAS号14464-17-6 (2S)-2-(dibenzy... | CAS号26339-42-4 cis-1,3-Dibenzy... | CAS号28092-55-9 6ξ-acetoxy-1,3-... | CAS号55645-40-4 内-2,3-双(苄氨基)丁二酸 | CAS号58-85-5 D-生物素 | CAS号26339-42-4 cis-1,3-Dibenzy...

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    专利信息


    专利号:US-4014895-A
    优先权日:1972-06-22
    标 题:Method for synthesis of optically active thiolactones
    发明人:AOKI YASUHIKO; SUZUKI HIROYUKI; AKIYAMA HISAO; OKANO SHIGERU
    权利人:SUMITOMO CHEMICAL CO
    摘要:A new method for the production of intermediates in the synthesis of an optically active biotin, which comprises reacting a dicarboxylic acid of the formula: ##SPC1## n Or its reactive derivative with an optically active primary amine, reducing the resulting trione with a metal hydride, hydrolyzing the resultant amide-alcohol and treating the thus produced lactone with a thiolactonating agent to give a thiolactone of the formula: ##SPC2## n , the said trione and amide-alcohol being respectively novel and representable by the formulae: ##SPC3##

    专利号:US-10737239-B2
    优先权日:2015-11-27
    标题 :Ultrafast high space-time-yield synthesis of metal-organic frameworks
    发明人:BURCKHART JULIA; MARX STEFAN; ARNOLD LENA; HOFMANN CLAUS; Müller Ulrich
    权利人:BASF SE
    摘要:The invention relates to a process for the preparation of metal-organic frameworks (MOFs) in form of a homogenous powder, and a process wherein the metal-organic framework is molded into shaped bodies.

    专利号:US-9951095-B2
    优先权日:2014-05-16
    标 题:Chromium metal organic frameworks and synthesis of metal organic frameworks
    发明人:ZHOU HONG-CAI; Liu tian-fu; LIAN XIZHEN; ZOU LANFANG; FENG DAWEI
    权利人:TEXAS A & M UNIV SYS
    摘要:The present invention relates to monocrystalline metal organic frameworks comprising chromium ions and carboxylate ligands and the use of the same, for example their use for storing a gas. The invention also relates to methods for preparing metal organic frameworks comprising chromium, titanium or iron ions and carboxylate ligands. The methods of the invention allow such metal organic frameworks to be prepared in monocrystalline or polycrystalline forms.

    专利号:US-11891406-B2
    优先权日:2019-03-14
    标题:Conductivity enhancement of MOFs via development of MOFpolymer composite material
    发明人:PEEDIKAKKAL ABDUL MALIK P; AL-BETAR ABDUL-RAHMAN; AL-MOUSA AMMAR HUSSAIN
    权利人:UNIV KING FAHD PET & MINERALS
    摘要:A method for enhancing the conductivity of MOF-5 by the development of an MOF-5 polymer composite material. The composite material incorporates a conductive polymer, preferably polyaniline, in the solvo-thermal synthesis pathway of MOF-5. The electrically conductive MOF-5 composite exhibits electric conductivity three orders of magnitude higher than that of MOF-5 while maintaining the crystallinity, robustness, and thermal stability of MOF-5.

    专利号:US-2018333696-A1
    优先权日:2015-11-27
    标题:Ultrafast high space-time-yield synthesis of metal-organic frameworks

    专利号:US-4403096-A
    优先权日:1980-07-10
    标 题:Optically active imidazolidin-2-one derivatives
    发明人:HAZAMA MOTOO; ARATANI TADATOSHI; SUZUKAMO GOHU; TAKAHASHI TAKEO
    权利人:SUMITOMO CHEMICAL CO
    摘要:A novel optically active cis-4,5-disubstituted imidazolidin-2-one derivative of the formula: wherein R1 is a C1-C4 alkyl group or benzyl and R2 is a chiral aralkyl group optionally having at least one of C1-C4 alkyl, C1-C4 alkoxy and hydroxyl groups is produced asymmetrically by the reaction of 1,3-dibenzyl-cis-4,5-dicarboxy-imidazolidin-2-one or its anhydride with an optically active secondary amine of the formula: wherein R1 and R2 are each as defined above and is transformed into the lactone of 1,3-dibenzyl-cis-4-carboxy-5-hydroxymethyl-imidazolidin-2-one, which is a key intermediate in the synthesis of d-biotin.

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    合成参考文献


    摘要:Kleemann, A.; Engel, J.; Kutscher, B.; Reichert, D., Pharmaceutical Substances[Online], Thieme: Stuttgart, (2003).
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