专利号:US-4014895-A 优先权日:1972-06-22 标 题:Method for synthesis of optically active thiolactones 发明人:AOKI YASUHIKO; SUZUKI HIROYUKI; AKIYAMA HISAO; OKANO SHIGERU 权利人:SUMITOMO CHEMICAL CO 摘要:A new method for the production of intermediates in the synthesis of an optically active biotin, which comprises reacting a dicarboxylic acid of the formula: ##SPC1## n Or its reactive derivative with an optically active primary amine, reducing the resulting trione with a metal hydride, hydrolyzing the resultant amide-alcohol and treating the thus produced lactone with a thiolactonating agent to give a thiolactone of the formula: ##SPC2## n , the said trione and amide-alcohol being respectively novel and representable by the formulae: ##SPC3##
专利号:US-10737239-B2 优先权日:2015-11-27 标题 :Ultrafast high space-time-yield synthesis of metal-organic frameworks 发明人:BURCKHART JULIA; MARX STEFAN; ARNOLD LENA; HOFMANN CLAUS; Müller Ulrich 权利人:BASF SE 摘要:The invention relates to a process for the preparation of metal-organic frameworks (MOFs) in form of a homogenous powder, and a process wherein the metal-organic framework is molded into shaped bodies.
专利号:US-9951095-B2 优先权日:2014-05-16 标 题:Chromium metal organic frameworks and synthesis of metal organic frameworks 发明人:ZHOU HONG-CAI; Liu tian-fu; LIAN XIZHEN; ZOU LANFANG; FENG DAWEI 权利人:TEXAS A & M UNIV SYS 摘要:The present invention relates to monocrystalline metal organic frameworks comprising chromium ions and carboxylate ligands and the use of the same, for example their use for storing a gas. The invention also relates to methods for preparing metal organic frameworks comprising chromium, titanium or iron ions and carboxylate ligands. The methods of the invention allow such metal organic frameworks to be prepared in monocrystalline or polycrystalline forms.
专利号:US-11891406-B2 优先权日:2019-03-14 标题:Conductivity enhancement of MOFs via development of MOFpolymer composite material 发明人:PEEDIKAKKAL ABDUL MALIK P; AL-BETAR ABDUL-RAHMAN; AL-MOUSA AMMAR HUSSAIN 权利人:UNIV KING FAHD PET & MINERALS 摘要:A method for enhancing the conductivity of MOF-5 by the development of an MOF-5 polymer composite material. The composite material incorporates a conductive polymer, preferably polyaniline, in the solvo-thermal synthesis pathway of MOF-5. The electrically conductive MOF-5 composite exhibits electric conductivity three orders of magnitude higher than that of MOF-5 while maintaining the crystallinity, robustness, and thermal stability of MOF-5.
专利号:US-2018333696-A1 优先权日:2015-11-27 标题:Ultrafast high space-time-yield synthesis of metal-organic frameworks
专利号:US-4403096-A 优先权日:1980-07-10 标 题:Optically active imidazolidin-2-one derivatives 发明人:HAZAMA MOTOO; ARATANI TADATOSHI; SUZUKAMO GOHU; TAKAHASHI TAKEO 权利人:SUMITOMO CHEMICAL CO 摘要:A novel optically active cis-4,5-disubstituted imidazolidin-2-one derivative of the formula: wherein R1 is a C1-C4 alkyl group or benzyl and R2 is a chiral aralkyl group optionally having at least one of C1-C4 alkyl, C1-C4 alkoxy and hydroxyl groups is produced asymmetrically by the reaction of 1,3-dibenzyl-cis-4,5-dicarboxy-imidazolidin-2-one or its anhydride with an optically active secondary amine of the formula: wherein R1 and R2 are each as defined above and is transformed into the lactone of 1,3-dibenzyl-cis-4-carboxy-5-hydroxymethyl-imidazolidin-2-one, which is a key intermediate in the synthesis of d-biotin.