CAS: 2170-06-1; Trimethyl(Phenylethynyl)Silane

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CAS号16029-98-4 三甲基碘硅烷 | CAS号536-74-3 苯乙炔 | CAS号108-86-1 溴苯 | CAS号1066-54-2 三甲基硅基乙炔 | CAS号591-50-4 碘苯 | CAS号762-72-1 烯丙基三甲基硅烷 | CAS号108-90-7 氯苯 | CAS号17763-67-6 三氟甲烷磺酰苯 | CAS号124515-97-5 [hydroxy(tosylo... | CAS号102998-76-5 1-phenylundec-1... | CAS号109-09-1 2-氯吡啶 | CAS号13141-42-9 2-(Phenylethyny... | CAS号372-48-5 2-氟吡啶 | CAS号4747-15-3 Β-苯乙烯甲醚 | CAS号31378-03-7 2-(对甲苯磺酰基)苯乙酮 | CAS号16212-08-1 Benzene,1-methy... | CAS号4891-38-7 苯丙炔酸甲酯 | CAS号92961-15-4 3-苯基咪唑并[1,2-a]吡啶 | CAS号4105-21-9 2-苯基咪唑并[1,2-a]吡啶

📜苯乙炔置于正丁基锂体系中,用 四氢呋喃,正己烷,乙腈 用作溶剂,化学反应 26.0H,反应生成苯基乙炔基三甲基硅烷
参考文献:1炔烃和氯硅烷的et 2 Zn介导的化学计量c(sp)-H甲硅烷基化
标题:1炔烃和氯硅烷的et 2 Zn介导的化学计量c(sp)-H甲硅烷基化
摘要:报道了et 2 Zn介导的1-炔烃甲硅烷基化的第一个例子.在该反应中容许一系列官能团.机理研究支持炔基锌作为反应的中间体.该反应方案为制备炔基硅烷提供了一种实用的方法,并扩展了有机金属锌在有机合成中的应用.
Doi:10.1016/j.Tetlet.2019.05.017

专利信息

专利号:US-8618281-B2
优先权日:2006-01-03
标 题 :Geometric synthesis of porphyrin rods
发明人：LINDSEY JONATHAN S; YU LIANHE; THAMYONGKIT PATCHANITA; BHISE ANIL D
权利人:LINDSEY JONATHAN S; YU LIANHE; THAMYONGKIT PATCHANITA; BHISE ANIL D; UNIV NORTH CAROLINA STATE
摘要:A method of making a compound of Formula I′ n ncomprises reacting a compound of the formula DLCHO, with a compound of the formulan n nto produce the compound of Formula I′. Methods of using the compounds are also described, particularly as intermediates for the synthesis of porphyrin rods, which porphyrin rods are in turn useful for (among other things) the production of molecular memory devices.

专利号:US-10919904-B2
优先权日:2016-08-17
标 题 :Northern-southern route to synthesis of bacteriochlorins
发明人：LIU YIZHOU; LINDSEY JONATHAN S; ALLU SRINIVASA RAO; FUJITA HIKARU
权利人:UNIV NORTH CAROLINA STATE
摘要:Described herein are chlorins, bacteriochlorins, methods and intermediates for the synthesis of bacteriochlorins, and methods of using such bacteriochlorins for, among other things, diagnostic and therapeutic purposes such as luminescent compounds in flow cytometry, and as active agents in photodynamic therapy (PDT).

专利号:US-6916982-B2
优先权日:2000-07-21
标题:Synthesis of perylene-porphyrin building blocks and polymers thereof for the production of light-harvesting arrays
发明人：LOEWE ROBERT S; TOMIZAKI KIN-YA; LINDSEY JONATHAN S
权利人:UNIV NORTH CAROLINA STATE
摘要:The present invention provides methods, compounds, and compositions for the synthesis of light harvesting arrays, such arrays comprising: (a) a first substrate comprising a first electrode; and (b) a layer of light harvesting rods electrically coupled to said first electrode, each of said light harvesting rods comprising a polymer of Formula I:n nX 1 X m+1 ) m   (I)n nwherein m is at least 1; X 1 is a charge separation group, and X 2 through X m+1 are chromophores. At least one of X 2 through X m+1 has at least one perylene group coupled thereto.

专利号:US-5446203-A
优先权日:1992-08-25
标题:Synthesis of haloenones and aryl or alkyl substituted enones or alkenes
发明人：MCNELIS EDWARD
权利人:UNIV NEW YORK
摘要:Alternative methods for synthesizing haloenones and haloakenes and their use as starting materials for synthesis of substituted or unsubstituted alkyl and aryl substituted enones and alkenes, including tamoxifen and tamoxifen analogs, using such haloenones and haloalkenes.

专利号:US-7741475-B2
优先权日:2006-02-13
标题:Synthesis of monovalent and polyvalent arabinans and mannose-capped arabinans of the protective cell-wall coat of mycobacterium tuberculosis
发明人：FRASER-REID BERTRAM; LU JUN
权利人:NATURAL PRODUCTS & GLYCOTECHNO
摘要:The present application provides arabinans and mannose-capped arabinan compositions of formulas I-VIII, described herein, and methods of making the compositions.

专利号:US-9822123-B2
优先权日:2005-02-18
标 题 :De novo synthesis of bacteriochlorins
发明人：KIM HAN-JE; LINDSEY JONATHAN S
权利人:UNIV NORTH CAROLINA STATE
摘要:A method of making a bacteriochlorin is carried out by condensing a pair of compounds of Formula II n nto produce the bacteriochlorin, wherein R is an acetal or aldehyde group. The condensing may be carried out in an organic solvent, preferably in the presence of an acid. The bacteriochlorins are useful for a variety of purposes such as active agents in photodynamic therapy, luminescent compounds in flow cytometry, solar cells, light harvesting arrays, and molecular memory devices.