专利号:US-2024400861-A1 优先权日:2021-10-01 标题 :Triazole- And/Or Triazolium-Based Polymers And Copolymers As Additives For Chemical Mechanical Planarization Slurries 发明人:LARBIG GREGOR; KIRSCH PEER; HENGST MATTHIAS; SHI XIAOBO; STENDER MATTHIAS 权利人:VERSUM MAT US LLC 摘要:Synthesis of triazole- and/or triazolium-based polymers is disclosed. Chemical Mechanical Planarization (CMP) slurries comprise abrasives; activator; oxidizing agent; additive comprising triazole- and/or triazolium-based polymers; and water. The use of the synthesized triazole- and/or triazolium-based polymers in the CMP slurries reduces dishing and erosion in highly selective tungsten slurries.
专利号:WO-2024073211-A1 优先权日:2022-09-29 标题:Guanidinium-based polyionic liquids and their use as additives for chemical mechanical planarization slurries 发明人:LARBIG GREGOR; KIRSCH PEER; SHI XIAOBO 权利人:VERSUM MAT US LLC 摘要:Synthesis of guanidinium-based polymers is disclosed. Chemical Mechanical Planarization (CMP) slurries comprise abrasives; activator; oxidizing agent; additive comprising guanidinium-based polymers; and water. The use of the synthesized guanidinium-based polymers in the CMP slurries reduces dishing and erosion in highly selective tungsten slurries.
专利号:US-2025215130-A1 优先权日:2022-04-11 标 题:Polycationic Polymer Or Copolymer Having Different Cation Types For Slurries In Chemical Mechanical Planarization 发明人:LARBIG GREGOR; SHI XIAOBO 权利人:MERCK PATENT GMBH; VERSUM MAT US LLC 摘要:Synthesis of polycationic polymer or copolymer is disclosed. The polycationic polymer or copolymer are formed by at least one first cationic monomer and at least one second cationic monomer wherein the first cationic monomer and the second cationic monomer have different cationic groups; such as imidazolium group and non-imidazolium group. Chemical Mechanical Planarization (CMP) slurries comprise abrasives; activator; oxidizing agent; additive comprising polycationic polymer or copolymer; and water are also disclosed. The use of the synthesized polycationic polymer or copolymer in the CMP slurries reduces dishing and erosion in highly selective tungsten slurries.
专利号:WO-2024073209-A1 优先权日:2022-09-30 标 题 :Modified water-soluble polysaccharides having different cation types for slurries in chemical mechanical planarization 发明人:DAVIDI INBAL; LARBIG GREGOR; SHI XIAOBO; MA SANA 权利人:VERSUM MAT US LLC 摘要:Synthesis of cationic-modified water-soluble polysaccharide is disclosed. The cation is pendent to the polysaccharide backbone. Chemical Mechanical Planarization (CMP) slurries comprise abrasives; activator; oxidizing agent; additive comprising cationic-modified water-soluble polysaccharide; and water. The use of the synthesized cationic-modified water-soluble polysaccharide in the CMP slurries reduces dishing and erosion in highly selective tungsten slurries.
专利号:WO-2024129383-A1 优先权日:2022-12-13 标 题 :Dicationic polymer and copolymer and their use for chemical mechanical planarization 发明人:LARBIG GREGOR; MA SANA 权利人:VERSUM MAT US LLC 摘要:Synthesis of dicationic polymer or copolymer is disclosed. The dicationic polymer or copolymer are formed by at least one dicationic(or dual-cationic) monomer. Chemical Mechanical Planarization (CMP) slurries comprise abrasives; activator; oxidizing agent; additive comprising dicationic polymer or copolymer; and water. The use of the synthesized dicationic polymer or copolymer in the CMP slurries reduces dishing and erosion in highly selective tungsten slurries.
参考标题:Initial Intraorgan Formation Of Mercapturic Acid. 作者:Kazumi Sano,Yoji Ikegami,Takashi Uesugi 摘要:The Disposition Of S-Benzyl-Glutathione (Bsg) In Male Wistar Rats Was Evaluated By The Hplc Method To Examine Whether The Kidney And Liver Contributed Independently To The Biosynthesis Of S-Benzyl-N-Acetylcysteine (Bnac), A Mercapturic Acid (Chart 1). After Intravenous Injection, Bsg Was Rapidly Transported In Both The Kidney And The Liver At A Ratio Of About 7:3. Simultaneously, A Large Amount Of Bnac Was Found In Both The Kidney And The Liver. In The Kidney, S-Benzyl-Cysteine (Bcys) Reached A Maximum Concentration (Cmax) At 2 Min After Bsg Injection, Whereas Bnac Reached Cmax Within 3 To 5 Min. The Generation Of Bnac Was Also Observed In The Liver. While Renal Bnac Reached Cmax Within 3 To 5 Min, Hepatic Bnac Reached Cmax Around 5 Min After Bsg Injection. Moreover, The Elimination Half-Life Of The Bnac After Intravenous Injection Of The Bsg Was Equivalent To That Observed After Intravenous Injection Of The Bnac Itself. These Results Demonstrate That The Kidney Contributes To The Initial Intraorgan Generation Of Bnac And That This Mercapturic Acid Is Also Synthesized In The Liver And Preferentially Excreted Into Urine.
合成参考文献
参考文献:10.1093/jat/16.3.147 摘要:Dinoff TM, Winter CK, Jones AD, New R. An Evaluation of Sample Preparation Techniques for the GC/MS Analysis of Urinary aercapturic Acid Conjugates. Journal of Analytical Toxicology. 1992 May 01;16(3):147–51. doi: 10.1093/jat/16.3.147. 参考文献:10.1016/s0378-4347(96)00259-9 摘要:Einig T, Dunemann L, Dehnen W. Sensitive gas chromatographic method for determination of mercapturic acids in human urine. Journal of Chromatography B: Biomedical Sciences and Applications. 1996 Dec;687(2):379–85. doi: 10.1016/s0378-4347(96)00259-9. 参考文献:10.1002/rcm.1580 摘要:Barbieri A, Sabatini L, Accorsi A, Roda A, Violante FS. Simultaneous determination of t,t ‐muconic, S ‐phenylmercapturic and S ‐benzylmercapturic acids in urine by a rapid and sensitive liquid chromatography/electrospray tandem mass spectrometry method. Rapid Comm Mass Spectrometry. 2004 Jul 30;18(17):1983–8. doi: 10.1002/rcm.1580.