合成目标产物 Tungsten(Vi) Chloride 主要起始原料 Disulfur Dichloride And Tungsten
(文献来源)合成步骤主要原料 Disulfur Dichloride 和 Tungsten
四氯化钨置于氯体系中,用 Gas 用作溶剂,化学反应生成六氯化钨 参考文献:Dzevitskii,B. E.; Skorobogatov,G. A.,Journal Of General Chemistry Of The Ussr,1987,Vol. 57,P. 2372-2377 标题:Dzevitskii,B. E.; Skorobogatov,G. A.,Journal Of General Chemistry Of The Ussr,1987,Vol. 57,P. 2372-2377
专利信息
专利号:US-5502126-A 优先权日:1993-06-17 标 题 :Process for the synthesis of isoprene butadiene rubber 发明人:BELL ANTHONY J; MATRANA BARRY A; HALASA ADEL F 权利人:GOODYEAR TIRE & RUBBER 摘要:The subject invention relates to a technique for synthesizing rubbery non-tapered, random, copolymers of 1,3-butadiene and isoprene. These rubbery copolymers exhibit an excellent combination of properties for utilization in tire sidewall rubber compounds for truck tires. By utilizing these isoprene-butadiene rubbers in tire sidewalls, tires having improved cut growth resistance can be built without sacrificing rolling resistance. Such rubbers can also be employed in tire tread compounds to improve tread wear characteristics and decrease rolling resistance without sacrificing traction characteristics. This invention more specifically discloses a process for the synthesis of isoprene-butadiene rubbers which comprises copolymerizing isoprene monomer and 1,3-butadiene monomer in an organic solvent in the presence of a catalyst system which is made by the sequential steps of (1) mixing (a) an organoaluminum hydride, (b) a member selected from the group consisting of aliphatic alcohols, cycloaliphatic alcohols, aliphatic thiols, cycloaliphatic thiols, trialkyl silanols, and triaryl silanols, and (c) optionally, 1,3-butadiene in an organic solvent to produce a modified organoaluminum catalyst component; (2) adding an organometallic compound which contains a metal from Group III-B of the Periodic System to the modified organoaluminum catalyst component to produce a Group III-B metal containing catalyst component; and (3) adding a compound which contains at least one labile halogen atom to the Group III-B metal containing catalyst component.
专利号:US-5997949-A 优先权日:1995-09-22 标题 :Synthesis of W-Si-N films by chemical vapor deposition using WF6, SiH4 and NH3 发明人:NICOLET MARC-A; MADAR ROLAND; BERNARD CLAUDE; FLEMING JAMES G; ROHERTY-OSMUN ELIZABETH LYNN; SMITH PAUL M; CUSTER JONATHAN S; JONES RONALD V 权利人:CALIFORNIA INST OF TECHN; SANDIA CORP 摘要:The present invention relates to the forming of amorphous or near-amorphous, ternary films of W-Si-N on substrates by chemical vapor deposition of WF 6 , SiH 4 and NH 3 and a carrier gas. The present invention method will allow the conformal forming of amorphous or near-amorphous, ternary films of W-Si-N on patterned non-planar substrates at temperatures at or below about 450° C., by chemical vapor deposition of WF 6 , SiH 4 and NH 3 and a carrier gas. A typical temperature range for the formation of the films is between 473° K. and 773° K., while the reactor pressure can be varied between 0.1 to 50 Torr. The composition of the deposited films is adjusted by varying the flow ratios of the reactive gases.
专利号:US-10669160-B2 优先权日:2018-04-30 标题:Heterogeneous wet synthesis process for preparation of high purity tungsten pentahalide 发明人:LIU YUMIN; LI FENG; WAN ZHIWEN; FAFARD CLAUDIA; WIESE STEFAN; HUSSON GUILLAUME; NIKIFOROV GRIGORY; SUI BIN; GIRARD JEAN-MARC 权利人:AIR LIQUIDE; AIR LIQUIDE AMERICAN 摘要:Synthesis of tungsten pentahalide compositions having low impurity profiles are disclosed. The specific impurity profile permits deposition of high purity tungsten-containing films using vapor deposition processes or other semiconductor manufacturing processes without introduction of performance-impacting contaminants.
专利号:US-2009137828-A1 优先权日:2005-08-18 标 题 :Synthesis of 1A-Fluoro-25-Hydroxy-16-23E-Diene-26,27-Bishomo-20-Epi-Cholecalciferol 发明人:USKOKOVIC MILAN R; MARCZAK STANISLAW; LOO RALF; VAN DER SLUIS MARCEL; JANKOWSKI PAWEL; MAEHR HUBERT 权利人:BIOXELL SPA 摘要:The invention provides a method of producing 20-methyl vitamin D3 compounds of formula (I). The method includes allylic and olefin oxidation, de-carbonylation, carbonyl reduction, fluoride substitution, epoxide deoxygenation, and Wittig-type couplings.
专利号:US-4366101-A 优先权日:1979-06-21 标 题 :Synthesis of long-chain alkanes having terminal functionality 发明人:GIBSON THOMAS W 权利人:PROCTER & GAMBLE 摘要:A process for preparing primary substituted n-alkane compounds, comprising contacting the olefin product of an olefin metathesis reaction having an alpha-olefin as the reactant with a bis-cyclopentadienyl zirconium hydrohalide and, after contacting the product of the olefin-zirconium hydrohalide reaction with an electrophilic reagent, recovering said primary substituted n-alkane compound.
专利号:US-4268697-A 优先权日:1979-06-21 标 题 :Synthesis of long-chain alkanes having terminal functionality 发明人:GIBSON THOMAS W 权利人:PROCTER & GAMBLE 摘要:A process for preparing primary substituted n-alkane compounds, comprising contacting the olefin product of an olefin metathesis reaction having an alpha-olefin as the reactant with a bis-cyclopentadienyl zirconium hydrohalide and, after contacting the product of the olefin-zirconium hydrohalide reaction with an electrophilic reagent, recovering said primary substituted n-alkane compound.
[参考文献]: Tobias Flt, Et Al. Material Decomposition In Dual-Energy Computed Tomography Separates High-Z Elements From Iodine, Identifying Potential Contrast Media Tailored For Dual Contrast Medium Examinations. J Comput Assist Tomogr. 2015 Nov-Dec;39(6):975-80.
合成参考文献
摘要:Toyota, S.; Iwanaga, T., Science of Synthesis, (2010) 45, 761. 摘要:Masuda, T.; Shiotsuki, M.; Sanda, F., Science of Synthesis, (2010) 45, 1426. 摘要:Kaminsky, W., Science of Synthesis, (2009) 48, 730. 摘要:López-Carrillo, V.; Echavarren, A. M., Science of Synthesis Knowledge Updates, (2011) 2, 22. 摘要:Bruneau, C.; Fischmeister, C., Science of Synthesis: C-1 Building Blocks in Organic Synthesis, (2013) 2, 356.